Citation: Ruofan Yin, Zhaoxin Guo, Rui Liu, Xian-Sen Tao. Ultrafast synthesis of Na₃V₂(PO₄)₃ cathode for high performance sodium-ion batteries[J]. Chinese Chemical Letters, ;2025, 36(2): 109643. doi: 10.1016/j.cclet.2024.109643 shu

Ultrafast synthesis of Na₃V₂(PO₄)₃ cathode for high performance sodium-ion batteries

Ruofan Yin ^{a, 1} ,
Zhaoxin Guo ^{b, 1} ,
Rui Liu ^b ,
Xian-Sen Tao ^{a, *,}

a.
School of Chemistry, Chemical Engineering and Materials, Jining University, Qufu 273155, China
b.
School of Materials Science and Engineering, Shandong University of Science and Technology, Qingdao 266590, China

taoxsen@jnxy.edu.cn

Received Date: 1 January 2024
Revised Date: 23 January 2024
Accepted Date: 7 February 2024
Available Online: 12 February 2024

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Na₃V₂(PO₄)₃ (NVP) is regarded as alternative cathode material for sodium-ion batteries (SIBs) due to its potential high-rate performance and pronounced long-term cycle stability. However, electronic conductivity and tap density are difficult to be balanced. Herein, we report that high-temperature shock (HTS) can prepare "single crystalline like" NVP which combines high-rate capability with high tap density together into one with the assistance of carbon framework and large particle. Thus, high reversible capacity of 110 mAh/g at 0.1 C with 89.9% capacity retention after 1600 cycles at 1 C and specific capacity of 83.5 mAh/g at 50 C rate has been exhibited. This study provides a novel strategy to guide the production of high tap density, and rate performance polyanionic cathode materials.
- Sodium-ion batteries,
- Cathode materials,
- Na₃V₂(PO₄)₃,
- High-temperature shock,
- Cycling stability
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沈阳化工大学材料科学与工程学院沈阳 110142

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通讯作者: 陈斌, bchen63@163.com

Ultrafast synthesis of Na₃V₂(PO₄)₃ cathode for high performance sodium-ion batteries