Citation: Sen Qiao, Kunquan Chen, Qiang Liu, Zhixiang Wang, Xiangyu Chen. Charge transfer complex enabled photoreduction of ether phosphonium salts for the selective oxyalkylation of enamides[J]. Chinese Chemical Letters, ;2024, 35(2): 108979. doi: 10.1016/j.cclet.2023.108979 shu

Charge transfer complex enabled photoreduction of ether phosphonium salts for the selective oxyalkylation of enamides

Sen Qiao ^{a, 1} ,
Kunquan Chen ^{a, 1} ,
Qiang Liu ^{a, *,} ,
Zhixiang Wang ^{a, b, *,} ,
Xiangyu Chen ^{a, b, *,}

a.
School of Chemical Sciences, University of the Chinese Academy of Sciences, Beijing 100049, China
b.
Binzhou Institute of Technology, Weiqiao-UCAS Science and Technology Park, Binzhou 256606, China

liuqiang@ucas.ac.cn

zxwang@ucas.ac.cn

chenxiangyu20@ucas.ac.cn

Received Date: 31 May 2023
Revised Date: 9 August 2023
Accepted Date: 24 August 2023
Available Online: 27 August 2023

Figures(4)

A charge transfer complex (CTC)-enabled photoreduction of ether phosphonium salts for the generation of oxyalkyl radicals was described. The photoreduction provides a convenient method to achieve selective oxyalkylation of enamides with broad substrate scope. The method features operational simplicity, mild and inherent green conditions.
- Enamides,
- Phosphonium salts,
- Ethers,
- Charge transfer complex,
- Visible light
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