Citation: Fahui Xiang, Lu Li, Zhen Yuan, Wuji Wei, Xiaoqing Zheng, Shimin Chen, Yisi Yang, Liangji Chen, Zizhu Yao, Jianwei Fu, Zhangjing Zhang, Shengchang Xiang. Enhanced C₂H₂/CO₂ separation in tetranuclear Cu(Ⅱ) cluster-based metal-organic frameworks by adjusting divider length of pore space partition[J]. Chinese Chemical Letters, ;2025, 36(3): 109672. doi: 10.1016/j.cclet.2024.109672 shu

Enhanced C₂H₂/CO₂ separation in tetranuclear Cu(Ⅱ) cluster-based metal-organic frameworks by adjusting divider length of pore space partition

Fahui Xiang ^{a, b, 1} ,
Lu Li ^{a, 1} ,
Zhen Yuan ^a ,
Wuji Wei ^a ,
Xiaoqing Zheng ^a ,
Shimin Chen ^a ,
Yisi Yang ^a ,
Liangji Chen ^a ,
Zizhu Yao ^a ,
Jianwei Fu ^b ,
Zhangjing Zhang ^{a, *,} ,
Shengchang Xiang ^{a, *,}

a.
Fujian Provincial Key Laboratory of Polymer Materials, College of Chemistry and Materials Science, Fujian Normal University Fuzhou 350108, China
b.
Institute of Quality Standards and Testing Technology for Agro-Products, Fujian Key Laboratory of Agro-Products Quality and Safety, Fujian Academy of Agricultural Sciences, Fuzhou 350001, China

zzhang@fjnu.edu.cn

scxiang@fjnu.edu.cn

Received Date: 24 December 2023
Revised Date: 8 February 2024
Accepted Date: 22 February 2024
Available Online: 8 March 2024

Figures(6)

Achieving efficient adsorption and separation of C₂H₂/CO₂ mixtures is a goal that people have always pursued to improve the situation of high energy consumption brought by traditional separation technologies in industry today. High-nuclearity metal cluster-based MOFs with different functionalities are promising for this separation, but it is a complicated and difficult task to precisely control their structures. The strategy of pore-space partition (PSP) is a powerful way to construct this type MOFs, which has the characteristic of isostructural relationship, and can be resulted in a similar performance for them. Therefore, it is an interesting work to explore the effect of MOFs property by adjusting the size of PSP dividers. Herein, three tetranuclear Cu(Ⅱ) cluster-based MOFs (FJU-112/113/114) with dual functionalities has been successfully obtained by PSP strategy with various lengths of divider units. With the highest microporosity and unique functional site, FJU-114 realized a good improvement in the adsorption and separation performance of C₂H₂/CO₂. The gas adsorption and lab-scale C₂H₂/CO₂ breakthrough experiments demonstrated that FJU-114 exhibits the highest adsorption uptake of 77 cm³/g for C₂H₂, and shows the best separation factor of 4.2 among three MOFs. The GCMC simulation reveals that a stronger adsorption binding site of C₂H₂ in FJU-114a located in the cage Ⅱ near the unchanged tetranuclear copper node, combined with its high microporosity to achieve the effect of dual functionalities for the improvement performance of C₂H₂ adsorption and separation.
- Metal-organic frameworks,
- Dual functionalities,
- Pore space partition,
- C₂H₂/CO₂ separation,
- Divider length adjustment
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Enhanced C2H2/CO2 separation in tetranuclear Cu(Ⅱ) cluster-based metal-organic frameworks by adjusting divider length of pore space partition

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通讯作者: 陈斌, bchen63@163.com

Enhanced C₂H₂/CO₂ separation in tetranuclear Cu(Ⅱ) cluster-based metal-organic frameworks by adjusting divider length of pore space partition