Citation: Yunlei Zhang, Yiran Liu, Wen Guan, Mengxue Cao, Yao Chen, Pengwei Huo. Strong metal-support interaction between AuPd nanoparticles and oxygen-rich defect ZrO₂ for enhanced catalytic 5-hydroxymethylfurfural oxidation[J]. Chinese Chemical Letters, ;2024, 35(2): 108932. doi: 10.1016/j.cclet.2023.108932 shu

Strong metal-support interaction between AuPd nanoparticles and oxygen-rich defect ZrO₂ for enhanced catalytic 5-hydroxymethylfurfural oxidation

Yunlei Zhang ^a ,
Yiran Liu ^a ,
Wen Guan ^a ,
Mengxue Cao ^a ,
Yao Chen ^{b, *,} ,
Pengwei Huo ^{a, *,}

a.
Institute of Green Chemistry and Chemical Technology, School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, China
b.
School of the Environment and Safety, Jiangsu University, Zhenjiang 212013, China

chenyao1390@ujs.edu.cn

huopw@ujs.edu.cn

Received Date: 11 May 2023
Revised Date: 25 July 2023
Accepted Date: 13 August 2023
Available Online: 15 August 2023

Figures(4)

The unique properties of metal oxide surfaces, crystal surfaces and defects play vital roles in biomass upgrading reactions. In this work, hierarchical porous bowl-shaped ZrO₂ (HB-ZrO₂) with mixed crystal phase was designed and employed as the support for loading AuPd bimetal with different proportions to synthesize AuPd/HB-ZrO₂ catalysts. The effects of surface chemistry, oxygen defects, bimetal interaction and metal-support interaction of AuPd/HB-ZrO₂ on catalytic performance for the selective oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA) were systematically investigated. The Au₂Pd₁/HB-ZrO₂ catalyst afforded a satisfactory FDCA yield of 99.9% from HMF oxidation using O₂ as the oxidant in water, accompanied with an excellent FDCA productivity at 97.6 mmol g⁻¹ h⁻¹. This work offers fresh insights into rationally designing efficient catalysts with oxygen-rich defects for the catalytic upgrading of biomass platform chemicals.
- 5-Hydroxymethylfurfural oxidation,
- 2,5-Furandicarboxylic acid,
- Oxygen-rich defect ZrO₂,
- AuPd bimetal,
- Bowl-shaped structure
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沈阳化工大学材料科学与工程学院沈阳 110142

Strong metal-support interaction between AuPd nanoparticles and oxygen-rich defect ZrO2 for enhanced catalytic 5-hydroxymethylfurfural oxidation

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通讯作者: 陈斌, bchen63@163.com

Strong metal-support interaction between AuPd nanoparticles and oxygen-rich defect ZrO₂ for enhanced catalytic 5-hydroxymethylfurfural oxidation