Citation: Ping Wang, Ting Wang, Ming Xu, Ze Gao, Hongyu Li, Bowen Li, Yuqi Wang, Chaoqun Qu, Ming Feng. Keplerate polyoxomolybdate nanoball mediated controllable preparation of metal-doped molybdenum disulfide for electrocatalytic hydrogen evolution in acidic and alkaline media[J]. Chinese Chemical Letters, ;2024, 35(7): 108930. doi: 10.1016/j.cclet.2023.108930 shu

Keplerate polyoxomolybdate nanoball mediated controllable preparation of metal-doped molybdenum disulfide for electrocatalytic hydrogen evolution in acidic and alkaline media

Ping Wang ^a ,
Ting Wang ^{a, *,} ,
Ming Xu ^a ,
Ze Gao ^b ,
Hongyu Li ^a ,
Bowen Li ^a ,
Yuqi Wang ^a ,
Chaoqun Qu ^{a, *,} ,
Ming Feng ^{a, *,}

a.
Key Laboratory of Functional Materials Physics and Chemistry of the Ministry of Education, Jilin Normal University, Changchun 130103, China
b.
School of Science, Changchun University of Science and Technology, Changchun 130022, China

wangt@jlnu.edu.cn

quchaoqun@jlnu.edu.cn

mingfeng@jlnu.edu.cn

Received Date: 19 June 2023
Revised Date: 31 July 2023
Accepted Date: 14 August 2023
Available Online: 18 August 2023

Figures(5)

Rationally designed novel cost-effective hydrogen evolution reaction (HER) electrocatalysts with controlled surface composition and advanced structural superiority is extremely critical to optimize the HER performance. Polyoxometalates (POMs) with structural diversity and adjustable element compositions represent a promising precursor for rational design and preparation of HER electrocatalysts. Herein, a series of transition metal-doped MoS₂ materials with different surface engineered structures (Fe, Cr, V doping and S vacancies) (M-MoS₂/CC, M = Fe, Cr and V) were fabricated by a simple hydrothermal-vulcanization strategy using Keplerate polyoxomolybdate nanoball ({Mo₇₂Fe₃₀}, {Mo₇₂Cr₃₀}, {Mo₇₂V₃₀}, {Mo₁₃₂}) as precursors. The enlarged interlayer spacing as well as the integration of homogeneous transition metal doping and abundant sulfur vacancies endows prepared M-MoS₂/CC with superior HER electrocatalytic performance and excellent long-term working stability in both acidic and alkaline media. The optimized Fe-MoS₂/CC afford current densities of 10 and 50 mA/cm² at overpotentials of 188/272 mV and 194/394 mV in 0.5 mol/L H₂SO₄ and 1.0 mol/L KOH aqueous solution, respectively, outperforming most of reported typical transition metal sulfide-based catalysts. This work represents an important breakthrough for POMs-mediated highly efficient transition metal sulfide-based HER electrocatalysts with wide range pH activity and may provide new options for the rational design of promising HER electrocatalysts and beyond.
- Polyoxometalate,
- Electrocatalytic,
- Hydrogen evolution reaction,
- Doping,
- MoS₂
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