Citation: Zhikang Wu, Guoyong Dai, Qi Li, Zheyu Wei, Shi Ru, Jianda Li, Hongli Jia, Dejin Zang, Mirjana Čolović, Yongge Wei. POV-based molecular catalysts for highly efficient esterification of alcohols with aldehydes as acylating agents[J]. Chinese Chemical Letters, ;2024, 35(8): 109061. doi: 10.1016/j.cclet.2023.109061 shu

POV-based molecular catalysts for highly efficient esterification of alcohols with aldehydes as acylating agents

Zhikang Wu ^{a, 1} ,
Guoyong Dai ^{a, 1} ,
Qi Li ^a ,
Zheyu Wei ^a ,
Shi Ru ^a ,
Jianda Li ^a ,
Hongli Jia ^{a, b, *,} ,
Dejin Zang ^{a, c, *,} ,
Mirjana Čolović ^{d, **,} ,
Yongge Wei ^{a, b, *,}

a.
Key Lab of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, China
b.
State Key Laboratory of Natural and Biomimetic Drugs, Peking University, Beijing 100191, China
c.
Institute of Materia Medica, Shandong First Medical University & Shandong Academy of Medical Sciences, Ji'nan 250117, China
d.
University of Belgrade, ‟Vinča‟ Institute of Nuclear Sciences-National Institute of thе Republic of Serbia, Department of Physical Chemistry, Belgrade 11351, Serbia

^**

jiahongli@bjmu.edu.cn

zangdejin_lm@163.com

colovicm@vin.bg.ac.rs

yonggewei@tsinghua.edu.cn

Received Date: 12 July 2023
Revised Date: 16 August 2023
Accepted Date: 7 September 2023
Available Online: 9 September 2023

Figures(8)

The selective oxidative esterification of aldehydes with alcohols to the corresponding esters has been one of the hot spots in scientific research and industrial synthesis. However, the application of precious metal catalytic systems is limited by their complicated synthetic steps and high cost. Thus a highly efficient, green, recyclable selective synthesis method of esters catalyzed by polyoxovanadate (POV)-based molecular catalysts has been developed in this paper. The results show that supramolecular interaction between POV and 1,3-dibenzylimidazolium bromide (Act₂Im) can efficiently convert alcohols and aldehydes to the corresponding esters in high yield under much milder conditions. Mechanistic insight is also provided based on the control experiments, single crystal X-ray diffraction and cyclic voltammetry studies.
- POV,
- Oxidation,
- Supramolecular,
- Esterification,
- Catalyst
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