Citation: Guizhi Zhu, Junrui Tan, Longfei Tan, Qiong Wu, Xiangling Ren, Changhui Fu, Zhihui Chen, Xianwei Meng. Growth of CeCo-MOF in dendritic mesoporous organosilica as highly efficient antioxidant for enhanced thermal stability of silicone rubber[J]. Chinese Chemical Letters, ;2025, 36(1): 109669. doi: 10.1016/j.cclet.2024.109669 shu

Growth of CeCo-MOF in dendritic mesoporous organosilica as highly efficient antioxidant for enhanced thermal stability of silicone rubber

Guizhi Zhu ^{a, b} ,
Junrui Tan ^a ,
Longfei Tan ^{a, *,} ,
Qiong Wu ^a ,
Xiangling Ren ^a ,
Changhui Fu ^a ,
Zhihui Chen ^{b, *,} ,
Xianwei Meng ^{a, *,}

a.
State Key Laboratory of Cryogenic Science and Technology, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China
b.
School of Materials Science and Engineering, Changzhou University, Changzhou 213164, China

longfeitan@mail.ipc.ac.cn

czh@cczu.edu.cn

mengxw@mail.ipc.ac.cn

Received Date: 25 December 2023
Revised Date: 20 February 2024
Accepted Date: 22 February 2024
Available Online: 23 February 2024

Figures(5)

High-efficient rubber antioxidants for enhanced heat resistance without compromising mechanical properties remain an enormous and long-term challenge for the rubber industry. Herein, we employed the in-situ growth of Ce-doped Co-metal-organic framework (CeCo-MOF) in dendritic mesoporous organosilica nanoparticles (DMONs@CeCo-MOF, denoted as DCCM) to prepare a novel antioxidant that exhibit outstanding thermal stability. Dendritic mesoporous organosilica nanoparticles (DMONs) effectively alleviated the incompatibility of CeCo-MOF in the polymer matrix, and the effective scavenging of free radicals was attributed to the various oxidation states of metal ions in CeCo-MOF. Surprising, by adding only 0.5 phr (parts per hundred of rubber) of DMONs@CeCo-MOF to silicone rubber, (SR), the retention rate of tensile strength increased from 37.3% to 61.6% after aging 72 h at 250 ℃, and the retention rate of elongation at break of DCCM/SR1 composites reached 68%, which was 5.43 times of SR. The strategy of anchoring MOFs on the surface of silica also provides a viable method for preparing effective compound functionalized rubber antioxidant.
- Mesoporous organosilica nanoparticles,
- Silicone rubber,
- Metal-organic framework,
- Antioxidants,
- Thermal stability,
- Thermal oxidative degradation
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