Citation: Yi Herng Chan, Zhe Phak Chan, Serene Sow Mun Lock, Chung Loong Yiin, Shin Ying Foong, Mee Kee Wong, Muhammad Anwar Ishak, Ven Chian Quek, Shengbo Ge, Su Shiung Lam. Thermal pyrolysis conversion of methane to hydrogen (H₂): A review on process parameters, reaction kinetics and techno-economic analysis[J]. Chinese Chemical Letters, ;2024, 35(8): 109329. doi: 10.1016/j.cclet.2023.109329 shu

Thermal pyrolysis conversion of methane to hydrogen (H₂): A review on process parameters, reaction kinetics and techno-economic analysis

a.
PETRONAS Research Sdn. Bhd. (PRSB), Kawasan Institusi Bangi, Lot 3288 & 3289, Off Jalan Ayer Itam, Kajang 43000, Malaysia
b.
PETRONAS Carbon Capture & Storage (CCS) Enterprise, PETRONAS Twin Towers, Kuala Lumpur City Centre, Kuala Lumpur 50088, Malaysia
c.
CO₂ Research Center (CO2RES), Department of Chemical Engineering, Universiti Teknologi PETRONAS, Seri Iskandar 32610, Malaysia
d.
Department of Chemical Engineering and Energy Sustainability, Faculty of Engineering, Universiti Malaysia Sarawak (UNIMAS), Kota Samarahan 94300, Malaysia
e.
Institute of Sustainable and Renewable Energy (ISuRE), Universiti Malaysia Sarawak (UNIMAS), Kota Samarahan 94300, Malaysia
f.
Higher Institution Centre of Excellence (HICoE), Institute of Tropical Aquaculture and Fisheries (AKUATROP), Universiti Malaysia Terengganu, Kuala Nerus 21030, Malaysia
g.
Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, College of Materials Science and Engineering, Nanjing Forestry University, Nanjing 210037, China
h.
Center for Global Health Research (CGHR), Saveetha Medical College, Saveetha Institute of Medical and Technical Sciences (SIMATS), Saveetha University, Chennai 602105, India

^**

chan.yiherng@petronas.com.my

clyiin@unimas.my

lam@umt.edu.my

Received Date: 26 July 2023
Revised Date: 30 October 2023
Accepted Date: 15 November 2023
Available Online: 23 November 2023

Figures(5)

Hydrogen (H₂) is a promising renewable energy which finds wide applications as the world gears toward low-carbon economy. However, current H₂ production via steam methane reforming of natural gas or gasification of coal are laden with high CO₂ footprints. Recently, methane (CH₄) pyrolysis has emerged as a potential technology to generate low-carbon H₂ and solid carbon. In this review, the current state-of-art and recent progress of H₂ production from CH₄ pyrolysis are reviewed in detail. Aspects such as fundamental mechanism and chemistry involved, effect of process parameters on the conversion efficiency and reaction kinetics for various reaction media and catalysts are elucidated and critically discussed. Temperature, among other factors, plays the most critical influence on the methane pyrolysis reaction. Molten metal/salt could lower the operating temperature of methane pyrolysis to < 1000 ℃, whereas plasma technology usually operates in the regime of > 1000 ℃. Based on the reaction kinetics, metal-based catalysts were more efficient in lowering the activation energy of the reaction to 29.5–88 kJ/mol from that of uncatalyzed reaction (147–420.7 kJ/mol). Besides, the current techno-economic performance of the process reveals that the levelized cost of H₂ is directly influenced by the sales price of carbon (by-product) generated, which could offset the overall cost. Lastly, the main challenges of reactor design for efficient product separation and retrieval, as well as catalyst deactivation/poisoning need to be debottlenecked.
- Pyrolysis,
- Methane,
- Hydrogen,
- Reaction kinetics,
- Techno-economic analysis
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Thermal pyrolysis conversion of methane to hydrogen (H2): A review on process parameters, reaction kinetics and techno-economic analysis

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通讯作者: 陈斌, bchen63@163.com

Thermal pyrolysis conversion of methane to hydrogen (H₂): A review on process parameters, reaction kinetics and techno-economic analysis