Citation: Yufeng Wu, Mingjun Jing, Juan Li, Wenhui Deng, Mingguang Yi, Zhanpeng Chen, Meixia Yang, Jinyang Wu, Xinkai Xu, Yanson Bai, Xiaoqing Zou, Tianjing Wu, Xianyou Wang. Collaborative integration of Fe-N_x active center into defective sulfur/selenium-doped carbon for efficient oxygen electrocatalysts in liquid and flexible Zn-air batteries[J]. Chinese Chemical Letters, ;2024, 35(9): 109269. doi: 10.1016/j.cclet.2023.109269 shu

Collaborative integration of Fe-N_x active center into defective sulfur/selenium-doped carbon for efficient oxygen electrocatalysts in liquid and flexible Zn-air batteries

National Base for International Science & Technology Cooperation, National Local Joint Engineering Laboratory for Key Materials of New Energy Storage Battery, Key Laboratory of Environmentally Friendly Chemistry and Application of Ministry of Education, Xiangtan University, Xiangtan 411105, China

jingmingjun@xtu.edu.cn

twu@xtu.edu.cn

Received Date: 14 August 2023
Revised Date: 3 September 2023
Accepted Date: 31 October 2023
Available Online: 2 November 2023

Figures(4)

Strategic active site organization is imperative for the advancement of effective and long-lasting catalysts of oxygen reduction reactions. However, the controllable multi-active site design is a highly intricate topic for catalyst synthesis. Employing pre-trapping and post-activation strategy, Fe-N bonding structure and S, Se functionalized heteroatom are integrated into a conductive porous carbon. In this process, the nitrogen-abundant polymer 1,3,5-triformylbenzene-tris(4-aminophenyl)benzene (Tf-TAPA) adsorbs Fe³⁺ under the intrinsically metal anchoring ability of N atoms and simultaneously in-situ assembles long-chain thiophene-S. Subsequently, the Fe³⁺ is transformed into Fe-N_x moieties with the conversion of the organic chain to incompletely graphitized carbon. Furthermore, the alteration of the electronic configuration achieved through the introduction of dual-atom S and Se leads to a pronounced enhancement in catalytic efficiency. Benefitting from the Fe-N_x bonding structure, dense structural defects, and conductive carbon networks, the resultant Fe-S,Se/NCNs possesses a positive half-wave potential of 0.86 V and a 90% current retention rate, outstripping the Pt/C benchmark. Moreover, the liquid and flexible ZAB driven by Fe-S,Se/NCNs achieves large power densities of 259.7 and 164.7 mW/cm², respectively. This study provides a new comprehension in developing an efficient and stable M-N-C oxygen electrocatalyst.
- Atomic regulation,
- Chalcogens co-doped,
- Catalytic performance,
- Noble metal-free electrocatalyst,
- Zn-air battery
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Collaborative integration of Fe-Nx active center into defective sulfur/selenium-doped carbon for efficient oxygen electrocatalysts in liquid and flexible Zn-air batteries

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通讯作者: 陈斌, bchen63@163.com

Collaborative integration of Fe-N_x active center into defective sulfur/selenium-doped carbon for efficient oxygen electrocatalysts in liquid and flexible Zn-air batteries