Citation: Xiaoxiao Huang, Zhi-Long He, Yangpeng Chen, Lei Li, Zhenyu Yang, Chunyang Zhai, Mingshan Zhu. Novel P-doping-tuned Pd nanoflowers/S,N-GQDs photo-electrocatalyst for high-efficient ethylene glycol oxidation[J]. Chinese Chemical Letters, ;2024, 35(6): 109271. doi: 10.1016/j.cclet.2023.109271 shu

Novel P-doping-tuned Pd nanoflowers/S,N-GQDs photo-electrocatalyst for high-efficient ethylene glycol oxidation

Xiaoxiao Huang ^a ,
Zhi-Long He ^a ,
Yangpeng Chen ^a ,
Lei Li ^{b, *,} ,
Zhenyu Yang ^b ,
Chunyang Zhai ^{a, *,} ,
Mingshan Zhu ^c

a.
School of Materials Science and Chemical Engineering, Ningbo University, Ningbo 315211, China
b.
College of Biological, Chemical Sciences and Engineering, Jiaxing University, Jiaxing 314001, China
c.
Guangdong Key Lab oratory of Environmental Pollution and Health, School of Environment, Jinan University, Guangzhou 510632, China

leili@mail.zjxu.edu.cn

zhaichunyang@edu.nbu.cn

Received Date: 7 July 2023
Revised Date: 16 October 2023
Accepted Date: 31 October 2023
Available Online: 4 November 2023

Figures(5)

Traditional photo-electcatalyst structures of small noble metal nanoparticles assembling into large-scale photoactive semiconductors still suffer from agglomeration of noble metal nanoparticles, insufficient charge transfer, undesirable photoresponse ability that restricted the photo-electrocatalytic performance. To this end, a novel design strategy is proposed in this work, namely integrating small-scale photoactive materials (doped graphene quantum dots, S,N-GQDs) with large-sized noble metal (PdP) nanoflowers to form novel photo-electrocatalysts for high-efficient alcohol oxidation reaction. As expected, superior electrocatalytic performance of PdP/S,N-GQDs for ethylene glycol oxidation is acquired, thanks to the nanoflower structure with larger specific surface area and abundant active sites. Furthermore, nonmetal P are demonstrated, especially optimizing the adsorption strength, enhancing the interfacial contact, reducing metal agglomeration, ensuring uniform and efficient doping of S,N-GQDs, and ultimately significantly boost the catalytic activity of photo-electrocatalysts.
- Non-metallic P–doping,
- Sulfur nitrogen co-doped graphene quantum dots,
- Pd nanoflowers,
- Photo-electrocatalytic,
- Ethylene glycol oxidation
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