Citation: Panke Zhou, Hong Yu, Mun Yin Chee, Tao Zeng, Tianli Jin, Hongling Yu, Shuo Wu, Wen Siang Lew, Xiong Chen. Electron push-pull effects induced performance promotion in covalent organic polymer thin films-based memristor for neuromorphic application[J]. Chinese Chemical Letters, ;2024, 35(5): 109279. doi: 10.1016/j.cclet.2023.109279 shu

Electron push-pull effects induced performance promotion in covalent organic polymer thin films-based memristor for neuromorphic application

Panke Zhou ^a ,
Hong Yu ^a ,
Mun Yin Chee ^b ,
Tao Zeng ^c ,
Tianli Jin ^b ,
Hongling Yu ^a ,
Shuo Wu ^b ,
Wen Siang Lew ^{b, *,} ,
Xiong Chen ^{a, *,}

a.
State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou 350116, China
b.
School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371, Singapore
c.
Department of Materials Science and Engineering, National University of Singapore, Singapore 117575, Singapore

wensiang@ntu.edu.sg

chenxiong987@fzu.edu.cn

Received Date: 31 August 2023
Revised Date: 31 October 2023
Accepted Date: 1 November 2023
Available Online: 8 November 2023

Figures(6)

Covalent organic polymer (COP) thin film-based memristors have generated intensive research interest, but the studies are still in their infancy. Herein, by controlling the content of hydroxyl groups in the aldehyde monomer, Py-COP thin films with different electronic push-pull effects were fabricated bearing distinct memory performances, where the films were prepared by the solid-liquid interface method on the ITO substrates and further fabricated as memory devices with ITO/Py-COPs/Ag architectures. The Py-COP-1-based memory device only exhibited binary memory behavior with an ON/OFF ratio of 1:10^1.87. In contrast, the device based on Py-COP-2 demonstrated ternary memory behavior with an ON/OFF ratio of 1:10^0.6: 10^3.1 and a ternary yield of 55%. The ternary memory mechanism of the ITO/Py-COP-2/Ag memory device is most likely due to the combination of the trapping of charge carriers and conductive filaments. Interestingly, the Py-COPs-based devices can successfully emulate the synaptic potentiation/depression behavior, clarifying the programmability of these devices in neuromorphic systems. These results suggest that the electronic properties of COPs can be precisely tuned at the molecular level, which provides a promising route for designing multi-level memory devices.
- Covalent organic polymers,
- Push-pull effects,
- Multi-level memory,
- Memristor
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