Citation: Zhimin Sun, Xin-Hui Guo, Yue Zhao, Qing-Yu Meng, Li-Juan Xing, He-Lue Sun. Dynamically switchable porphyrin-based molecular tweezer for on−off fullerene recognition[J]. Chinese Chemical Letters, ;2024, 35(6): 109162. doi: 10.1016/j.cclet.2023.109162 shu

Dynamically switchable porphyrin-based molecular tweezer for on−off fullerene recognition

College of Chemistry and Materials Science, Hebei Key Laboratory of Organic Functional Molecules, Hebei Normal University, Shijiazhuang 050024, China

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xinglijuan@hebtu.edu.cn

heluesun@hebtu.edu.cn

Received Date: 2 August 2023
Revised Date: 20 September 2023
Accepted Date: 28 September 2023
Available Online: 30 September 2023

Figures(5)

Herein, a novel molecular tweezer based on 2,2′-bipyridine-bridged porphyrin subunits was constructed for efficient fullerenes recognition. The syn conformation of the molecule, which was obtained by Zn(Ⅱ) coordination, gives rise to a proper cavity to interact with fullerene guests to form a stable 1:1 complex in toluene solution. It exhibits distinct binding selectivity towards C₆₀ over C₇₀. Moreover, the fullerene recognition capacity can be adequately suppressed by importing H₂PO₄⁻ to competitively capture Zn(Ⅱ) along with syn-anti conformational conversion. Subsequently, the molecular tweezer regenerated to bind the fullerene by introducing the Ca²⁺ into the system. Significantly, the association-disassociation process can be switched reversibly and repeatedly.
- Molecular tweezer,
- Fullerene recognition,
- Supramolecular chemistry,
- Conformation conversion,
- Coordination
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