Citation: Tao Long, Peng Chen, Bin Feng, Caili Yang, Kairong Wang, Yulei Wang, Can Chen, Yaping Wang, Ruotong Li, Meng Wu, Minhuan Lan, Wei Kong Pang, Jian-Fang Wu, Yuan-Li Ding. Reinforced concrete-like Na_3.5V_1.5Mn_0.5(PO₄)₃@graphene hybrids with hierarchical porosity as durable and high-rate sodium-ion battery cathode[J]. Chinese Chemical Letters, ;2024, 35(4): 109267. doi: 10.1016/j.cclet.2023.109267 shu

Reinforced concrete-like Na_3.5V_1.5Mn_0.5(PO₄)₃@graphene hybrids with hierarchical porosity as durable and high-rate sodium-ion battery cathode

Tao Long ^a ,
Peng Chen ^a ,
Bin Feng ^a ,
Caili Yang ^a ,
Kairong Wang ^a ,
Yulei Wang ^a ,
Can Chen ^a ,
Yaping Wang ^a ,
Ruotong Li ^a ,
Meng Wu ^{b, *,} ,
Minhuan Lan ^c ,
Wei Kong Pang ^d ,
Jian-Fang Wu ^a ,
Yuan-Li Ding ^{a, *,}

a.
College of Materials Science and Engineering, Hunan University, Changsha 410082, China
b.
Department of Physics, Xiamen University, Xiamen 361005, China
c.
College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China
d.
Institute for Superconducting & Electronic Materials, Faculty of Engineering, University of Wollongong, Wollongong, NSW 2522, Australia

meng.wu@xmu.edu.cn

ylding@hnu.edu.cn

Received Date: 19 September 2023
Revised Date: 12 October 2023
Accepted Date: 31 October 2023
Available Online: 3 November 2023

Figures(4)

Realizing high-rate capability and high-efficiency utilization of polyanionic cathode materials is of great importance for practical sodium-ion batteries (SIBs) since they usually suffer from extremely low electronic conductivity and limited ionic diffusion kinetics. Herein, taking Na_3.5V_1.5Mn_0.5(PO₄)₃ (NVMP) as an example, a reinforced concrete-like hierarchical and porous hybrid (NVMP@C@3DPG) built from 3D graphene ("rebar") frameworks and in situ generated carbon coated NVMP ("concrete") has been developed by a facile polymer assisted self-assembly and subsequent solid-state method. Such hybrids deliver superior rate capability (73.9 mAh/g up to 20 C) and excellent cycling stability in a wide temperature range with a high specific capacity of 88.4 mAh/g after 5000 cycles at 15 C at room temperature, and a high capacity retention of 97.1% after 500 cycles at 1 C (−20 ℃), and maintaining a high reversible capacity of 110.3 mAh/g in full cell. This work offers a facile and efficient strategy to develop advanced polyanionic cathodes with high-efficiency utilization and 3D electron/ion transport systems.
- Sodium-ion battery,
- Polyanionic cathode,
- Hybrid structure,
- Interconnected structure,
- Energy storage
1. [1]
  J.Y. Hwang, S.T. Myung, Y.K. Sun, Chem. Soc. Rev. 46 (2017) 3529–3614. doi: 10.1039/C6CS00776G
2. [2]
  N. Yabuuchi, K. Kubota, M. Dahbi, S.J.C. r. Komaba, Chem. Rev. 114 (2014) 11636–11682. doi: 10.1021/cr500192f
3. [3]
  J. Feng, S.H. Luo, K.X. Cai, et al., Chin. Chem Lett. 33 (2022) 2316–2326. doi: 10.1016/j.cclet.2021.09.077
4. [4]
  P. Chen, C. Wu, Z. Wang, et al., ACS Appl. Energy Mater. 5 (2022) 2542–2552. doi: 10.1021/acsaem.1c04061
5. [5]
  Z. Jian, W. Han, X. Lu, et al., Adv. Energy Mater. 3 (2013) 156–160. doi: 10.1002/aenm.201200558
6. [6]
  Y. Jiang, X. Zhou, D. Li, et al., Adv. Energy Mater. 8 (2018) 1800068. doi: 10.1002/aenm.201800068
7. [7]
  Y.Y. Wang, B.H. Hou, J.Z. Guo, et al., Adv. Energy Mater. 8 (2018) 1703252. doi: 10.1002/aenm.201703252
8. [8]
  L. Zhao, H. Zhao, Z. Du, et al., Electrochim. Acta 282 (2018) 510–519. doi: 10.1016/j.electacta.2018.06.074
9. [9]
  Y. Chen, J. Cheng, C. Wang, et al., Chem. Eng. J. 413 (2021) 127451. doi: 10.1016/j.cej.2020.127451
10. [10]
  D. Meghnani, S. Kumar Singh, N. Srivastava, et al., Chem. Phys. Chem. 23 (2022) e202200459. doi: 10.1002/cphc.202200459
11. [11]
  D. Yan, S. Xiao, X. Li, et al., ChemSusChem 15 (2022) e202201121. doi: 10.1002/cssc.202201121
12. [12]
  Y. Jiang, Z. Yang, W. Li, et al., Adv. Energy Mater. 5 (2015) 1402104. doi: 10.1002/aenm.201402104
13. [13]
  L. Mo, L. Zhu, L. Xie, et al., J. Phys. Chem. Solids. 157 (2021) 110187. doi: 10.1016/j.jpcs.2021.110187
14. [14]
  J. Kim, J.K. Yoo, Y.S. Jung, K.J.A.E.M. Kang, Adv. Energy Mater. 3 (2013) 1004–1007. doi: 10.1002/aenm.201300205
15. [15]
  L. Bi, Z. Song, X. Liu, et al., J. Alloys Compd. 845 (2020) 156271. doi: 10.1016/j.jallcom.2020.156271
16. [16]
  R. Klee, M. Wiatrowski, M.J. Aragon, et al., ACS Appl. Mater. Interfaces 9 (2017) 1471–1478. doi: 10.1021/acsami.6b12688
17. [17]
  X. Rui, W. Sun, C. Wu, Y. Yu, Q. Yan, Adv. Mater. 27 (2015) 6670–6676. doi: 10.1002/adma.201502864
18. [18]
  G. Li, D. Jiang, H. Wang, et al., J. Power Sources 265 (2014) 325–334. doi: 10.1016/j.jpowsour.2014.04.054
19. [19]
  B. Zhang, K. Ma, X. Lv, et al., J. Alloys Compd. 867 (2021) 159060. doi: 10.1016/j.jallcom.2021.159060
20. [20]
  H.B. Huang, S.H. Luo, C.L. Liu, et al., Appl. Surf. Sci. 487 (2019) 1159–1166. doi: 10.1016/j.apsusc.2019.05.224
21. [21]
  H. Xiong, G. Sun, Z. Liu, et al., Angew. Chem. Int. Ed. 60 (2021) 10334–10341. doi: 10.1002/anie.202100954
22. [22]
  Y.L. Ding, P. Kopold, K. Hahn, et al., Adv. Funct. Mater. 26 (2016) 1112–1119. doi: 10.1002/adfm.201504294
23. [23]
  J. Zhang, X. Zhao, Y. Song, et al., Energy Storage Mater 23 (2019) 25–34. doi: 10.1016/j.ensm.2019.05.041
24. [24]
  M. Abbate, H. Pen, M. Czyżyk, et al., J. Electron. Spectrosc. 62 (1993) 185– 195. doi: 10.1016/0368-2048(93)80014-D
25. [25]
  Z. Chen, Z. Chen, Z. Liu, et al., Phys. Rev. Lett. 119 (2017) 156801. doi: 10.1103/PhysRevLett.119.156801
1. [1]
  Zhijia Zhang , Shihao Sun , Yuefang Chen , Yanhao Wei , Mengmeng Zhang , Chunsheng Li , Yan Sun , Shaofei Zhang , Yong Jiang . Epitaxial growth of Cu_2-xSe on Cu (220) crystal plane as high property anode for sodium storage. Chinese Chemical Letters, 2024, 35(7): 108922-. doi: 10.1016/j.cclet.2023.108922
2. [2]
  Xinyu Ren , Hong Liu , Jingang Wang , Jiayuan Yu . Electrospinning-derived functional carbon-based materials for energy conversion and storage. Chinese Chemical Letters, 2024, 35(6): 109282-. doi: 10.1016/j.cclet.2023.109282
3. [3]
  Ningning Zhao , Yuyan Liang , Wenjie Huo , Xinyan Zhu , Zhangxing He , Zekun Zhang , Youtuo Zhang , Xianwen Wu , Lei Dai , Jing Zhu , Ling Wang , Qiaobao Zhang . Separator functionalization enables high-performance zinc anode via ion-migration regulation and interfacial engineering. Chinese Chemical Letters, 2024, 35(9): 109332-. doi: 10.1016/j.cclet.2023.109332
4. [4]
  Shuangliang Xie , Yuyue Chen , Qing He , Liang Chen , Jikun Yang , Shiqing Deng , Yimei Zhu , He Qi . Relaxor antiferroelectric-relaxor ferroelectric crossover in NaNbO₃-based lead-free ceramics for high-efficiency large-capacitive energy storage. Chinese Chemical Letters, 2024, 35(7): 108871-. doi: 10.1016/j.cclet.2023.108871
5. [5]
  Wenhao Chen , Muxuan Wu , Han Chen , Lue Mo , Yirong Zhu . Cu₂Se@C thin film with three-dimensional braided structure as a cathode material for enhanced Cu²⁺ storage. Chinese Chemical Letters, 2024, 35(5): 108698-. doi: 10.1016/j.cclet.2023.108698
6. [6]
  Shengyu Zhao , Qinhao Shi , Wuliang Feng , Yang Liu , Xinxin Yang , Xingli Zou , Xionggang Lu , Yufeng Zhao . Suppression of multistep phase transitions of O3-type cathode for sodium-ion batteries. Chinese Chemical Letters, 2024, 35(5): 108606-. doi: 10.1016/j.cclet.2023.108606
7. [7]
  Shengyu Zhao , Xuan Yu , Yufeng Zhao . A water-stable high-voltage P3-type cathode for sodium-ion batteries. Chinese Chemical Letters, 2024, 35(9): 109933-. doi: 10.1016/j.cclet.2024.109933
8. [8]
  Hui Gu , Mingyue Gao , Kuan Shen , Tianli Zhang , Junhao Zhang , Xiangjun Zheng , Xingmei Guo , Yuanjun Liu , Fu Cao , Hongxing Gu , Qinghong Kong , Shenglin Xiong . F127 assisted fabrication of Ge/rGO/CNTs nanocomposites with three-dimensional network structure for efficient lithium storage. Chinese Chemical Letters, 2024, 35(9): 109273-. doi: 10.1016/j.cclet.2023.109273
9. [9]
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10. [10]
  Jun-Ming Cao , Kai-Yang Zhang , Jia-Lin Yang , Zhen-Yi Gu , Xing-Long Wu . Differential bonding behaviors of sodium/potassium-ion storage in sawdust waste carbon derivatives. Chinese Chemical Letters, 2024, 35(4): 109304-. doi: 10.1016/j.cclet.2023.109304
11. [11]
  Binyang Qin , Mengqi Wang , Shimei Wu , Yining Li , Chilin Liu , Yufei Zhang , Haosen Fan . Carbon dots confined nanosheets assembled NiCo₂S₄@CDs cross-stacked architecture for enhanced sodium ion storage. Chinese Chemical Letters, 2024, 35(7): 108921-. doi: 10.1016/j.cclet.2023.108921
12. [12]
  Xiping Dong , Xuan Wang , Zhixiu Lu , Qinhao Shi , Zhengyi Yang , Xuan Yu , Wuliang Feng , Xingli Zou , Yang Liu , Yufeng Zhao . Construction of Cu-Zn Co-doped layered materials for sodium-ion batteries with high cycle stability. Chinese Chemical Letters, 2024, 35(5): 108605-. doi: 10.1016/j.cclet.2023.108605
13. [13]
  Chao Ma , Cong Lin , Jian Li . MicroED as a powerful technique for the structure determination of complex porous materials. Chinese Journal of Structural Chemistry, 2024, 43(3): 100209-100209. doi: 10.1016/j.cjsc.2023.100209
14. [14]
  Yuhang Li , Yang Ling , Yanhang Ma . Application of three-dimensional electron diffraction in structure determination of zeolites. Chinese Journal of Structural Chemistry, 2024, 43(4): 100237-100237. doi: 10.1016/j.cjsc.2024.100237
15. [15]
  Hai-Ling Wang , Zhong-Hong Zhu , Hua-Hong Zou . Structure and assembly mechanism of high-nuclear lanthanide-oxo clusters. Chinese Journal of Structural Chemistry, 2024, 43(9): 100372-100372. doi: 10.1016/j.cjsc.2024.100372
16. [16]
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17. [17]
  Shunshun Jiang , Ji Zhang , Jing Wang , Shan-Tao Zhang . Excellent energy storage properties in non-stoichiometric Bi_0.5Na_0.5TiO₃-based relaxor ferroelectric ceramics. Chinese Chemical Letters, 2024, 35(7): 108955-. doi: 10.1016/j.cclet.2023.108955
18. [18]
  Ya Song , Mingxia Zhou , Zhu Chen , Huali Nie , Jiao-Jing Shao , Guangmin Zhou . Integrated interconnected porous and lamellar structures realized fast ion/electron conductivity in high-performance lithium-sulfur batteries. Chinese Chemical Letters, 2024, 35(6): 109200-. doi: 10.1016/j.cclet.2023.109200
19. [19]
  Run-Han Li , Tian-Yi Dang , Wei Guan , Jiang Liu , Ya-Qian Lan , Zhong-Min Su . Evolution exploration and structure prediction of Keggin-type group IVB metal-oxo clusters. Chinese Chemical Letters, 2024, 35(5): 108805-. doi: 10.1016/j.cclet.2023.108805
20. [20]
  Zhengzheng LIU , Pengyun ZHANG , Chengri WANG , Shengli HUANG , Guoyu YANG . Synthesis, structure, and electrochemical properties of a sandwich-type {Co₆}-cluster-added germanotungstate. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1173-1179. doi: 10.11862/CJIC.20240039

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沈阳化工大学材料科学与工程学院沈阳 110142

Reinforced concrete-like Na3.5V1.5Mn0.5(PO4)3@graphene hybrids with hierarchical porosity as durable and high-rate sodium-ion battery cathode

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通讯作者: 陈斌, bchen63@163.com

Reinforced concrete-like Na_3.5V_1.5Mn_0.5(PO₄)₃@graphene hybrids with hierarchical porosity as durable and high-rate sodium-ion battery cathode