Citation: Zhenjie Yang, Chenyang Hu, Xuan Pang, Xuesi Chen. Sequence design in terpolymerization of ε-caprolactone, CO₂ and cyclohexane oxide: Random ester-carbonate distributions lead to large-span tunability[J]. Chinese Chemical Letters, ;2024, 35(5): 109340. doi: 10.1016/j.cclet.2023.109340 shu

Sequence design in terpolymerization of ε-caprolactone, CO₂ and cyclohexane oxide: Random ester-carbonate distributions lead to large-span tunability

Key Laboratory of Polymer Ecomaterials, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China

xpang@ciac.ac.cn

Received Date: 22 September 2023
Revised Date: 21 November 2023
Accepted Date: 23 November 2023
Available Online: 25 November 2023

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It is of great interest to make a degradable material widely tailorable to replace petroleum-derived products among diverse applications. Here, we report the construction of a new multi-purpose degradable material for the first time via a simple ternary copolymerization system comprising ε-caprolactone (ε-CL), cyclohexane oxide (CHO) and CO₂. Under low pressure of 1 bar ~5 bar, the ring-opening polymerization (ROP) of ε-CL and ring-opening copolymerization (ROCOP) of CO₂ and CHO can simultaneously proceed. The carbonate units are randomly distributed on the polymer chain. These random terpolymers have controllable molar mass (10–106 kDa) and compositions (4–33 mol% CO₂). And the obtained materials show large-span tunability from tough plastic to elastomer and even adhesive.
- Polyesters,
- CO₂-derived copolymers,
- Random copolymerization,
- Elastomers,
- Adhesives
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Sequence design in terpolymerization of ε-caprolactone, CO2 and cyclohexane oxide: Random ester-carbonate distributions lead to large-span tunability

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通讯作者: 陈斌, bchen63@163.com

Sequence design in terpolymerization of ε-caprolactone, CO₂ and cyclohexane oxide: Random ester-carbonate distributions lead to large-span tunability