Citation: Dongying Fu, Lin Pan, Yanli Ma, Yue Zhang. Bilayered Dion–Jacobson lead-iodine hybrid perovskite with aromatic spacer for broadband photodetection[J]. Chinese Chemical Letters, ;2025, 36(2): 109621. doi: 10.1016/j.cclet.2024.109621 shu

Bilayered Dion–Jacobson lead-iodine hybrid perovskite with aromatic spacer for broadband photodetection

Dongying Fu ^{a, b, *,} ,
Lin Pan ^a ,
Yanli Ma ^a ,
Yue Zhang ^a

a.
Institute of Crystalline Materials, Shanxi University, Taiyuan 030006, China
b.
State Key Laboratory of Quantum Optics and Quantum Optics Devices, Shanxi University, Taiyuan 030006, China

dyfu@sxu.edu.cn

Received Date: 9 January 2024
Revised Date: 30 January 2024
Accepted Date: 7 February 2024
Available Online: 9 February 2024

Figures(4)

Dion–Jacobson (DJ) phase hybrid perovskites have been proven to improve the photovoltaic performance of the devices due to its unique structure. At present, some DJ hybrid perovskites have been reported and used for photodetection filed, but most of them are based on lead-bromide systems, which is not conducive to construct broadband photodetection devices due to the limitation of intrinsic absorption. Herein, we constructed a bilayered DJ hybrid perovskite (3AMPY)(EA)Pb₂I₇ (3AMPY²⁺ is 3-(aminomethyl)pyridinium, EA⁺ is ethylammonium) using an aromatic spacer, which exhibit large current on/off ratios of ~10⁴ under 520 and 637 nm illumination. In particular, the single crystal device based on (3AMPY)(EA)Pb₂I₇ shows a distinguished detectivity of 7.4 × 10¹² Jones and a high responsivity of 0.89 A/W under 637 nm illumination. Such finding not only enriches the quantities of DJ hybrid perovskites, but also provides useful assistance for constructing high-performance optoelectronic device in the future.
- Dion–Jacobson,
- Hybrid perovskite,
- Aromatic spacer,
- Two-dimensional,
- Broadband photodetection
1. [1]
  F. Zhang, S.Y. Park, C. Yao, et al., Science 375 (2022) 71–76. doi: 10.1126/science.abj2637
2. [2]
  A. Dučinskas, G.Y. Kim, D. Moia, et al., ACS Energy Lett. 6 (2021) 337–344. doi: 10.1021/acsenergylett.0c02344
3. [3]
  C. Chen, X. Zhao, Y. Gong, et al., Chem. Mater. 35 (2023) 3265–3275. doi: 10.1021/acs.chemmater.3c00278
4. [4]
  X. Li, W. Ke, B. Traoré, et al., J. Am. Chem. Soc. 141 (2019) 12880–12890. doi: 10.1021/jacs.9b06398
5. [5]
  I.H. Park, K.C. Kwon, Z. Zhu, et al., J. Am. Chem. Soc. 142 (2020) 18592–18598. doi: 10.1021/jacs.0c08189
6. [6]
  Y. Liu, H. Zhou, Y. Ni, et al., Joule 7 (2023) 1016–1032. doi: 10.1016/j.joule.2023.03.010
7. [7]
  W. Guo, Z. Yang, J. Dan, M. Wang, Nano Energy 86 (2021) 106129. doi: 10.1016/j.nanoen.2021.106129
8. [8]
  L. Mao, P. Guo, M. Kepenekian, et al., J. Am. Chem. Soc. 142 (2020) 8342–8351. doi: 10.1021/jacs.0c01625
9. [9]
  W. He, Y. Yang, C. Li, et al., J. Am. Chem. Soc. 145 (2023) 14044–14051. doi: 10.1021/jacs.3c03921
10. [10]
  M. Guan, Y. Xie, Y. Zhang, et al., Adv. Mater. 35 (2023) 2210611. doi: 10.1002/adma.202210611
11. [11]
  J. Chen, Z. Zhai, Q. Liu, H. Zhou, Nanoscale Horiz. 8 (2023) 1628–1651. doi: 10.1039/D3NH00209H
12. [12]
  Q. Fan, Y. Ma, H. Xu, et al., Adv. Opt. Mater. 11 (2023) 2202277. doi: 10.1002/adom.202202277
13. [13]
  Y. Li, J.V. Milić, A. Ummadisingu, et al., Nano Lett. 19 (2019) 150–157. doi: 10.1021/acs.nanolett.8b03552
14. [14]
  R. Shi, Z. Zhang, W.H. Fang, R. Long, J. Mater. Chem. A 8 (2020) 9168–9176. doi: 10.1039/D0TA01944E
15. [15]
  Y. Fan, Q. Chen, Z. Li, et al., Small 19 (2023) 2303814. doi: 10.1002/smll.202303814
16. [16]
  H. Ye, Y. Peng, X. Shang, et al., Adv. Funct. Mater. 32 (2022) 2200223. doi: 10.1002/adfm.202200223
17. [17]
  K. Song, P. Zhou, L. Zong, et al., Chin. Chem. Lett. 34 (2023) 107464. doi: 10.1016/j.cclet.2022.04.062
18. [18]
  Z. Wei, Y. Zhao, J. Jiang, et al., Chin. Chem. Lett. 31 (2020) 3055–3064. doi: 10.1016/j.cclet.2020.05.016
19. [19]
  S. Yu, M. Abdellah, T. Pullerits, K. Zheng, Z. Liang, Adv. Funct. Mater. 31 (2021) 2104342. doi: 10.1002/adfm.202104342
20. [20]
  X. Zhang, T. Yang, X. Ren, Adv. Energy Mater. 11 (2021) 2002733. doi: 10.1002/aenm.202002733
21. [21]
  Z. Shi, Z. Ni, J. Huang, ACS Energy Lett. 7 (2022) 984–987. doi: 10.1021/acsenergylett.2c00098
22. [22]
  R. Zhao, R.P. Sabatini, T. Zhu, et al., J. Am. Chem. Soc. 143 (2021) 19901–19908. doi: 10.1021/jacs.1c09515
23. [23]
  A. Dučinskas, G.C. Fish, M.A. Hope, et al., J. Phys. Chem. Lett. 12 (2021) 10325–10332. doi: 10.1021/acs.jpclett.1c02937
24. [24]
  D. Fu, S. Wu, W. Cao, Z. Chen, X.M. Zhang, J. Mater. Chem. C 10 (2022) 9613–9620. doi: 10.1039/D2TC01623K
25. [25]
  L. Mao, W. Ke, L. Pedesseau, et al., J. Am. Chem. Soc. 140 (2018) 3775–3783. doi: 10.1021/jacs.8b00542
26. [26]
  S.A. Cuthriell, C.D. Malliakas, M.G. Kanatzidis, R.D. Schaller, J. Am. Chem. Soc. 145 (2023) 11710–11716. doi: 10.1021/jacs.3c02008
27. [27]
  D. Lu, G. Lv, Z. Xu, et al., J. Am. Chem. Soc. 142 (2020) 11114–11122. doi: 10.1021/jacs.0c03363
28. [28]
  A. Ummadisingu, A. Mishra, D.J. Kubicki, et al., Small 18 (2022) 2104287. doi: 10.1002/smll.202104287
29. [29]
  L. Gao, X. Li, B. Traoré, et al., J. Am. Chem. Soc. 143 (2021) 12063–12073. doi: 10.1021/jacs.1c03687
30. [30]
  Z. Fang, X. Hou, Y. Zheng, et al., Adv. Funct. Mater. 31 (2021) 2102330. doi: 10.1002/adfm.202102330
31. [31]
  P.S. Klee, Y. Hirano, D.B. Cordes, A.M.Z. Slawin, J.L. Payne, Cryst. Growth Des. 22 (2022) 3815–3823. doi: 10.1021/acs.cgd.2c00187
32. [32]
  D. Fu, W. Jia, S. Wu, et al., Chem. Mater. 35 (2023) 2541–2548. doi: 10.1021/acs.chemmater.2c03815
33. [33]
  L. Mao, Y. Wu, C.C. Stoumpos, M.R. Wasielewski, M.G. Kanatzidis, J. Am. Chem. Soc. 139 (2017) 5210–5215. doi: 10.1021/jacs.7b01312
34. [34]
  Y. Fu, X. Jiang, X. Li, et al., J. Am. Chem. Soc. 142 (2020) 4008–4021. doi: 10.1021/jacs.9b13587
35. [35]
  D. Fu, Z. Hou, Y. He, et al., ACS Appl. Mater. Interfaces 14 (2022) 11690–11698. doi: 10.1021/acsami.2c00806
36. [36]
  Z. Wang, X. Zhang, H. Ye, T. Zhu, J. Luo, Chem. Eur. J. 28 (2022) e202200849. doi: 10.1002/chem.202200849
37. [37]
  D. Fu, S. Wu, J. Xin, et al., Chem. Commun. 56 (2020) 14381–14384. doi: 10.1039/D0CC05679K
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