Citation: Xiao Li, Wanqiang Yu, Yujie Wang, Ruiying Liu, Qingquan Yu, Riming Hu, Xuchuan Jiang, Qingsheng Gao, Hong Liu, Jiayuan Yu, Weijia Zhou. Metal-encapsulated nitrogen-doped carbon nanotube arrays electrode for enhancing sulfion oxidation reaction and hydrogen evolution reaction by regulating of intermediate adsorption[J]. Chinese Chemical Letters, ;2024, 35(8): 109166. doi: 10.1016/j.cclet.2023.109166 shu

Metal-encapsulated nitrogen-doped carbon nanotube arrays electrode for enhancing sulfion oxidation reaction and hydrogen evolution reaction by regulating of intermediate adsorption

Xiao Li ^{a, 1} ,
Wanqiang Yu ^{a, 1} ,
Yujie Wang ^{a, 1} ,
Ruiying Liu ^a ,
Qingquan Yu ^a ,
Riming Hu ^{b, *,} ,
Xuchuan Jiang ^b ,
Qingsheng Gao ^c ,
Hong Liu ^{a, d} ,
Jiayuan Yu ^{a, *,} ,
Weijia Zhou ^{a, *,}

a.
Institute for Advanced Interdisciplinary Research (iAIR), School of Chemistry and Chemical Engineering, University of Jinan, Ji'nan 250022, China
b.
Institute for Smart Materials & Engineering, School of Materials Science and Engineering, University of Jinan, Ji'nan 250022, China
c.
College of Chemistry and Materials Science, and Guangdong Provincial Key Laboratory of Functional Supramolecular Coordination Materials and Applications, Jinan University, Guangzhou 510632, China
d.
State Key Laboratory of Crystal Materials, Shandong University, Ji'nan 250100, China

ism_hurm@ujn.edu.cn

ifc_yujy@ujn.edu.cn

ifc_zhouwj@ujn.edu.cn

Received Date: 1 June 2023
Revised Date: 28 August 2023
Accepted Date: 6 October 2023
Available Online: 8 October 2023

Figures(5)

For treatment of sulfion-containing wastewater, coupling the electrochemical sulfion oxidation reaction (SOR) with hydrogen evolution reaction (HER) can be an ideal way for sulfur and H₂ resources recovery. Herein, we synthesize a metal-modified carbon nanotube arrays electrode (Co@NCNTs/CC) for SOR and HER. This electrode has excellent performance for SOR and HER attributed to the unique array structure. It can achieve 99.36 mA/cm² at 0.6 V for SOR, and 10 mA/cm² at 0.067 V for HER. Density functional theory calculations verify that metal modification is able to regulate the electronic structure of carbon nanotube, which is able to optimize the adsorption of intermediates. Employed Co@NCNTs/CC as bifunctional electrodes to establish a hybrid electrolytic cell can reduce about 67% of energy consumption compared with the traditional water splitting electrolytic cell. Finally, the hybrid electrolytic cell is used to treat actual sulfion-containing wastewater, achieving the sulfur yield of 30 mg h⁻¹ cm⁻² and the hydrogen production of 0.64 mL/min.
- Sulfion oxidation reaction,
- Hydrogen evolution reaction,
- Nitrogen-doping carbon nanotube,
- Core-shell structure,
- Resource upgrade
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