Citation: Kangrong Yan, Ziqiu Shen, Yanchun Huang, Benfang Niu, Hongzheng Chen, Chang-Zhi Li. Curing the vulnerable heterointerface via organic-inorganic hybrid hole transporting bilayers for efficient inverted perovskite solar cells[J]. Chinese Chemical Letters, ;2024, 35(6): 109516. doi: 10.1016/j.cclet.2024.109516 shu

Curing the vulnerable heterointerface via organic-inorganic hybrid hole transporting bilayers for efficient inverted perovskite solar cells

State Key Laboratory of Silicon and Advanced Semiconductor Materials, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China

czli@zju.edu.cn

Received Date: 27 October 2023
Revised Date: 4 January 2024
Accepted Date: 5 January 2024
Available Online: 12 January 2024

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To promote the practices of perovskite photovoltaics, it requires to develop efficient perovskite solar cells (PVSCs) standing long-time operation under the adverse environments. Herein, we demonstrate that the tailor-made conjugated polymers as conductive adhesives stabilized the originally redox-reactive heterointerface between perovskite and metal oxide, facilitating the access of efficient and stable inverted PVSCs. It was revealed that bithiophene and phenyl alternating conjugated polymers with partial glycol chains atop of the metal oxide layer has resulted in effective organic-inorganic hybrid hole transporting bilayers, which allow maintaining efficient hole extraction and transport, meanwhile preventing halide migration to directly contact with the nickel oxide (NiO_x) layer. As a result, the corresponding inverted PVSCs with the organic-inorganic hole transporting bilayers have achieved an excellent power conversion efficiency of 23.22%, outperforming 20.65% of bare NiO_x-based devices. Moreover, the encapsulated PVSCs with organic-inorganic bilayers exhibited the excellent photostability with 91% of the initial efficiency after 1000-h one-sun equivalent illumination in ambient conditions. Overall, this work provides new insights into stabilizing the vulnerable heterointerface for perovskite solar cells.
- Perovskite solar cells,
- Conjugated polymer,
- Hole transporting bilayer,
- Charge extraction,
- Heterointerface degradation
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