Citation: Lei Wang, Jun-Jie Wu, Chang-Cun Yan, Wan-Ying Yang, Zong-Lu Che, Xin-Yu Xia, Xue-Dong Wang, Liang-Sheng Liao. Near-infrared organic lasers with ultra-broad emission bands by simultaneously harnessing four-level and six-level systems[J]. Chinese Chemical Letters, ;2024, 35(8): 109365. doi: 10.1016/j.cclet.2023.109365 shu

Near-infrared organic lasers with ultra-broad emission bands by simultaneously harnessing four-level and six-level systems

Lei Wang ^a ,
Jun-Jie Wu ^a ,
Chang-Cun Yan ^{b, *,} ,
Wan-Ying Yang ^a ,
Zong-Lu Che ^a ,
Xin-Yu Xia ^a ,
Xue-Dong Wang ^{a, **,} ,
Liang-Sheng Liao ^{a, c, **,}

a.
Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Institute of Functional Nano & Soft Materials (FUNSOM), Soochow University, Suzhou 215123, China
b.
Jiangsu Engineering Laboratory of Novel Functional Polymeric Materials, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China
c.
Macao Institute of Materials Science and Engineering, Macau University of Science and Technology, Macau SAR 999078, China

^**

cyan@suda.edu.cn

wangxuedong@suda.edu.cn

lsliao@suda.edu.cn

Received Date: 26 September 2023
Revised Date: 24 November 2023
Accepted Date: 3 December 2023
Available Online: 5 December 2023

Figures(6)

Organic lasers with broad emission bands in near-infrared (NIR) region are crucial for their applications in laser communication, night-vision as well as bioimaging owing to the abundance of selectable lasing wavelengths. However, for most organic gain materials, gain regions are limited in a small wavelength range because of the fixed energy level systems. Herein, we design a strategy to realize NIR organic lasers with broad emission bands based on tunable energy level systems induced by cascaded excited-state intramolecular proton transfer (ESIPT). A novel gain material named DHNN was developed, which can undergo a cascaded double-ESIPT process supporting four-level and six-level systems simultaneously. By doping DHNN into polystyrene microspheres, NIR lasers with tunable emission bands can be achieved based on the careful modulation of microcavities. Finally, organic lasers with an ultra-broad emission band ranging from 700 nm to 900 nm was successfully achieved by harnessing four-level and six-level systems simultaneously.
- Excited-state intramolecular proton transfer,
- Organic solid-state laser,
- Wide gain interval,
- Near-infrared emission,
- Molecular design
1. [1]
  T.H. Maiman, Nature 187 (1960) 493–494. doi: 10.1038/187493a0
2. [2]
  M.D. McGehee, A.J. Heeger, Adv. Mater. 12 (2000) 1655–1668. doi: 10.1002/1521-4095(200011)12:22<1655::AID-ADMA1655>3.0.CO;2-2
3. [3]
  S. Singh, V.R. Kanetkar, G. Sridhar, V. Muthuswamy, K. Raja, J. Lumin. 101 (2003) 285–291. doi: 10.1016/S0022-2313(02)00571-9
4. [4]
  I.D.W. Samuel, G.A. Turnbull, Chem. Rev. 107 (2007) 1272–1295. doi: 10.1021/cr050152i
5. [5]
  C. Grivas, M. Pollnau, Laser Photonics Rev. 6 (2012) 419–462. doi: 10.1002/lpor.201100034
6. [6]
  M.T. Hill, M.C. Gather, Nat. Photonics 8 (2014) 908–918. doi: 10.1038/nphoton.2014.239
7. [7]
  R.M. Ma, R.F. Oulton, Nat. Nanotechnol. 14 (2019) 12–22. doi: 10.1038/s41565-018-0320-y
8. [8]
  J.J. Wu, H.F. Gao, R. Lai, et al., Matter 2 (2020) 1233–1243. doi: 10.1016/j.matt.2020.01.023
9. [9]
  C.C. Yan, X.D. Wang, L.S. Liao, ACS Photonics 7 (2020) 1355–1366. doi: 10.1021/acsphotonics.0c00407
10. [10]
  J.J. Wu, M.P. Zhuo, R. Lai, et al., Angew. Chem. Int. Ed. 60 (2021) 9114–9119. doi: 10.1002/anie.202016786
11. [11]
  C.C. Yan, Y.P. Liu, W.Y. Yang, et al., Angew. Chem. Int. Ed. 61 (2022) e202210422. doi: 10.1002/anie.202210422
12. [12]
  W.Y. Yang, R.C. Lai, J.J. Wu, et al., Adv. Funct. Mater. 32 (2022) 2204129. doi: 10.1002/adfm.202204129
13. [13]
  T. Mutai, H. Tomoda, T. Ohkawa, Y. Yabe, K. Araki, Angew. Chem. Int. Ed. 47 (2008) 9522–9524. doi: 10.1002/anie.200803975
14. [14]
  P.W. Zhou, K. Han, Acc. Chem. Res. 51 (2018) 1681–1690. doi: 10.1021/acs.accounts.8b00172
15. [15]
  C.C. Yan, J.J. Wu, W.Y. Yang, et al., Sci. China Mater. 65 (2022) 1020–1027. doi: 10.1007/s40843-021-1800-0
16. [16]
  Z.L. Che, C.C. Yan, X.D. Wang, L.S. Liao, Chin. J. Chem. 40 (2022) 2468–2481. doi: 10.1002/cjoc.202200313
17. [17]
  W.Y. Yang, C.C. Yan, X.D. Wang, L.S. Liao, Sci. China Chem. 65 (2022) 1843–1853. doi: 10.1007/s11426-022-1375-y
18. [18]
  J.J. Wu, X.D. Wang, L.S. Liao, Laser Photonics Rev. 16 (2022) 2200366. doi: 10.1002/lpor.202200366
19. [19]
  J.J. Wu, S.W. Yu, Y.P. Liu, et al., Adv. Funct. Mater. 33 (2023) 2214308. doi: 10.1002/adfm.202214308
20. [20]
  A.U. Khan, M. Kasha, Proc. Natl. Acad. Sci. 80 (1983) 1767. doi: 10.1073/pnas.80.6.1767
21. [21]
  X. Cheng, K. Wang, S. Huang, et al., Angew. Chem. Int. Ed. 54 (2015) 8369–8373. doi: 10.1002/anie.201503914
22. [22]
  W. Zhang, Y.L. Yan, J.M. Gu, J.N. Yao, Y.S. Zhao, Angew. Chem. Int. Ed. 54 (2015) 7125–7129. doi: 10.1002/anie.201502684
23. [23]
  X. Cheng, Y.F. Zhang, S.H. Han, et al., Chem. Eur. J. 22 (2016) 4899–4903. doi: 10.1002/chem.201600355
24. [24]
  X.D. Wang, Q. Liao, H. Li, et al., J. Am. Chem. Soc. 137 (2015) 9289–9295. doi: 10.1021/jacs.5b03051
25. [25]
  G.Q. Wei, Y. Yu, M.P. Zhuo, X.D. Wang, L.S. Liao, J. Mater. Chem. C 8 (2020) 11916–11921. doi: 10.1039/d0tc02881a
26. [26]
  C.Y. Peng, J.Y. Shen, Y.T. Chen, et al., J. Am. Chem. Soc. 137 (2015) 14349–14357. doi: 10.1021/jacs.5b08562
27. [27]
  H.W. Tseng, J.Q. Liu, Y.A. Chen, et al., J. Phys. Chem. Lett. 6 (2015) 1477–1486. doi: 10.1021/acs.jpclett.5b00423
28. [28]
  A.P. Demchenko, K.C. Tang, P.T. Chou, Chem. Soc. Rev. 42 (2013) 1379–1408. doi: 10.1039/C2CS35195A
29. [29]
  C.C. Yan, Z.L. Che, W.Y. Yang, X.D. Wang, L.S. Liao, Opo-Electron. Adv. 6 (2023) 230007. doi: 10.29026/oea.2023.230007
30. [30]
  Y.X. Du, C.L. Zou, C.H. Zhang, et al., Light Sci. Appl. 9 (2020) 151. doi: 10.1038/s41377-020-00392-7
31. [31]
  C. Wei, S.Y. Liu, C.L. Zou, et al., J. Am. Chem. Soc. 137 (2015) 62–65. doi: 10.1021/ja5112817
1. [1]
  Wenxiang Ma , Xinyu He , Tianyi Chen , De-Li Ma , Hongzheng Chen , Chang-Zhi Li . Near-infrared non-fused electron acceptors for efficient organic photovoltaics. Chinese Chemical Letters, 2024, 35(4): 109099-. doi: 10.1016/j.cclet.2023.109099
2. [2]
  Ying Li , Yanjun Xu , Xingqi Han , Di Han , Xuesong Wu , Xinlong Wang , Zhongmin Su . A new metal–organic rotaxane framework for enhanced ion conductivity of solid-state electrolyte in lithium-metal batteries. Chinese Chemical Letters, 2024, 35(9): 109189-. doi: 10.1016/j.cclet.2023.109189
3. [3]
  Biao Fang , Runwei Mo . PVDF-based solid-state battery. Chinese Journal of Structural Chemistry, 2024, 43(8): 100347-100347. doi: 10.1016/j.cjsc.2024.100347
4. [4]
  Yikun Wang , Qiaomei Chen , Shijie Liang , Dongdong Xia , Chaowei Zhao , Christopher R. McNeill , Weiwei Li . Near-infrared double-cable conjugated polymers based on alkyl linkers with tunable length for single-component organic solar cells. Chinese Chemical Letters, 2024, 35(4): 109164-. doi: 10.1016/j.cclet.2023.109164
5. [5]
  Xinzhi Ding , Chong Liu , Jing Niu , Nan Chen , Shutao Xu , Yingxu Wei , Zhongmin Liu . Solid-state NMR study of the stability of MOR framework aluminum. Chinese Journal of Structural Chemistry, 2024, 43(4): 100247-100247. doi: 10.1016/j.cjsc.2024.100247
6. [6]
  Tianyi Hou , Yunhui Huang , Henghui Xu . Interfacial engineering for advanced solid-state Li-metal batteries. Chinese Journal of Structural Chemistry, 2024, 43(7): 100313-100313. doi: 10.1016/j.cjsc.2024.100313
7. [7]
  Peng Jia , Yunna Guo , Dongliang Chen , Xuedong Zhang , Jingming Yao , Jianguo Lu , Liqiang Zhang . In-situ imaging electrocatalysis in a solid-state Li-O₂ battery with CuSe nanosheets as air cathode. Chinese Chemical Letters, 2024, 35(5): 108624-. doi: 10.1016/j.cclet.2023.108624
8. [8]
  Qianqian Song , Yunting Zhang , Jianli Liang , Si Liu , Jian Zhu , Xingbin Yan . Boron nitride nanofibers enhanced composite PEO-based solid-state polymer electrolytes for lithium metal batteries. Chinese Chemical Letters, 2024, 35(6): 108797-. doi: 10.1016/j.cclet.2023.108797
9. [9]
  Chaochao Wei , Ru Wang , Zhongkai Wu , Qiyue Luo , Ziling Jiang , Liang Ming , Jie Yang , Liping Wang , Chuang Yu . Revealing the size effect of FeS₂ on solid-state battery performances at different operating temperatures. Chinese Chemical Letters, 2024, 35(6): 108717-. doi: 10.1016/j.cclet.2023.108717
10. [10]
  Caixia Li , Yi Qiu , Yufeng Zhao , Wuliang Feng . Self assembled electron blocking and lithiophilic interface towards dendrite-free solid-state lithium battery. Chinese Chemical Letters, 2024, 35(4): 108846-. doi: 10.1016/j.cclet.2023.108846
11. [11]
  Ting WANG , Peipei ZHANG , Shuqin LIU , Ruihong WANG , Jianjun ZHANG . A Bi-CP-based solid-state thin-film sensor: Preparation and luminescence sensing for bioamine vapors. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1615-1621. doi: 10.11862/CJIC.20240134
12. [12]
  Yang Deng , Yitao Ouyang , Chao Han . Constriction-susceptible makes fast cycling of lithium metal in solid-state batteries: Silicon as an example. Chinese Journal of Structural Chemistry, 2024, 43(7): 100276-100276. doi: 10.1016/j.cjsc.2024.100276
13. [13]
  Linhui Liu , Wuwan Xiong , Mingli Fu , Junliang Wu , Zhenguo Li , Daiqi Ye , Peirong Chen . Efficient NO_x abatement by passive adsorption over a Pd-SAPO-34 catalyst prepared by solid-state ion exchange. Chinese Chemical Letters, 2024, 35(4): 108870-. doi: 10.1016/j.cclet.2023.108870
14. [14]
  Hui Liu , Xiangyang Tang , Zhuang Cheng , Yin Hu , Yan Yan , Yangze Xu , Zihan Su , Futong Liu , Ping Lu . Constructing multifunctional deep-blue emitters with weak charge transfer excited state for high-performance non-doped blue OLEDs and single-emissive-layer hybrid white OLEDs. Chinese Chemical Letters, 2024, 35(10): 109809-. doi: 10.1016/j.cclet.2024.109809
15. [15]
  Ziling Jiang , Shaoqing Chen , Chaochao Wei , Ziqi Zhang , Zhongkai Wu , Qiyue Luo , Liang Ming , Long Zhang , Chuang Yu . Enabling superior electrochemical performance of NCA cathode in Li_5.5PS_4.5Cl_1.5-based solid-state batteries with a dual-electrolyte layer. Chinese Chemical Letters, 2024, 35(4): 108561-. doi: 10.1016/j.cclet.2023.108561
16. [16]
  Yudi Cheng , Xiao Wang , Jiao Chen , Zihan Zhang , Jiadong Ou , Mengyao She , Fulin Chen , Jianli Li . A near-infrared fluorescent probe for visualizing transformation pathway of Cys/Hcy and H₂S and its applications in living system. Chinese Chemical Letters, 2024, 35(5): 109156-. doi: 10.1016/j.cclet.2023.109156
17. [17]
  Ying Zhao , Yin-Hang Chai , Tian Chen , Jie Zheng , Ting-Ting Li , Francisco Aznarez , Li-Long Dang , Lu-Fang Ma . Size-controlled synthesis and near-infrared photothermal response of Cp* Rh-based metalla[2]catenanes and rectangular metallamacrocycles. Chinese Chemical Letters, 2024, 35(6): 109298-. doi: 10.1016/j.cclet.2023.109298
18. [18]
  Xuan Zhu , Lin Zhou , Xiao-Yun Huang , Yan-Ling Luo , Xin Deng , Xin Yan , Yan-Juan Wang , Yan Qin , Yuan-Yuan Tang . (Benzimidazolium)2GeI4: A layered two-dimensional perovskite with dielectric switching and broadband near-infrared photoluminescence. Chinese Journal of Structural Chemistry, 2024, 43(6): 100272-100272. doi: 10.1016/j.cjsc.2024.100272
19. [19]
  Xuejian Xing , Pan Zhu , E Pang , Shaojing Zhao , Yu Tang , Zheyu Hu , Quchang Ouyang , Minhuan Lan . D-A-D-structured boron-dipyrromethene with aggregation-induced enhanced phototherapeutic efficiency for near-infrared fluorescent and photoacoustic imaging-guided synergistic photodynamic and photothermal cancer therapy. Chinese Chemical Letters, 2024, 35(10): 109452-. doi: 10.1016/j.cclet.2023.109452
20. [20]
  Jieqiong Xu , Wenbin Chen , Shengkai Li , Qian Chen , Tao Wang , Yadong Shi , Shengyong Deng , Mingde Li , Peifa Wei , Zhuo Chen . Organic stoichiometric cocrystals with a subtle balance of charge-transfer degree and molecular stacking towards high-efficiency NIR photothermal conversion. Chinese Chemical Letters, 2024, 35(10): 109808-. doi: 10.1016/j.cclet.2024.109808

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(199)
HTML views(5)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142