Citation: Mengjia Luo, Xiaohui Li, Xingxing Jiang, Zheshuai Lin, Zhengyang Zhou. The compatibly large nonlinear optical effect and high laser-induced damage threshold in a thiophosphate CsInP₂S₇ constructed with [P₂S₇]^4- and [InS₆]^9-[J]. Chinese Chemical Letters, ;2024, 35(1): 109108. doi: 10.1016/j.cclet.2023.109108 shu

The compatibly large nonlinear optical effect and high laser-induced damage threshold in a thiophosphate CsInP₂S₇ constructed with [P₂S₇]^4- and [InS₆]^9-

Mengjia Luo ^{a, 1} ,
Xiaohui Li ^{d, 1} ,
Xingxing Jiang ^{c, *,} ,
Zheshuai Lin ^c ,
Zhengyang Zhou ^{b, *,}

a.
Nanchang Key Laboratory of Photoelectric Conversion and Energy Storage Materials, Nanchang Institute of Technology, Nanchang 330099, China
b.
Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China
c.
Functional Crystals Lab, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China
d.
Institute of Experimental Physics, Free University Berlin, Berlin D-14195, Germany

xxjiang@mail.ipc.ac.cn

zhouzhengyang@mail.sic.ac.cn

Received Date: 11 July 2023
Revised Date: 20 August 2023
Accepted Date: 14 September 2023
Available Online: 16 September 2023

Figures(4)

It is challenging to cooperatively improve the nonlinear optical (NLO) efficiency and the laser-induced damage threshold (LIDT). This work reports a novel IR NLO materials CsInP₂S₇ (CIPS) designed by combination the strategies of alkali metals substitution and microscopic NLO units PS₄ introduction based on AgGaS₂. CIPS was composed of strongly distorted [InS₆]^9- octahedra and [P₂S₇]^4- dimers constructed by corner-sharing [PS₄]^3-, which increase the NLO efficiency and decrease thermal expansion anisotropy simultaneously. Compared with AgGaS₂, CIPS exhibited strong phase matchable NLO response ca. 1.1 × AGS@2.1 µm, high LIDT ca. 20.8 × AgGaS₂, and IR transparency up to 15.3 µm. Structural analysis and theoretical investigation confirmed that large SHG effect and ultrahigh LIDT of CIPS originated from the synergistic contribution of [InS₆]^9- octahedra and [P₂S₇]^4- dimers. These results indicate that CIPS is a promising NLO candidate in the mid-IR region, and this study provides a new approach for developing potential NLO-LIDT compatible materials.
- Infrared nonlinear optics materials,
- A novel thiophosphate,
- Structure design,
- Structure-activity relationship,
- High laser-induced damage threshold
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The compatibly large nonlinear optical effect and high laser-induced damage threshold in a thiophosphate CsInP2S7 constructed with [P2S7]4- and [InS6]9-

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通讯作者: 陈斌, bchen63@163.com

The compatibly large nonlinear optical effect and high laser-induced damage threshold in a thiophosphate CsInP₂S₇ constructed with [P₂S₇]^4- and [InS₆]^9-