Citation: Xuying Yu, Jiarong Mi, Yulan Han, Cai Sun, Mingsheng Wang, Guocong Guo. A stable radiochromic semiconductive viologen-based metal–organic framework for dual-mode direct X-ray detection[J]. Chinese Chemical Letters, ;2024, 35(9): 109233. doi: 10.1016/j.cclet.2023.109233 shu

A stable radiochromic semiconductive viologen-based metal–organic framework for dual-mode direct X-ray detection

Xuying Yu ^{a, c} ,
Jiarong Mi ^{a, b} ,
Yulan Han ^d ,
Cai Sun ^b ,
Mingsheng Wang ^{a, *,} ,
Guocong Guo ^{a, *,}

a.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350608, China
b.
College of Chemistry, Fuzhou University, Fuzhou 350108, China
c.
University of Chinese Academy of Sciences, Beijing 100049, China
d.
School of Chemistry and Chemical Engineering, Queen's University Belfast, Belfast BT9 5AG, United Kingdom

mswang@fjirsm.ac.cn

gcguo@fjirsm.ac.cn

Received Date: 18 September 2023
Revised Date: 16 October 2023
Accepted Date: 23 October 2023
Available Online: 24 October 2023

Figures(5)

Direct X-ray detectors, which directly convert X-rays into electrical signals through semiconductors, have higher space solution than scintillator-mediated indirect X-ray ones and are high desirable for early cancer detection and other applications, but the mainstream commercial α-Se detector is still largely limited by high production costs, large leakage current and low stability. This article reports an easily prepared, stable radiochromic semiconductive metal–organic framework (MOF), (MV)[Cd₃(tdc)₄]·2H₂O (RCS-1, H₂tdc = 2,5-thiophenedicarboxylic acid; MV²⁺ = methyl viologen cation) with direct X-ray detecting ability. With a large bulk resistivity of 8.40 × 10⁹ Ω cm, this material ensures minimal dark current and low noise for X-ray detection. Additionally, it exhibits higher sensitivity to W Kα X-rays (98.58 µC Gy⁻¹ cm⁻²) than α-Se (~20 µC Gy⁻¹ cm⁻²). Meanwhile, unlike most reported direct X-ray detecting semiconductors, compound RCS-1 shows remarkable color change upon X-ray irradiation owing to the presence of photochromism-active viologen cations. This feature offers an appealing visual detecting ability to direct X-ray detectors that provide only the electrical signals.
- Metal-organic framework,
- Viologen,
- Photochromism,
- Conductance,
- X-ray detection
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