Citation: Boyuan Hu, Jian Zhang, Yulin Yang, Yayu Dong, Jiaqi Wang, Wei Wang, Kaifeng Lin, Debin Xia. Dual-functional POM@IL complex modulate hole transport layer properties and interfacial charge dynamics for highly efficient and stable perovskite solar cells[J]. Chinese Chemical Letters, ;2024, 35(7): 108933. doi: 10.1016/j.cclet.2023.108933 shu

Dual-functional POM@IL complex modulate hole transport layer properties and interfacial charge dynamics for highly efficient and stable perovskite solar cells

MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, China

zhaji@hit.edu.cn

ylyang@hit.edu.cn

Received Date: 30 June 2023
Revised Date: 31 July 2023
Accepted Date: 14 August 2023
Available Online: 15 August 2023

Figures(5)

The severe interfacial charge recombination as well as the stability issues brought by the Li-TFSI still hinder the commercialization of high-performance perovskite solar cells (PSCs). Here, a polyoxometalates (POMs)-based complex, POM@ ionic liquid (IL), is synthesized and applied as an effective additive that simultaneously enhances the performance and stability of PSCs. The interactions between POM@IL complex and Li-TFSI inhibit the aggregation of Li-TFSI. The synergistic oxidation of POM@IL complex and Li-TFSI towards 2, 2′, 7, 7′-tetrakis[N, N-di(4-methoxyphenyl)amino]-9, 9'-spirobifluorene (Spiro-OMeTAD) effectively enhances the electrical properties of hole transport layer film and the photovoltaic performances of PSCs. The champion device modified with the POM@IL complex yields an excellent power conversion efficiency (PCE) of 22.73%. Moreover, the incorporation of POM@IL improves the humidity stability of PSCs. After storing under high humidity conditions (25 ℃, 60% RH) for 1200 h, the POM@IL modified device retained a remarkable 81.2% of its initial PCE. This work provides new insight into constructing POMs-based materials for high-performance photovoltaic devices.
- Polyoxometalates,
- Ionic liquid,
- Perovskite solar cells,
- Energy alignment,
- Humidity stability
1. [1]
  Best research-cell efficiency chart, 2023, https://www.nrel.gov/pv/cell-efficiency.html, accessed 29 January 2023.
2. [2]
  S. Zhan, W. Din, Z. S, et al., Adv. Powder Mater. 1 (2022) 100036. doi: 10.1016/j.apmate.2022.100036
3. [3]
  Z. Li, M. Wu, L. Yang, et al., Adv. Funct. Mater. 33 (2023) 2212606. doi: 10.1002/adfm.202212606
4. [4]
  N. Li, A. Feng, X. Guo, et al., Adv. Energy Mater. 12 (2022) 2103241. doi: 10.1002/aenm.202103241
5. [5]
  X. Guo, N. Li, Y. Xu, et al., Adv. Funct. Mater. 33 (2023) 2213995. doi: 10.1002/adfm.202213995
6. [6]
  T. Webb, X. Liu, J.E.W. Robert, et al., Adv. Energy Mater. 12 (2022) 2200666. doi: 10.1002/aenm.202200666
7. [7]
  T. Zhang, F. Wang, H.B. Kim, et al., Science 377 (2022) 495–501. doi: 10.1126/science.abo2757
8. [8]
  P. Yan, D. Yang, H. Wang, et al., Energy Environ. Sci. 15 (2022) 3630–3669. doi: 10.1039/d2ee01256a
9. [9]
  B. Tan, S.R. Raga, A.S.R. Chesman, et al., Adv. Energy Mater. 9 (2019) 1901519. doi: 10.1002/aenm.201901519
10. [10]
  Y. Liu, Z. Hong, Q. Chen, Adv. Mater. 28 (2016) 440–446. doi: 10.1002/adma.201504293
11. [11]
  L. Caliò, M. Salado, S. Kazim, et al., Joule 2 (2018) 1800–1815. doi: 10.1016/j.joule.2018.06.012
12. [12]
  F.M. Rombach, S.A. Haque, T.J. Macdonald, Energy Environ. Sci. 14 (2021) 5161–5190. doi: 10.1039/d1ee02095a
13. [13]
  C.M. Wolff, P. Caprioglio, M. Stolterfoht, et al., Adv. Mater. 31 (2019) 1902762. doi: 10.1002/adma.201902762
14. [14]
  I. Gelmetti, N. Montcada, A. Pérez-Rodríguez, et al., Energy Environ. Sci. 12 (2019) 1309–1316. doi: 10.1039/c9ee00528e
15. [15]
  T. Kirchartz, Philos. Trans. R. Soc. A 377 (2019) 20180286. doi: 10.1098/rsta.2018.0286
16. [16]
  A. Abate, T. Leijtens, S. Pathak, et al., Phys. Chem. Chem. Phys. 15 (2013) 2572. doi: 10.1039/c2cp44397j
17. [17]
  H.J. Snaith, M. Grätzel, Appl. Phys. Lett. 89 (2006) 262114. doi: 10.1063/1.2424552
18. [18]
  U.B. Cappel, T. Daeneke, U. Bach, Nano Lett. 12 (2012) 4925–4931. doi: 10.1021/nl302509q
19. [19]
  R.L. Forward, K.Y. Chen, D.M. Weekes, et al., ACS Energy Lett. 4 (2019) 2547–2551. doi: 10.1021/acsenergylett.9b01766
20. [20]
  Z. Li, C. Xiao, Y. Yang, et al., Energy Environ. Sci. 10 (2017) 1234–1242. doi: 10.1039/C7EE00358G
21. [21]
  F. Lin, J. Luo, Y. Zhang, et al., J. Mater. Chem. A 11 (2023) 2544–2567. doi: 10.1039/d2ta08597f
22. [22]
  Y. Liu, T. Liu, X. Guo, et al., Adv. Funct. Mater. 33 (2023) 2210028. doi: 10.1002/adfm.202210028
23. [23]
  Q. Lou, G. Lou, H. Guo, et al., Adv. Energy Mater. 12 (2022) 2201344. doi: 10.1002/aenm.202201344
24. [24]
  J. Xia, Y. Zhang, C. Xiao, et al., Joule 6 (2022) 1689–1709. doi: 10.1016/j.joule.2022.05.012
25. [25]
  Y. Han, G. Zhang, H. Xie, et al., Nano Energy 96 (2022) 107072. doi: 10.1016/j.nanoen.2022.107072
26. [26]
  D.L. Long, E. Burkholder, L. Cronin, Chem. Soc. Rev. 36 (2007) 105. doi: 10.1039/B502666K
27. [27]
  M.R. Horn, A. Singh, S. Alomari, et al., Energy Environ. Sci. 14 (2021) 1652–1700. doi: 10.1039/d0ee03407j
28. [28]
  J. Duan, H. Shabbir, Z. Chen, et al., J. Am. Chem. Soc. 145 (2023) 7268–7277. doi: 10.1021/jacs.2c12992
29. [29]
  L. Liu, Z. Wu, Z. Zheng, et al., Chin. Chem. Lett. 33 (2022) 4326–4330. doi: 10.1016/j.cclet.2021.12.031
30. [30]
  A.V. Anyushin, A. Kondinski, T.N. Parac-Vogt, Chem. Soc. Rev. 49 (2020) 382–432. doi: 10.1039/c8cs00854j
31. [31]
  N.I. Gumerova, A. Rompel, Nat. Rev. Chem. 2 (2018) 0112. doi: 10.1038/s41570-018-0112
32. [32]
  Q. Wang, B. Xu, Y. Wang, et al., Inorg. Chem. 60 (2021) 7753–7761. doi: 10.1021/acs.inorgchem.1c00135
33. [33]
  M. Martin-Sabi, J. Soriano-López, R.S. Winter, et al., Nat. Catal. 1 (2018) 208–213. doi: 10.1038/s41929-018-0037-1
34. [34]
  Q. Kang, Q. Liao, C. Yang, et al., Adv. Energy Mater. 12 (2022) 2103892. doi: 10.1002/aenm.202103892
35. [35]
  A. Misra, I.F. Castillo, D. P, et al., Angew. Chem. Int. Ed. 57 (2018) 14926–14931. doi: 10.1002/anie.201809893
36. [36]
  S. Herrmann, L.D. Matteis, J.M. Fuente, et al., Angew. Chem. Int. Ed. 56 (2017) 1667–1670. doi: 10.1002/anie.201611072
37. [37]
  M. Zhang, A.M. Zhang, X.X. Wang, et al., J. Mater. Chem. A 6 (2018) 8735–8741. doi: 10.1039/c8ta01062e
38. [38]
  J. Meng, M. Lei, C. Lai, et al., Angew. Chem. Int. Ed. 60 (2021) 23256–23266. doi: 10.1002/anie.202108143
39. [39]
  J. Meng, F. Chu, J. Hu, et al., Adv. Funct. Mater. 29 (2019) 1902220. doi: 10.1002/adfm.201902220
40. [40]
  B. Hu, J. Zhang, Y. Yang, et al., ACS Appl. Mater. Interfaces 14 (2022) 17610–17620. doi: 10.1021/acsami.1c24337
41. [41]
  F. Wu, S. Mabrouk, M. Han, et al., J. Energy Chem. 76 (2023) 414–420. doi: 10.1016/j.jechem.2022.10.011
1. [1]
  Chen Lu , Zefeng Yu , Jing Cao . Advancement in porphyrin/phthalocyanine compounds-based perovskite solar cells. Chinese Journal of Structural Chemistry, 2024, 43(3): 100240-100240. doi: 10.1016/j.cjsc.2024.100240
2. [2]
  Tiantian Gong , Yanan Chen , Shuo Wang , Miao Wang , Junwei Zhao . Rigid-flexible-ligand-ornamented lanthanide-incorporated selenotungstates and photoluminescence properties. Chinese Journal of Structural Chemistry, 2024, 43(9): 100370-100370. doi: 10.1016/j.cjsc.2024.100370
3. [3]
  Kangrong Yan , Ziqiu Shen , Yanchun Huang , Benfang Niu , Hongzheng Chen , Chang-Zhi Li . Curing the vulnerable heterointerface via organic-inorganic hybrid hole transporting bilayers for efficient inverted perovskite solar cells. Chinese Chemical Letters, 2024, 35(6): 109516-. doi: 10.1016/j.cclet.2024.109516
4. [4]
  Bo Yang , Pu-An Lin , Tingwei Zhou , Xiaojia Zheng , Bing Cai , Wen-Hua Zhang . Facile surface regulation for highly efficient and thermally stable perovskite solar cells via chlormequat chloride. Chinese Chemical Letters, 2024, 35(10): 109425-. doi: 10.1016/j.cclet.2023.109425
5. [5]
  Xinyu Yu , Fei Wu , Xianglang Sun , Linna Zhu , Baoyu Xia , Zhong'an Li . Low-cost dopant-free fluoranthene-based branched hole transporting materials for efficient and stable n-i-p perovskite solar cells. Chinese Chemical Letters, 2024, 35(10): 109821-. doi: 10.1016/j.cclet.2024.109821
6. [6]
  Chenghao Ge , Peng Wang , Pei Yuan , Tai Wu , Rongjun Zhao , Rong Huang , Lin Xie , Yong Hua . Tuning hot carrier transfer dynamics by perovskite surface modification. Chinese Chemical Letters, 2024, 35(10): 109352-. doi: 10.1016/j.cclet.2023.109352
7. [7]
  Chen Lian , Si-Han Zhao , Hai-Lou Li , Xinhua Cao . A giant Ce-containing poly(tungstobismuthate): Synthesis, structure and catalytic performance for the decontamination of a sulfur mustard simulant. Chinese Chemical Letters, 2024, 35(10): 109343-. doi: 10.1016/j.cclet.2023.109343
8. [8]
  Chi Li , Peng Gao . Is dipole the only thing that matters for inverted perovskite solar cells?. Chinese Journal of Structural Chemistry, 2024, 43(6): 100324-100324. doi: 10.1016/j.cjsc.2024.100324
9. [9]
  Huipeng Zhao , Xiaoqiang Du . Polyoxometalates as the redox anolyte for efficient conversion of biomass to formic acid. Chinese Journal of Structural Chemistry, 2024, 43(2): 100246-100246. doi: 10.1016/j.cjsc.2024.100246
10. [10]
  Luyu Zhang , Zirong Dong , Shuai Yu , Guangyue Li , Weiwen Kong , Wenjuan Liu , Haisheng He , Yi Lu , Wei Wu , Jianping Qi . Ionic liquid-based in situ dynamically self-assembled cationic lipid nanocomplexes (CLNs) for enhanced intranasal siRNA delivery. Chinese Chemical Letters, 2024, 35(7): 109101-. doi: 10.1016/j.cclet.2023.109101
11. [11]
  Zhenyu Hu , Zhenchun Yang , Shiqi Zeng , Kun Wang , Lina Li , Chun Hu , Yubao Zhao . Cationic surface polarization centers on ionic carbon nitride for efficient solar-driven H₂O₂ production and pollutant abatement. Chinese Chemical Letters, 2024, 35(10): 109526-. doi: 10.1016/j.cclet.2024.109526
12. [12]
  Yuqing Wang , Zhemin Li , Qingjun Lu , Qizhao Li , Jiaxin Luo , Chengjie Li , Yongshu Xie . Solar cells based on doubly concerted companion dyes with the efficiencies modulated by inserting an ethynyl group at different positions. Chinese Chemical Letters, 2024, 35(5): 109093-. doi: 10.1016/j.cclet.2023.109093
13. [13]
  Shaonan Liu , Shuixing Dai , Minghua Huang . The impact of ester groups on 1,8-naphthalimide electron transport material in organic solar cells. Chinese Journal of Structural Chemistry, 2024, 43(6): 100277-100277. doi: 10.1016/j.cjsc.2023.100277
14. [14]
  Yikun Wang , Qiaomei Chen , Shijie Liang , Dongdong Xia , Chaowei Zhao , Christopher R. McNeill , Weiwei Li . Near-infrared double-cable conjugated polymers based on alkyl linkers with tunable length for single-component organic solar cells. Chinese Chemical Letters, 2024, 35(4): 109164-. doi: 10.1016/j.cclet.2023.109164
15. [15]
  Yixia Zhang , Caili Xue , Yunpeng Zhang , Qi Zhang , Kai Zhang , Yulin Liu , Zhaohui Shan , Wu Qiu , Gang Chen , Na Li , Hulin Zhang , Jiang Zhao , Da-Peng Yang . Cocktail effect of ionic patch driven by triboelectric nanogenerator for diabetic wound healing. Chinese Chemical Letters, 2024, 35(8): 109196-. doi: 10.1016/j.cclet.2023.109196
16. [16]
  Pei Cao , Yilan Wang , Lejian Yu , Miao Wang , Liming Zhao , Xu Hou . Dynamic asymmetric mechanical responsive carbon nanotube fiber for ionic logic gate. Chinese Chemical Letters, 2024, 35(6): 109421-. doi: 10.1016/j.cclet.2023.109421
17. [17]
  Qiangwei Wang , Huijiao Liu , Mengjie Wang , Haojie Zhang , Jianda Xie , Xuanwei Hu , Shiming Zhou , Weitai Wu . Observation of high ionic conductivity of polyelectrolyte microgels in salt-free solutions. Chinese Chemical Letters, 2024, 35(4): 108743-. doi: 10.1016/j.cclet.2023.108743
18. [18]
  Yuxin Wang , Zhengxuan Song , Yutao Liu , Yang Chen , Jinping Li , Libo Li , Jia Yao . Methyl functionalization of trimesic acid in copper-based metal-organic framework for ammonia colorimetric sensing at high relative humidity. Chinese Chemical Letters, 2024, 35(6): 108779-. doi: 10.1016/j.cclet.2023.108779
19. [19]
  Hongxia Li , Xiyang Wang , Du Qiao , Jiahao Li , Weiping Zhu , Honglin Li . Mechanism of nanoparticle aggregation in gas-liquid microfluidic mixing. Chinese Chemical Letters, 2024, 35(4): 108747-. doi: 10.1016/j.cclet.2023.108747
20. [20]
  Zhao Li , Huimin Yang , Wenjing Cheng , Lin Tian . Recent progress of in situ/operando characterization techniques for electrocatalytic energy conversion reaction. Chinese Chemical Letters, 2024, 35(9): 109237-. doi: 10.1016/j.cclet.2023.109237

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(86)
HTML views(3)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142