Citation: Zhong-Hui Sun, Yu-Qi Zhang, Zhen-Yi Gu, Dong-Yang Qu, Hong-Yu Guan, Xing-Long Wu. CoPSe nanoparticles confined in nitrogen-doped dual carbon network towards high-performance lithium/potassium ion batteries[J]. Chinese Chemical Letters, ;2025, 36(1): 109590. doi: 10.1016/j.cclet.2024.109590 shu

CoPSe nanoparticles confined in nitrogen-doped dual carbon network towards high-performance lithium/potassium ion batteries

Zhong-Hui Sun ^a ,
Yu-Qi Zhang ^a ,
Zhen-Yi Gu ^b ,
Dong-Yang Qu ^{a, *,} ,
Hong-Yu Guan ^{a, *,} ,
Xing-Long Wu ^{b, *,}

a.
Guangdong Engineering Technology Research Center for Photoelectric Sensing Materials and Devices, c/o School of Chemistry and Chemical Engineering, Guangzhou University, Guangzhou 510006, China
b.
MOE Key Laboratory for UV Light-Emitting Materials and Technology, Northeast Normal University, Changchun 130024, China

dyqu@gzhu.edu.cn

guanhy@gzhu.edu.cn

xinglong@nenu.edu.cn

Received Date: 6 December 2023
Revised Date: 19 January 2024
Accepted Date: 29 January 2024
Available Online: 4 February 2024

Figures(4)

The metal ion batteries have gained widespread attention for wearable electronics due to their competitive energy density and long cycling life. Exploring the advanced anode materials is significant for next generation energy storage systems. However, severe electrode volume changes and sluggish redox kinetics are the critical problems for lithium/potassium ion batteries (LIBs/PIBs) towards large-scale applications. Herein, we prepare a novel anode material, which consists of reduced graphene oxide wrapping one-dimensional (1D) N-doped porous carbon nanotube with cobalt phosphoselenide (CoPSe) nanoparticles embedded inside them (rGO@CoPSe/NC). Benefited from the dual carbon decorations and ultrafine nanoparticles structure, it achieves a reversible capacity of 245 mAh/g at 5 A/g after 2000 cycles for LIBs and 215 mAh/g at 1 A/g after 500 cycles for PIBs. The pseudocapacitance and GITT measurements are used to investigate the electrochemical kinetics of rGO@CoPSe/NC for LIBs. In addition, the lithium ion full cell also shows good electrochemical performance when paired with high capacity LiNi_0.8Co_0.1Mn_0.1O₂ cathode. This work provides a feasible electrode design strategy for high-efficiency metal ion batteries based on multidimensional nanoarchitecture engineering and composition tailoring.
- Cobalt phosphoselenide,
- Lithium-ion batteries,
- Potassium-ion batteries,
- Reduced graphene oxide,
- Structural stability,
- Full cell
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