Citation: Bin Dong, Ning Yu, Qiu-Yue Wang, Jing-Ke Ren, Xin-Yu Zhang, Zhi-Jie Zhang, Ruo-Yao Fan, Da-Peng Liu, Yong-Ming Chai. Double active sites promoting hydrogen evolution activity and stability of CoRuOH/Co₂P by rapid hydrolysis[J]. Chinese Chemical Letters, ;2024, 35(7): 109221. doi: 10.1016/j.cclet.2023.109221 shu

Double active sites promoting hydrogen evolution activity and stability of CoRuOH/Co₂P by rapid hydrolysis

State Key Laboratory of Heavy Oil Processing, College of Chemistry and Chemical Engineering, China University of Petroleum (East China), Qingdao 266580, China

dongbin@upc.edu.cn

ymchai@upc.edu.cn

Received Date: 15 January 2023
Revised Date: 25 September 2023
Accepted Date: 17 October 2023
Available Online: 24 October 2023

Figures(5)

Cobalt-based phosphides show excellent hydrogen evolution reaction (HER) performance, however, improving the intrinsic activity and stability of it in alkaline electrolyte still remains a challenge. Herein, CoRuOH/Co₂P/CF with heterojunction structure was developed by means of molten salt and rapid hydrolysis (30 s). The OH⁻ from rapid surface hydrolysis of Co₂P as a hydrogen adsorption site can facilitate the formation of thin CoRuOH layer as a water dissociation site, which may bring out better synergistic effect for alkaline HER. Moreover, the covering of CoRuOH can improve the stability of Co₂P for HER. When drives at 100 mA/cm², it only requires overpotential of 81 mV in 1.0 mol/L KOH (25 ℃). Even at higher current density (1000 mA/cm²), CoRuOH/Co₂P/CF can also operate stability for at least 100 h. When coupling with NiFe-LDH/IF in a two-electrode system, the voltage of NiFe-LDH/IF⁽⁺⁾ || CoRuOH/Co₂P/CF⁽⁻⁾ at 1000 mA/cm² is merely 1.77 V with 100 h, demonstrating great potential for water splitting. The implementation of this work provides a new strategy and reference for the further improvement of transition metal phosphides as HER electrocatalysts.
- CoRuOH/Co₂P/CF,
- Enhanced activity and stability,
- Double active site,
- Large current density,
- Hydrogen evolution reaction
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Double active sites promoting hydrogen evolution activity and stability of CoRuOH/Co2P by rapid hydrolysis

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通讯作者: 陈斌, bchen63@163.com

Double active sites promoting hydrogen evolution activity and stability of CoRuOH/Co₂P by rapid hydrolysis