Citation: Ying-Yu Zhang, Jia-Qi Luo, Yan Han, Wan-Ying Zhang, Yi Zhang, Hai-Feng Lu, Da-Wei Fu. Bistable switch molecule DPACdCl₄ showing four physical channels and high phase transition temperature[J]. Chinese Chemical Letters, ;2025, 36(1): 109530. doi: 10.1016/j.cclet.2024.109530 shu

Bistable switch molecule DPACdCl₄ showing four physical channels and high phase transition temperature

Ying-Yu Zhang ^{a, 1} ,
Jia-Qi Luo ^{a, 1} ,
Yan Han ^a ,
Wan-Ying Zhang ^{a, b} ,
Yi Zhang ^a ,
Hai-Feng Lu ^{a, *,} ,
Da-Wei Fu ^{a, b, *,}

a.
Institute for Science and Applications of Molecular Ferroelectrics, Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Zhejiang Normal University, Jinhua 321004, China
b.
Ordered Matter Science Research Center, Jiangsu Key Laboratory for Science and applications of Molecular Ferroelectrics, Southeast University, Nanjing 211189, China

luhaifeng@zjnu.edu.cn

dawei@seu.edu.cn

Received Date: 17 October 2023
Revised Date: 11 December 2023
Accepted Date: 17 January 2024
Available Online: 23 January 2024

Figures(6)

Multiple switchable physical channels within one material or device, encompassing optical, electrical, thermal, and mechanical pathways, can enable multifunctionality in mechanical-thermal-opto-electronic applications. Achieving integrated encryption and enhanced performance in storage and sensing presents a formidable challenge in the synthesis and functionality of new materials. In an effort to overcome the complexities associated with these multiple physical functions, this study investigates the large-size crystal of DPACdCl₄ (DPA = diisopropylammonium), revealing significant features in rare multi-channel switches. This compound demonstrates the ability to switch between "OFF/0" and "ON/1" states in the mechanical-thermal-opto-electronic channels. Consequently, DPACdCl₄ possesses four switchable physical channels, characterized by a higher phase transition temperature of 440.7 K and a competitive piezoelectric coefficient of 46 pC/N. Furthermore, solid-state NMR analysis indicates that thermally activated molecular vibrations significantly contribute to its multifunctional switching capabilities.
- Organic-inorganic hybrid,
- Phase transition,
- Crystal,
- Perovskite,
- Piezoelectricity
1. [1]
  M. Liu, Z.Y. Zhou, T.X. Nan, et al., Adv. Mater. 25 (2013) 1435–1439. doi: 10.1002/adma.201203792
2. [2]
  B.B. Mukherjee, S.K. Batabyal, A.J. Pal, Adv. Mater. 19 (2007) 717–722. doi: 10.1002/adma.200601490
3. [3]
  D.W. Fu, H.L. Cai, Y. Liu, et al., Science 339 (2013) 425–428. doi: 10.1126/science.1229675
4. [4]
  Y. Zhang, H.Y. Ye, H.L. Cai, et al., Adv. Mater. 26 (2014) 4515–4520. doi: 10.1002/adma.201400806
5. [5]
  W. Li, A. Thirumurugan, P.T. Barton, et al., J. Am. Chem. Soc. 136 (2014) 7801–7804. doi: 10.1021/ja500618z
6. [6]
  A. Piecha-Bisiorek, A. Bialonska, R. Jakubas, et al., Adv. Mater. 27 (2015) 5023–5027. doi: 10.1002/adma.201501812
7. [7]
  Y. Zhang, H.Y. Ye, D.W. Fu, et al., Angew. Chem. Int. Ed. 53 (2014) 2114–2118. doi: 10.1002/anie.201307690
8. [8]
  D.Y. Wang, D.Z. Zhang, P. Li, et al., Nano-Micro Lett. 13 (2021) 57. doi: 10.1007/s40820-020-00580-5
9. [9]
  J. Long, J. Rouquette, J.M. Thibaud, et al., Angew. Chem. Int. Ed. 54 (2015) 2236–2240. doi: 10.1002/anie.201410523
10. [10]
  S. Horiuchi, Y. Tokunaga, G. Giovannetti, et al., Nature 463 (2010) 789–792. doi: 10.1038/nature08731
11. [11]
  H. Xu, R. Chen, Q. Sun, et al., Chem. Soc. Rev. 43 (2014) 3259–3302. doi: 10.1039/C3CS60449G
12. [12]
  S. Horiuchi, R. Kumai, Y. Tokunaga, et al., J. Am. Chem. Soc. 130 (2008) 13382–13391. doi: 10.1021/ja8032235
13. [13]
  H.Y. Ye, S.H. Li, Y. Zhang, et al., J. Am. Chem. Soc. 136 (2014) 10033–10040. doi: 10.1021/ja503344b
14. [14]
  A. Katrusiak, M. Szafranski, J. Am. Chem. Soc. 128 (2006) 15775–15785. doi: 10.1021/ja0650192
15. [15]
  P. Serra-Crespo, M.A. Veen, E. Gobechiya, et al., J. Am. Chem. Soc. 134 (2012) 8314–8317. doi: 10.1021/ja300655f
16. [16]
  J. Boixel, V. Guerchais, H.L. Bozec, et al., J. Am. Chem. Soc. 136 (2014) 5367–5375. doi: 10.1021/ja4131615
17. [17]
  X. Dong, J. Liang, Z. Xu, et al., Chin. Chem. Lett. 35 (2024) 108708. doi: 10.1016/j.cclet.2023.108708
18. [18]
  X. Zhang, Y. Yao, L. Liang, et al., Angew. Chem. Int. Ed. 61 (2022) e202205939. doi: 10.1002/anie.202205939
19. [19]
  G. Teri, Q.Q. Jia, H.F. Ni, et al., Dalton Trans. 52 (2023) 1074–1081. doi: 10.1039/D2DT04014J
20. [20]
  Y. Zhou, Y. Li, Q. Ding, et al., Chin. Chem. Lett. 32 (2021) 263–265. doi: 10.1016/j.cclet.2020.11.014
21. [21]
  L.X. Zhang, L.Y. Mei, K.Y. Wang, et al., Nano-Micro Lett. 15 (2023) 177. doi: 10.1007/s40820-023-01140-3
22. [22]
  D.X. Liu, H.L. Zhu, W.X. Zhang, et al., Angew. Chem. Int. Ed. 62 (2023) e202218902. doi: 10.1002/anie.202218902
23. [23]
  M.M. Lun, J.Q. Luo, Z.X. Zhang, et al., Chem. Eng. J. 475 (2023) 145969. doi: 10.1016/j.cej.2023.145969
24. [24]
  Y.Y. Yu, P.Z. Huang, Y.Z. Wang, et al., Chin. Chem. Lett. 32 (2021) 3558–3561. doi: 10.1016/j.cclet.2021.02.040
25. [25]
  R.G. Xiong, S.Q. Lu, Z.X. Zhang, et al., Angew. Chem. Int. Ed. 59 (2020) 9574–9578. doi: 10.1002/anie.202000290
26. [26]
  J.Y. Li, T. Zhang, M.M. Lun, et al., Small 19 (2023) 2301364. doi: 10.1002/smll.202301364
27. [27]
  M.M. Lun, C.Y. Su, J. Li, et al., Small 19 (2023) 2303127. doi: 10.1002/smll.202303127
28. [28]
  K. Ding, H.S. Ye, C.Y. Su, et al., Nat. Commun. 14 (2023) 2863. doi: 10.1038/s41467-023-38590-7
29. [29]
  M.M. Lun, H.F. Ni, Z.X. Zhang, et al., Angew. Chem. Int. Ed. 63 (2024) e202313590. doi: 10.1002/anie.202313590
30. [30]
  G. Teri, Q.Q. Jia, Q. Guo, et al., Sci. China Mater. 66 (2023) 3687–3695. doi: 10.1007/s40843-023-2499-x
31. [31]
  H.F. Ni, L.K. Ye, P.C. Zhuge, et al., Chem. Sci. 14 (2023) 1781–1786. doi: 10.1039/D2SC05857J
32. [32]
  D.Y. Fu, Y.L. Ma, C.Y. Su, et al., J. Mater. Chem. C 11 (2023) 11492–11499. doi: 10.1039/D3TC01926H
33. [33]
  J.Q. Wang, G. Teri, H.F. Ni, et al., Inorg. Chem. Front. 10 (2023) 3860–3866. doi: 10.1039/D3QI00594A
34. [34]
  G. Teri, H.F. Ni, Q.F. Luo, et al., Mater. Chem. Front. 7 (2023) 2235–2240. doi: 10.1039/D3QM00105A
35. [35]
  L.P. Miao, N. Ding, N. Wang, et al., Nat. Mater. 21 (2022) 1158–1164. doi: 10.1038/s41563-022-01322-1
36. [36]
  Y.M. You, W.Q. Liao, D.W. Zhao, et al., Science 357 (2017) 306–309. doi: 10.1126/science.aai8535
37. [37]
  H.Y. Ye, Y.Y. Tang, P.F. Li, et al., Science 361 (2018) 151–155. doi: 10.1126/science.aas9330
38. [38]
  H.Y. Zhang, H.H. Jiang, Y. Zhang, et al., Angew. Chem. Int. Ed. 61 (2022) e202200135. doi: 10.1002/anie.202200135
39. [39]
  T. Zhang, K. Xu, J. Li, et al., Natl. Sci. Rev. 10 (2023) nwac240. doi: 10.1093/nsr/nwac240
40. [40]
  N. Zhang, W.C. Sun, Y. Zhang, et al., Nat. Commun. 14 (2023) 5854. doi: 10.1038/s41467-023-41560-8
41. [41]
  Y.Y. Fan, S.Q. Deng, T.Y. Li, et al., Chin. Chem. Lett. 34 (2023) 107796. doi: 10.1016/j.cclet.2022.107796
42. [42]
  H. Peng, Z.K. Xu, Y. Du, et al., Angew. Chem. Int. Ed. 62 (2023) e20230673.
43. [43]
  J.C. Liu, Y.H. Ai, Q. Liu, et al., Adv. Mater. 35 (2023) 2302436. doi: 10.1002/adma.202302436
44. [44]
  H. Peng, Q. Liu, Y. Liu, et al., Chin. Chem. Lett. 34 (2023) 107980. doi: 10.1016/j.cclet.2022.107980
45. [45]
  M. Rok, P. Starynowicz, A. Ciżman, et al., Inorg. Chem. 59 (2020) 11986–11994. doi: 10.1021/acs.inorgchem.0c00830
46. [46]
  B. Gao, H. Qi, H. Liu, et al., Chin. Chem. Lett. 35 (2024) 108598. doi: 10.1016/j.cclet.2023.108598
47. [47]
  S.A. Wolf, D.D. Awschalom, D.D. Buhrman, et al., Science 294 (2001) 1488–1495. doi: 10.1126/science.1065389
48. [48]
  M. Mączka, J.-K. Zaręba, A. Gągor, et al., Chem. Mater. 33 (2021) 2331–2342. doi: 10.1021/acs.chemmater.0c04440
49. [49]
  K. Mencel, V. Kinzhybalo, R. Jakubas, et al., Chem. Mater. 33 (2021) 8591–8601. doi: 10.1021/acs.chemmater.1c01266
50. [50]
  Y.J. Zhao, X. Yin, P.W. Li, et al., Nano-Micro Lett. 15 (2023) 187. doi: 10.1007/s40820-023-01161-y
51. [51]
  M. Szafranski, A. Katrusiak, K. Stahl, et al., J. Mater. Chem. A 9 (2021) 10769–10779. doi: 10.1039/D1TA01875B
52. [52]
  M. A. Nowok, J.K. Zarȩba, et al., ACS Appl. Mater. Interface 14 (2022) 1460–1471.
53. [53]
  Q.Q. Jia, T. Shao, L. Tong, et al., Chin. Chem. Lett. 34 (2023) 107539. doi: 10.1016/j.cclet.2022.05.053
54. [54]
  Q.Q. Jia, H.F. Lu, J.Q. Luo, et al., Small 20 (2024) 2306989. doi: 10.1002/smll.202306989
55. [55]
  T. Yang, Y. Liu, L. Hua, et al., Chin. Chem. Lett. 35 (2024) 108707. doi: 10.1016/j.cclet.2023.108707
56. [56]
  S.N. Du, D. Su, Z.Y. Ruan, et al., Angew. Chem. Int. Ed. 61 (2022) e202204700. doi: 10.1002/anie.202204700
57. [57]
  M. Mączka, J.K. Zaręba, A. Gągor, et al., Chem. Mater. 33 (2021) 2331–2342. doi: 10.1021/acs.chemmater.0c04440
58. [58]
  J.J. Liang, S.J. Wang, Z. Luo, et al., Nano-Micro Lett. 15 (2023) 5. doi: 10.1007/s40820-022-00978-3
1. [1]
  Zhi-Yuan Yue , Hua-Kai Li , Na Wang , Shan-Shan Liu , Le-Ping Miao , Heng-Yun Ye , Chao Shi . Dehydration-triggered structural phase transition-associated ferroelectricity in a hybrid perovskite-type crystal. Chinese Chemical Letters, 2024, 35(10): 109355-. doi: 10.1016/j.cclet.2023.109355
2. [2]
  Wenli Xu , Yingzhao Zhang , Rui Wang , Chenyang Liu , Jialin Liu , Xiangyu Huo , Xinying Liu , He Zhang , Jianxu Ding . In-situ passivating surface defects of ultra-thin MAPbBr3 perovskite single crystal films for high performance photodetectors. Chinese Journal of Structural Chemistry, 2025, 44(1): 100454-100454. doi: 10.1016/j.cjsc.2024.100454
3. [3]
  Tian Yang , Yi Liu , Lina Hua , Yaoyao Chen , Wuqian Guo , Haojie Xu , Xi Zeng , Changhao Gao , Wenjing Li , Junhua Luo , Zhihua Sun . Lead-free hybrid two-dimensional double perovskite with switchable dielectric phase transition. Chinese Chemical Letters, 2024, 35(6): 108707-. doi: 10.1016/j.cclet.2023.108707
4. [4]
  Zhaohong Chen , Mengzhen Li , Jinfei Lan , Shengqian Hu , Xiaogang Chen . Organic ferroelastic enantiomers with high T_c and large dielectric switching ratio triggered by order-disorder and displacive phase transition. Chinese Chemical Letters, 2024, 35(10): 109548-. doi: 10.1016/j.cclet.2024.109548
5. [5]
  Pu Zhang , Xiang Mao , Xuehua Dong , Ling Huang , Liling Cao , Daojiang Gao , Guohong Zou . Two UV organic-inorganic hybrid antimony-based materials with superior optical performance derived from cation-anion synergetic interactions. Chinese Chemical Letters, 2024, 35(9): 109235-. doi: 10.1016/j.cclet.2023.109235
6. [6]
  Mao-Fan Li , Ming‐Yu Guo , De-Xuan Liu , Xiao-Xian Chen , Wei-Jian Xu , Wei-Xiong Zhang . Multi-stimuli responsive behaviors in a new chiral hybrid nitroprusside salt (R-3-hydroxypyrrolidinium)₂[Fe(CN)₅(NO)]. Chinese Chemical Letters, 2024, 35(12): 109507-. doi: 10.1016/j.cclet.2024.109507
7. [7]
  Xin Dong , Jing Liang , Zhijin Xu , Huajie Wu , Lei Wang , Shihai You , Junhua Luo , Lina Li . Exploring centimeter-sized crystals of bismuth-iodide perovskite toward highly sensitive X-ray detection. Chinese Chemical Letters, 2024, 35(6): 108708-. doi: 10.1016/j.cclet.2023.108708
8. [8]
  Le Ye , Wei-Xiong Zhang . Structural phase transition in a new organic-inorganic hybrid post-perovskite: (N,N-dimethylpyrrolidinium)[Mn(N(CN)2)3]. Chinese Journal of Structural Chemistry, 2024, 43(6): 100257-100257. doi: 10.1016/j.cjsc.2024.100257
9. [9]
  Shengyu Zhao , Qinhao Shi , Wuliang Feng , Yang Liu , Xinxin Yang , Xingli Zou , Xionggang Lu , Yufeng Zhao . Suppression of multistep phase transitions of O3-type cathode for sodium-ion batteries. Chinese Chemical Letters, 2024, 35(5): 108606-. doi: 10.1016/j.cclet.2023.108606
10. [10]
  Botao Gao , He Qi , Hui Liu , Jun Chen . Role of polarization evolution in the hysteresis effect of Pb-based antiferroelecrtics. Chinese Chemical Letters, 2024, 35(4): 108598-. doi: 10.1016/j.cclet.2023.108598
11. [11]
  Keke Han , Wenjun Rao , Xiuli You , Haina Zhang , Xing Ye , Zhenhong Wei , Hu Cai . Two new high-temperature molecular ferroelectrics [1,5-3.2.2-Hdabcni]X (X = ClO₄⁻, ReO₄⁻). Chinese Chemical Letters, 2024, 35(6): 108809-. doi: 10.1016/j.cclet.2023.108809
12. [12]
  Shengyu Zhao , Xuan Yu , Yufeng Zhao . A water-stable high-voltage P3-type cathode for sodium-ion batteries. Chinese Chemical Letters, 2024, 35(9): 109933-. doi: 10.1016/j.cclet.2024.109933
13. [13]
  Kailong Zhang , Chao Zhang , Luanhui Wu , Qidong Yang , Jiadong Zhang , Guang Hu , Liang Song , Gaoran Li , Wenlong Cai . Chloride molten salt derived attapulgite with ground-breaking electrochemical performance. Chinese Chemical Letters, 2024, 35(10): 109618-. doi: 10.1016/j.cclet.2024.109618
14. [14]
  Kangrong Yan , Ziqiu Shen , Yanchun Huang , Benfang Niu , Hongzheng Chen , Chang-Zhi Li . Curing the vulnerable heterointerface via organic-inorganic hybrid hole transporting bilayers for efficient inverted perovskite solar cells. Chinese Chemical Letters, 2024, 35(6): 109516-. doi: 10.1016/j.cclet.2024.109516
15. [15]
  Na Wang , Wang Luo , Huaiyi Shen , Huakai Li , Zejiang Xu , Zhiyuan Yue , Chao Shi , Hengyun Ye , Leping Miao . Crystal engineering regulation achieving inverse temperature symmetry breaking ferroelasticity in a cationic displacement type hybrid perovskite system. Chinese Chemical Letters, 2024, 35(5): 108696-. doi: 10.1016/j.cclet.2023.108696
16. [16]
  Zhuoer Cai , Yinan Zhang , Xiu-Ni Hua , Baiwang Sun . Phase transition arising from order-disorder motion in stable layered two-dimensional perovskite. Chinese Journal of Structural Chemistry, 2024, 43(11): 100426-100426. doi: 10.1016/j.cjsc.2024.100426
17. [17]
  Yan Cheng , Hai-Quan Yao , Ya-Di Zhang , Chao Shi , Heng-Yun Ye , Na Wang . Nitrate-bridged hybrid organic-inorganic perovskites. Chinese Journal of Structural Chemistry, 2024, 43(9): 100358-100358. doi: 10.1016/j.cjsc.2024.100358
18. [18]
  Ting Shi , Ziyang Song , Yaokang Lv , Dazhang Zhu , Ling Miao , Lihua Gan , Mingxian Liu . Hierarchical porous carbon guided by constructing organic-inorganic interpenetrating polymer networks to facilitate performance of zinc hybrid supercapacitors. Chinese Chemical Letters, 2025, 36(1): 109559-. doi: 10.1016/j.cclet.2024.109559
19. [19]
  Ce Liang , Qiuhui Sun , Adel Al-Salihy , Mengxin Chen , Ping Xu . Recent advances in crystal phase induced surface-enhanced Raman scattering. Chinese Chemical Letters, 2024, 35(9): 109306-. doi: 10.1016/j.cclet.2023.109306
20. [20]
  Jiakun Bai , Junhui Jia , Aisen Li . An elastic organic crystal with piezochromic luminescent behavior. Chinese Journal of Structural Chemistry, 2024, 43(6): 100323-100323. doi: 10.1016/j.cjsc.2024.100323

Get Citation

PDF

XML

Metrics

PDF Downloads(10)
Abstract views(178)
HTML views(13)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Bistable switch molecule DPACdCl4 showing four physical channels and high phase transition temperature

Metrics

通讯作者: 陈斌, bchen63@163.com

Bistable switch molecule DPACdCl₄ showing four physical channels and high phase transition temperature