Citation: Chang Liu, Zirui Song, Xinglan Deng, Shihong Xu, Renji Zheng, Wentao Deng, Hongshuai Hou, Guoqiang Zou, Xiaobo Ji. Interfacial/bulk synergetic effects accelerating charge transferring for advanced lithium-ion capacitors[J]. Chinese Chemical Letters, ;2024, 35(6): 109081. doi: 10.1016/j.cclet.2023.109081 shu

Interfacial/bulk synergetic effects accelerating charge transferring for advanced lithium-ion capacitors

Chang Liu ^a ,
Zirui Song ^b ,
Xinglan Deng ^{b, *,} ,
Shihong Xu ^{c, *,} ,
Renji Zheng ^c ,
Wentao Deng ^b ,
Hongshuai Hou ^b ,
Guoqiang Zou ^b ,
Xiaobo Ji ^b

a.
School of Chemistry and Chemical Engineering, Hunan Institute of Engineering, Xiangtan 411104, China
b.
College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China
c.
Key Laboratory of Hunan Province for Clean and Efficient Utilization of Strategic Calcium-Containing Mineral Resources, School of Minerals Processing and Bioengineering, Central South University, Changsha 410083, China

dengxinglan1124@163.com

shihong.xu@csu.edu.cn

Received Date: 6 August 2023
Revised Date: 26 August 2023
Accepted Date: 10 September 2023
Available Online: 12 September 2023

Figures(4)

The exploration of advanced materials through rational structure/phase design is the key to develop high-performance lithium-ion capacitors (LICs). However, high complexity of material preparation and difficulty in quantity production largely hinder the further development. Herein, Cu₅FeS_4-x/C (CFS@C) heterojunction with rich sulfur vacancies has successfully achieved from natural bornite, presenting low cost-effective and bulk-production prospect. Density functional theory (DFT) calculations indicate that rich vacancies in bulk phase can decrease band gap of bornite and thus improve its intrinsic electron conductivity, as well as the heterojunction spontaneously evokes a built-in electric field between its interfacial region, largely reducing the migration barrier from 1.27 eV to 0.75 eV. Benefited from these merits, the CFS@C electrodes deliver outperformed lithium storage performance, e.g., high reversible capacity (822.4 mAh/g at 0.1 A/g), excellent cycling stability (up to 820 cycles at 2 A/g and 540 cycles at 5 A/g with respective capacity retention of over or nearly 100%). With CFS@C as anode and porous carbon nanosheets (PCS) as cathode, the assembled CFS@C//PCS LIC full cells exhibit high energy/power density characteristics of 139.2 Wh/kg at 2500 W/kg. This work is expected to offer significant insights into structure modifications/devising toward natural minerals for advanced energy-storage systems.
- Bulk/interfacial modification,
- Heterostructure,
- Sulfur vacancies,
- Lithium ion capacitors,
- Capacitors
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