Citation: Xingang Kong, Yabei Su, Cuijuan Xing, Weijie Cheng, Jianfeng Huang, Lifeng Zhang, Haibo Ouyang, Qi Feng. Facile synthesis of porous TiO₂/SnO₂ nanocomposite as lithium ion battery anode with enhanced cycling stability via nanoconfinement effect[J]. Chinese Chemical Letters, ;2024, 35(11): 109428. doi: 10.1016/j.cclet.2023.109428 shu

Facile synthesis of porous TiO₂/SnO₂ nanocomposite as lithium ion battery anode with enhanced cycling stability via nanoconfinement effect

a.
School of Materials Science and Engineering, Shaanxi University of Science and Technology, Xi'an 710021, China
b.
College of Chemistry and Chemical Engineering, Xingtai University, Xingtai 054001, China

yezhu_1983@163.com

Received Date: 12 November 2023
Revised Date: 6 December 2023
Accepted Date: 19 December 2023
Available Online: 24 December 2023

Figures(7)

SnO₂ is a potential anode material with high theoretical capacity for lithium-ion batteries (LIBs), however, its applications have been limited by the severe volume expansion during charging-discharging process. In this work, an inverse opal TiO₂/SnO₂ composite with an interconnect network nanostructure was designed to confine SnO₂ nanoparticles in the porous TiO₂. Due to this nanoconfinement structure, the volume expansion in the process was effectively alleviated, therefore the safety performance and cycling stability of the battery were effectively improved. At the same time, with a large number of microporous structures in the framework, the appearance of pseudocapacitance improves the rate performance and reversible capacity. In terms of electrochemical kinetics, its framework provides the connected path for charge migration, effectively reducing the charge transfer impedance, meanwhile, quantities of micropores in its skeleton could provide a smoother channel for lithium ions, thus greatly improving the diffusion rate of LIBs. The design of this nanostructure provides a new idea for the research of SnO₂-based anode with effectively enhanced electrochemical performance, which is promising anode for practical application.
- Inverse opal TiO₂/SnO₂,
- Nanoconfinement,
- Lithium-ion batteries,
- Stability,
- Pseudocapacitance
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沈阳化工大学材料科学与工程学院沈阳 110142

Facile synthesis of porous TiO2/SnO2 nanocomposite as lithium ion battery anode with enhanced cycling stability via nanoconfinement effect

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通讯作者: 陈斌, bchen63@163.com

Facile synthesis of porous TiO₂/SnO₂ nanocomposite as lithium ion battery anode with enhanced cycling stability via nanoconfinement effect