Citation: Pu Zhang, Xiang Mao, Xuehua Dong, Ling Huang, Liling Cao, Daojiang Gao, Guohong Zou. Two UV organic-inorganic hybrid antimony-based materials with superior optical performance derived from cation-anion synergetic interactions[J]. Chinese Chemical Letters, ;2024, 35(9): 109235. doi: 10.1016/j.cclet.2023.109235 shu

Two UV organic-inorganic hybrid antimony-based materials with superior optical performance derived from cation-anion synergetic interactions

Pu Zhang ^a ,
Xiang Mao ^a ,
Xuehua Dong ^{a, *,} ,
Ling Huang ^a ,
Liling Cao ^a ,
Daojiang Gao ^a ,
Guohong Zou ^{b, *,}

a.
College of Chemistry and Materials Science, Sichuan Normal University, Chengdu 610066, China
b.
College of Chemistry, Sichuan University, Chengdu 610065, China

dongxh027@sina.com

zough@scu.edu.cn

Received Date: 7 September 2023
Revised Date: 2 October 2023
Accepted Date: 23 October 2023
Available Online: 26 October 2023

Figures(5)

Finding suitable strategies to effectively enhance the optical properties of materials are the goal being pursued by researchers. Herein, cation-anion synergetic interactions strategy was proposed to develop two novel organic-inorganic hybrid antimony-based optical materials, (C₃H₅N₂)SbF₂SO₄ (Ⅰ) and (C₅H₆N)SbF₂SO₄ (Ⅱ), which were obtained by introducing Sb³⁺cation containing stereochemically active lone-pair (SCALP) and organic π-conjugated cations into sulphate system. The synergistic interactions of the organic π-conjugated cations, the inorganic [SbO₂F₂]³⁻ seesaw anions and the [SO₄]²⁻ distorted tetrahedra anions make their ultraviolet (UV) absorption edges approach 297 and 283 nm, respectively, and raise their birefringence up to 0.193@546 nm and 0.179@546 nm, respectively. Interestingly, although the two compounds have the same stoichiometric ratio and similar one-dimensional (1D) chain structure, they show opposite macroscopic symmetry, where the NCS compound (Ⅱ) exhibits a large second-harmonic generation (SHG) response (1.6 times that of KH₂PO₄). The two reported compounds are found to be promising UV optical materials in the experimental tests.
- Antimony-based crystals,
- Cation-anion synergetic interactions,
- Large birefringence,
- Short UV absorption edge,
- Organic-inorganic hybrid,
- Ionothermal synthesis
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