Citation: Mei-Chen Liu, Qing-Song Liu, Yi-Zhou Quan, Jia-Ling Yu, Gang Wu, Xiu-Li Wang, Yu-Zhong Wang. Phosphorus-silicon-integrated electrolyte additive boosts cycling performance and safety of high-voltage lithium-ion batteries[J]. Chinese Chemical Letters, ;2024, 35(8): 109123. doi: 10.1016/j.cclet.2023.109123 shu

Phosphorus-silicon-integrated electrolyte additive boosts cycling performance and safety of high-voltage lithium-ion batteries

The Collaborative Innovation Center for Eco-Friendly and Fire-Safety Polymeric Materials (MoE), National Engineering Laboratory of Eco-Friendly Polymeric Materials (Sichuan), State Key Laboratory of Polymer Materials Engineering, College of Chemistry, Sichuan University, Chengdu 610064, China

gangwu@scu.edu.cn

wangxiuli@scu.edu.cn

Received Date: 23 July 2023
Revised Date: 29 August 2023
Accepted Date: 18 September 2023
Available Online: 22 September 2023

Figures(5)

Safety and energy density are significant for lithium-ion batteries (LIBs), and the flammable organic electrolyte is one of the most critical causes of the safety problem of LIBs. Although LiNi_0.8Co_0.1Mn_0.1O₂ (NCM811) cathode with high capacity can improve the energy density, the interface stability between NCM811 cathode and electrolytes needs to be improved. Herein, we report a multifunctional additive, diethyl(2-(triethoxysilyl)ethyl)phosphonate (DETSP), which can suppress the flammability of the electrolyte and enhance the cycling stability of NCM811 cathode with a capacity retention of 89.9% after 400 cycles at 1 C, while that of the blank electrolyte is merely 61.3%. In addition, DETSP is compatible well with the graphite anode without impairing the electrochemical performances. Significantly, the performance and safety of NCM811/graphite full cells are also improved. Experimental and theoretical results demonstrate that DETSP can scavenge acidic byproducts and is beneficial to form a stable cathode-electrolyte interface (CEI). Accordingly, DETSP can potentially be an effective solution to ameliorating the safety of the commercial electrolyte and improving the stability of high-voltage cathodes.
- Electrolyte additive,
- NCM,
- Lithium-ion batteries,
- Safety,
- Cathode-electrolyte interface
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