Citation: Zheng-Wei Guo, Yi Chen, Zhe-Hong Chen, Xin-Xiong Li, Shou-Tian Zheng. Precisely manipulation of core composition of core-shell-type cobalt polyoxoniobates and proton conduction study[J]. Chinese Chemical Letters, ;2024, 35(1): 109124. doi: 10.1016/j.cclet.2023.109124 shu

Precisely manipulation of core composition of core-shell-type cobalt polyoxoniobates and proton conduction study

State Key Laboratory of Photocatalysis on Energy and Environment, School of Chemistry, Fuzhou University, Fuzhou 350108, China

lxx@fzu.edu.cn

stzheng@fzu.edu.cn

Received Date: 15 July 2023
Revised Date: 22 August 2023
Accepted Date: 18 September 2023
Available Online: 19 September 2023

Figures(5)

The development of core-shell nanoclusters with controllable composition is of utmost importance as the material properties depend on their constituent elements. However, precisely tuning their compositions at the atomic scale is not easily achieved because of the difficulty of using limited macroscopic synthetic methods for atomic-level modulation. In this work, we report an interesting example of precisely regulating the core composition of an inorganic core-shell-type cobalt polyoxoniobate [Co₂₆Nb₃₆O₁₄₀]³²⁻ by controlling reaction conditions, in which the inner Co-core composition could be tune while retaining the outer Nb-shell composition of resulting product, leading to a series of isostructural species with a general formula of {Co_26-nNb_36+nO₁₄₀} (n = 0–2). These rare species not only can display good powder and single-crystal proton conductivities, but also might provide helpful and atomic-level insights into the syntheses, structures and composition modifications of inorganic amorphous core-shell heterometal oxide nanoparticles.
- Polyoxoniobate,
- Core-shell,
- Nanocluster,
- Atomic-level modulation,
- Proton conduction
1. [1]
  M. Kitano, Y. Inoue, M. Sasase, et al., Angew. Chem. Int. Ed. 57 (2018) 2648–2652. doi: 10.1002/anie.201712398
2. [2]
  X. Cui, W. Li, K. Junge, et al., Angew. Chem. Int. Ed. 59 (2020) 7501–7507. doi: 10.1002/anie.201915526
3. [3]
  H. Xiao, B. Liu, L. Qiu, et al., Angew. Chem. Int. Ed. 61 (2022) e202115136. doi: 10.1002/anie.202115136
4. [4]
  D.Y. Liu, N.W. Yang, Q. Zeng, et al., Chin. Chem. Lett. 32 (2021) 3288–3297. doi: 10.1016/j.cclet.2021.04.053
5. [5]
  H. Dong, L.D. Sun, L.D. Li, et al., J. Am. Chem. Soc. 139 (2017) 18492–18495. doi: 10.1021/jacs.7b11836
6. [6]
  Y. Xiong, Y. Yang, F.J. DiSalvo, H.D. Abruña, J. Am. Chem. Soc. 140 (2018) 7248–7255. doi: 10.1021/jacs.8b03365
7. [7]
  C. Siefe, R.D. Mehlenbacher, C.S. Peng, et al., J. Am. Chem. Soc. 141 (2019) 16997–17005. doi: 10.1021/jacs.9b09571
8. [8]
  G. Liu, W. Zhou, Y. Ji, et al., J. Am. Chem. Soc. 143 (2021) 11262–11270. doi: 10.1021/jacs.1c05856
9. [9]
  S.F. Tan, G. Bisht, U. Anand, et al., J. Am. Chem. Soc. 140 (2018) 11680–11685. doi: 10.1021/jacs.8b05217
10. [10]
  S.T. Hunt, Y. Román-Leshkov, Acc. Chem. Res. 51 (2018) 1054–1062. doi: 10.1021/acs.accounts.7b00510
11. [11]
  Z.W. Qiu, Y.T. Xue, J.Y. Li, et al., Chin. Chem. Lett. 32 (2021) 2807–2811. doi: 10.1016/j.cclet.2021.02.029
12. [12]
  Z. Li, R. Wang, J. Xue, et al., J. Am. Chem. Soc. 141 (2019) 17610–17616. doi: 10.1021/jacs.9b06796
13. [13]
  J. Guan, S. Yang, T. Liu, et al., Angew. Chem. Int. Ed. 60 (2021) 21899–21904. doi: 10.1002/anie.202107437
14. [14]
  L. Tang, A. Ma, C. Zhang, et al., Angew. Chem. Int. Ed. 60 (2021) 17969–17973. doi: 10.1002/anie.202106804
15. [15]
  C. Falaise, S. Khlifi, P. Bauduin, et al., Angew. Chem. Int. Ed. 60 (2021) 14146–14153. doi: 10.1002/anie.202102507
16. [16]
  Z. Wang, J.W. Liu, H.F. Su, et al., J. Am. Chem. Soc. 141 (2019) 17884–17890. doi: 10.1021/jacs.9b09460
17. [17]
  J.W. Liu, Z. Wang, Y.M. Chai, et al., Angew. Chem. Int. Ed. 58 (2019) 6276–6279. doi: 10.1002/anie.201900568
18. [18]
  J.H. Huang, Y. Si, X.Y. Dong, et al., J. Am. Chem. Soc. 143 (2021) 12439–12444. doi: 10.1021/jacs.1c05568
19. [19]
  S.S. Mal, U. Kortz, Angew. Chem. Int. Ed. 44 (2005) 3777–3780. doi: 10.1002/anie.200500682
20. [20]
  A. Mgller, M.T. Pope, A.M. Todea, et al., Angew. Chem. Int. Ed. 46 (2007) 4477–4480. doi: 10.1002/anie.200700441
21. [21]
  Z.K. Zhu, Y.Y. Lin, R.D. Lai, et al., Chin. Chem. Lett. 34 (2023) 107773. doi: 10.1016/j.cclet.2022.107773
22. [22]
  K.J. Qin, D.J. Zang, Y.G. Wei, Chin. Chem. Lett. 34 (2023) 107999. doi: 10.1016/j.cclet.2022.107999
23. [23]
  X.F. Fan, W. Pang, H. Feng, et al., Chin. Chem. Lett. 33 (2022) 2783–2798. doi: 10.1016/j.cclet.2021.12.057
24. [24]
  Y. Chen, Z.W. Guo, X.X. Li, S.T. Zheng, G.Y. Yang, CCS Chem. 4 (2022) 1305–1314. doi: 10.31635/ccschem.021.202100774
25. [25]
  Z. Li, Z.H. Lv, H. Yu, et al., CCS Chem. 4 (2022) 2938–2945. doi: 10.31635/ccschem.021.202101573
26. [26]
  O. Renier, C. Falaise, H. Neal, K. Kozma, M. Nyman, Angew. Chem. Int. Ed. 55 (2016) 13480–13484. doi: 10.1002/anie.201607151
27. [27]
  X. Fang, P. Kogerler, Y. Furukawa, M. Speldrich, M. Luban, Angew. Chem. Int. Ed. 50 (2011) 5212–5216. doi: 10.1002/anie.201008225
28. [28]
  Z. Li, L.D. Lin, H. Yu, X.X. Li, S.T. Zheng, Angew. Chem. Int. Ed. 57 (2018) 15777–15781. doi: 10.1002/anie.201810074
29. [29]
  C. Busche, L. Vilá-Nadal, J. Yan, et al., Nature 515 (2014) 545–549. doi: 10.1038/nature13951
30. [30]
  Z.W. Guo, L.H. Lin, J.P. Ye, et al., Angew. Chem. Int. Ed. 62 (2023) e202305260. doi: 10.1002/anie.202305260
31. [31]
  I.D. Brown, D. Altermatt, Acta Crystallogr. Sect. B Struct. Crystallogr. Cryst. Chem. 41 (1985) 244–247. doi: 10.1107/S0108768185002063
32. [32]
  B. Tiwari, S. Ram, P. Banerji, ACS Sustain. Chem. Eng. 6 (2018) 16298–16307. doi: 10.1021/acssuschemeng.8b03197
33. [33]
  S. Ram, Acta Mater. 49 (2001) 2297–2307. doi: 10.1016/S1359-6454(01)00113-6
34. [34]
  S. Ram, J. Mater. Sci. 35 (2000) 3561–3571. doi: 10.1023/A:1004861413037
35. [35]
  S. Ram, Mater. Sci. Eng. A304-306 (2001) 923–927.
36. [36]
  H. Ma, B. Liu, B. Li, et al., J. Am. Chem. Soc. 138 (2016) 5897–5903. doi: 10.1021/jacs.5b13490
37. [37]
  Z. Li, X.X. Li, T. Yang, Z.W. Cai, S.T. Zheng, Angew. Chem. Int. Ed. 56 (2017) 2664–2669. doi: 10.1002/anie.201612046
38. [38]
  J.C. Liu, Q. Han, L.J. Chen, et al., Angew. Chem. Int. Ed. 57 (2018) 8416–8420. doi: 10.1002/anie.201803649
39. [39]
  R. Tsunashima, Y. Iwamoto, Y. Baba, Angew. Chem. Int. Ed. 53 (2014) 11228–11231. doi: 10.1002/anie.201406223
40. [40]
  R. Tsunashima, I. Nakamura, R. Oue, et al., Dalton Trans. 46 (2017) 12619–12624. doi: 10.1039/C7DT02623D
1. [1]
  Shuangliang Xie , Yuyue Chen , Qing He , Liang Chen , Jikun Yang , Shiqing Deng , Yimei Zhu , He Qi . Relaxor antiferroelectric-relaxor ferroelectric crossover in NaNbO₃-based lead-free ceramics for high-efficiency large-capacitive energy storage. Chinese Chemical Letters, 2024, 35(7): 108871-. doi: 10.1016/j.cclet.2023.108871
2. [2]
  Min Song , Qian Zhang , Tao Shen , Guanyu Luo , Deli Wang . Surface reconstruction enabled o-PdTe@Pd core-shell electrocatalyst for efficient oxygen reduction reaction. Chinese Chemical Letters, 2024, 35(8): 109083-. doi: 10.1016/j.cclet.2023.109083
3. [3]
  Shaonan Tian , Yu Zhang , Qing Zeng , Junyu Zhong , Hui Liu , Lin Xu , Jun Yang . Core-shell gold-copper nanoparticles: Evolution of copper shells on gold cores at different gold/copper precursor ratios. Chinese Journal of Structural Chemistry, 2023, 42(11): 100160-100160. doi: 10.1016/j.cjsc.2023.100160
4. [4]
  Hengying Xiang , Nanping Deng , Lu Gao , Wen Yu , Bowen Cheng , Weimin Kang . 3D core-shell nanofibers framework and functional ceramic nanoparticles synergistically reinforced composite polymer electrolytes for high-performance all-solid-state lithium metal battery. Chinese Chemical Letters, 2024, 35(8): 109182-. doi: 10.1016/j.cclet.2023.109182
5. [5]
  Yuan Zhang , Shenghao Gong , A.R. Mahammed Shaheer , Rong Cao , Tianfu Liu . Plasmon-enhanced photocatalytic oxidative coupling of amines in the air using a delicate Ag nanowire@NH₂-UiO-66 core-shell nanostructures. Chinese Chemical Letters, 2024, 35(4): 108587-. doi: 10.1016/j.cclet.2023.108587
6. [6]
  Guo-Hong Gao , Run-Ze Zhao , Ya-Jun Wang , Xiao Ma , Yan Li , Jian Zhang , Ji-Sen Li . Core–shell heterostructure engineering of CoP nanowires coupled NiFe LDH nanosheets for highly efficient water/seawater oxidation. Chinese Chemical Letters, 2024, 35(8): 109181-. doi: 10.1016/j.cclet.2023.109181
7. [7]
  Yunfa Dong , Shijie Zhong , Yuhui He , Zhezhi Liu , Shengyu Zhou , Qun Li , Yashuai Pang , Haodong Xie , Yuanpeng Ji , Yuanpeng Liu , Jiecai Han , Weidong He . Modification strategies for non-aqueous, highly proton-conductive benzimidazole-based high-temperature proton exchange membranes. Chinese Chemical Letters, 2024, 35(4): 109261-. doi: 10.1016/j.cclet.2023.109261
8. [8]
  Guoliang Liu , Zhiqiang Liu , Anmin Zheng . Modulation of zeolite surface realizes dynamic copper species redispersion. Chinese Journal of Structural Chemistry, 2024, 43(6): 100308-100308. doi: 10.1016/j.cjsc.2024.100308
9. [9]
  Jian Ji , Jie Yan , Honggen Peng . Modulation of dinuclear site by orbital coupling to boost catalytic performance. Chinese Journal of Structural Chemistry, 2024, 43(8): 100360-100360. doi: 10.1016/j.cjsc.2024.100360
10. [10]
  Bei Li , Zhaoke Zheng . In situ monitoring of the spatial distribution of oxygen vacancies at the single-particle level. Chinese Journal of Structural Chemistry, 2024, 43(10): 100331-100331. doi: 10.1016/j.cjsc.2024.100331
11. [11]
  Lei Wang , Jun-Jie Wu , Chang-Cun Yan , Wan-Ying Yang , Zong-Lu Che , Xin-Yu Xia , Xue-Dong Wang , Liang-Sheng Liao . Near-infrared organic lasers with ultra-broad emission bands by simultaneously harnessing four-level and six-level systems. Chinese Chemical Letters, 2024, 35(8): 109365-. doi: 10.1016/j.cclet.2023.109365
12. [12]
  Jiayao Li , Xinru Peng , Shiwei Yin , Changwei Wang , Yirong Mo . Metastability of π-π stacking between the closed-shell ions of like charges. Chinese Journal of Structural Chemistry, 2024, 43(5): 100213-100213. doi: 10.1016/j.cjsc.2023.100213
13. [13]
  Chengde Wang , Liping Huang , Shanshan Wang , Lihao Wu , Yi Wang , Jun Dong . A distinction of gliomas at cellular and tissue level by surface-enhanced Raman scattering spectroscopy. Chinese Chemical Letters, 2024, 35(5): 109383-. doi: 10.1016/j.cclet.2023.109383
14. [14]
  Qian-Qian Tang , Li-Fang Feng , Zhi-Peng Li , Shi-Hao Wu , Long-Shuai Zhang , Qing Sun , Mei-Feng Wu , Jian-Ping Zou . Single-atom sites regulation by the second-shell doping for efficient electrochemical CO₂ reduction. Chinese Chemical Letters, 2024, 35(9): 109454-. doi: 10.1016/j.cclet.2023.109454
15. [15]
  Mingjiao Lu , Zhixing Wang , Gui Luo , Huajun Guo , Xinhai Li , Guochun Yan , Qihou Li , Xianglin Li , Ding Wang , Jiexi Wang . Boosting the performance of LiNi_0.90Co_0.06Mn_0.04O₂ electrode by uniform Li₃PO₄ coating via atomic layer deposition. Chinese Chemical Letters, 2024, 35(5): 108638-. doi: 10.1016/j.cclet.2023.108638
16. [16]
  Jiahao Xie , Jin Liu , Bin Liu , Xin Meng , Zhuang Cai , Xiaoqin Xu , Cheng Wang , Shijie You , Jinlong Zou . Yolk shell-structured pyrite-type cobalt sulfide grafted by nitrogen-doped carbon-needles with enhanced electrical conductivity for oxygen electrocatalysis. Chinese Chemical Letters, 2024, 35(7): 109236-. doi: 10.1016/j.cclet.2023.109236
17. [17]
  Ruiying Liu , Li Zhao , Baishan Liu , Jiayuan Yu , Yujie Wang , Wanqiang Yu , Di Xin , Chaoqiong Fang , Xuchuan Jiang , Riming Hu , Hong Liu , Weijia Zhou . Modulating pollutant adsorption and peroxymonosulfate activation sites on Co3O4@N,O doped-carbon shell for boosting catalytic degradation activity. Chinese Journal of Structural Chemistry, 2024, 43(8): 100332-100332. doi: 10.1016/j.cjsc.2023.100332

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(230)
HTML views(10)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142