Citation: Juanjuan Wang, Fang Wang, Bin Qin, Yue Wu, Huan Yang, Xiaolong Li, Lanfang Wang, Xiufang Qin, Xiaohong Xu. Controlled synthesis and excellent magnetism of ferrimagnetic NiFe₂Se₄ nanostructures[J]. Chinese Chemical Letters, ;2024, 35(11): 109449. doi: 10.1016/j.cclet.2023.109449 shu

Controlled synthesis and excellent magnetism of ferrimagnetic NiFe₂Se₄ nanostructures

Juanjuan Wang ^{a, b, c} ,
Fang Wang ^{a, c, *,} ,
Bin Qin ^{a, c} ,
Yue Wu ^{a, c} ,
Huan Yang ^{a, c} ,
Xiaolong Li ^{a, c} ,
Lanfang Wang ^{a, c} ,
Xiufang Qin ^{a, c} ,
Xiaohong Xu ^{a, c, *,}

a.
Key Laboratory of Magnetic Molecules and Magnetic Information Materials of Ministry of Education & School of Chemistry and Materials Science of Shanxi Normal University, Taiyuan 030032, China
b.
Department of Chemistry & Chemical Engineering, Lyuliang University, Lishi 033001, China
c.
Collaborative Innovation Center for Advanced Permanent Magnetic Materials and Technology of Ministry of Education & Research Institute of Materials Science of Shanxi Normal University, Taiyuan 030032, China

wangfanghc@sxnu.edu.cn

xuxh@sxnu.edu.cn

Received Date: 25 October 2023
Revised Date: 23 November 2023
Accepted Date: 20 December 2023
Available Online: 23 December 2023

Figures(5)

3d transition metal chalcogenides have attracted much attention due to their unique magnetic properties. Although various Cr, V, and Fe-based chalcogenides have been fabricated recently, the limited Curie temperature (T_C) still hinders their practical application. Based on the structural and magnetic advantages of MFe₂O₄ and Fe₃Se₄, we developed a one-pot solution synthesis method for the fabrication of NiFe₂Se₄ nanostructures with structural continuity, to facilitate the investigation of their magnetic properties. Notably, the morphology of NiFe₂Se₄ can be controlled from nano-rods to nano-platelets by controlling the growth direction. The coercivity (H_C) of NiFe₂Se₄ with nano-cactus structure exhibits a maximum of 12.77 kOe at 5 K. The coercivity of ferrimagnetic NiFe₂Se₄ nano-platelets can be further adjusted to 1.52 kOe at room temperature. These results show that the magnetic properties of NiFe₂Se₄ can be significantly modified by controlling their morphologies. We also extend the method to the synthesis of CoFe₂Se₄ nano-cactus with an ultrahigh coercivity of 17.85 kOe at 5 K. Obviously, the synthesis strategy and their excellent magnetic properties of MFe₂Se₄ have sparked interest in ternary transition metal selenides as potential hard magnetic materials.
- Transition metal selenides,
- Hard magnetic materials,
- NiFe₂Se₄,
- Ferrimagnetic,
- Solution-process
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Controlled synthesis and excellent magnetism of ferrimagnetic NiFe₂Se₄ nanostructures