Citation: Yu Han, Liyun Zhou, Chengyu Wang, Shangti Feng, Rong Ma, Jie-Ping Wan. Recent advances in visible light-mediated chemical transformations of enaminones[J]. Chinese Chemical Letters, ;2024, 35(2): 108977. doi: 10.1016/j.cclet.2023.108977 shu

Recent advances in visible light-mediated chemical transformations of enaminones

Yu Han ^{a, b} ,
Liyun Zhou ^a ,
Chengyu Wang ^{b, *,} ,
Shangti Feng ^{c, *,} ,
Rong Ma ^b ,
Jie-Ping Wan ^{a, *,}

a.
College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, China
b.
School of Chemistry and Chemical Engineering, Linyi University, Linyi 276000, China
c.
Linyi Sanfeng Chemical Co., Ltd., Linyi 276000, China

wangchengyu@lyu.edu.cn

fsti666@163.com

wanjieping@jxnu.edu.cn

wanjieping@126.com

Received Date: 5 June 2023
Revised Date: 21 August 2023
Accepted Date: 24 August 2023
Available Online: 26 August 2023

Figures(30)

Enaminones, which possesses both the nucleophilic enamine as well as electrophilic enone structures, are well known versatile building blocks in organic synthesis. Meanwhile, visible light-mediated reactions have emerged as useful synthetic strategy with enhanced sustainability. Around the last decade, various photochemical transformations of enaminones have been developed to construct cyclic or acyclic compounds. In this review, we describe the recent advances in visible light-mediated chemical transformations of enaminones. Detailed discussion on the reaction mechanism of the related reactions is given to provide guide to the reader. Finally, a summary on the existing challenges and the future outlook towards the development of practical photocatalytic reactions of enaminones is also presented.
- Enaminone,
- Visible light,
- C-H functionalization,
- C=C bond cleavage,
- Cyclization,
- Multicomponent reactions
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沈阳化工大学材料科学与工程学院沈阳 110142