Citation: Lei Zhou, Youjun Zhou, Lizhen Fang, Yiqiao Bai, Yujia Meng, Liang Li, Jie Yang, Yong Yao. Pillar[5]arene based artificial light-harvesting supramolecular polymer for efficient and recyclable photocatalytic applications[J]. Chinese Chemical Letters, ;2024, 35(9): 109509. doi: 10.1016/j.cclet.2024.109509 shu

Pillar[5]arene based artificial light-harvesting supramolecular polymer for efficient and recyclable photocatalytic applications

Lei Zhou ^{a, b, 1} ,
Youjun Zhou ^{b, 1} ,
Lizhen Fang ^{a, b, 1} ,
Yiqiao Bai ^b ,
Yujia Meng ^b ,
Liang Li ^{a, *,} ,
Jie Yang ^{c, *,} ,
Yong Yao ^{b, *,}

a.
School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 201418, China
b.
School of Chemistry and Chemical Engineering, Nantong City Key Laboratory of Life-Organic Chemistry, Nantong University, Nantong 226019, China
c.
College of Science, Nanjing Forestry University, Nanjing 210037, China

lilianglcx@sit.edu.cn

jieyang@njfu.edu.cn

yaoyong1986@ntu.edu.cn

Received Date: 15 November 2023
Revised Date: 2 January 2024
Accepted Date: 10 January 2024
Available Online: 15 January 2024

Figures(5)

Photosynthesis is the process through which living plants utilize photosynthetic pigments, such as chlorophyll, to convert CO₂ and water into organic compounds and release O₂ under visible light. In this study, we have successfully constructed a fluorescent supramolecular polymer (P5Py₂/Zn/Gen)n by employing orthogonal pillar[5]arene-based molecular recognition and metal ion coordination. Within the supramolecular polymer, the guest molecule Gen unit acts as a light-harvesting moiety, as the ACQ effect is inhibited by host-guest interactions, while the (Py)₂/Zn center serves as a catalytic site. By employing this orthogonal self-assembly strategy, we have enhanced the stability of both the donor and acceptor in catalyzing the reduction of p-nitrophenol to p-aminophenol. Moreover, this photocatalyst can be reused at least 5 times without significant conversion loss. These findings provide a pathway for constructing a recyclable artificial LHS that mimics the entire photosynthesis process.
- Pillar[5]arenes,
- Light-harvest,
- Supramolecular polymer,
- Photosynthesis,
- Orthogonal self-assembly
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