Citation: Binyang Qin, Mengqi Wang, Shimei Wu, Yining Li, Chilin Liu, Yufei Zhang, Haosen Fan. Carbon dots confined nanosheets assembled NiCo₂S₄@CDs cross-stacked architecture for enhanced sodium ion storage[J]. Chinese Chemical Letters, ;2024, 35(7): 108921. doi: 10.1016/j.cclet.2023.108921 shu

Carbon dots confined nanosheets assembled NiCo₂S₄@CDs cross-stacked architecture for enhanced sodium ion storage

School of Chemistry and Chemical Engineering, Guangzhou University, Guangzhou 510006, China

yfzhang@gdut.edu.cn

hsfan@gzhu.edu.cn

Received Date: 9 June 2023
Revised Date: 31 July 2023
Accepted Date: 9 August 2023
Available Online: 13 August 2023

Figures(4)

Na⁺ batteries (SIBs) have been emerging as the most promising candidate for the next generation of secondary batteries. However, the development of high-performance and cost-effective anode materials is urgently needed for the large-scale applications of SIBs. In this study, carbon dots confined bimetallic sulfide (NiCo₂S₄) architecture (NiCo₂S₄@CDs) was proposed and synthesized from assembling nanosheets into cross-stacked superstructure and the subsequent confinement of carbon dots. This novel decussated structure assembly from nanosheets is greatly beneficial to the structure stability of electrode material during the successive charge/discharge processes. Besides, the CDs based carbon conductive network can enhance the electrical conductivity for facilitating the easy transport of electron/Na⁺. Benefitting from these advantages, NiCo₂S₄@CDs exhibits high-rate performance and an ultralong cycling life in SIBs. Specifically, the specific capacity of NiCo₂S₄@CDs can reach the discharge specific capacity as high as 568.9 mAh/g at 0.5 A/g, which can also maintain 302.7 mAh/g after 750 cycles at 5.0 A/g. Additionally, ex-situ characterization techniques such as ex-situ XRD and ex-situ XPS were employed to further explore the sodium storage mechanism of the NiCo₂S₄@CDs anode.
- Carbon dots,
- Sodium ion batteries,
- NiCo₂S₄@CDs,
- Cross-stacked architecture,
- Ex-situ XRD and XPS
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沈阳化工大学材料科学与工程学院沈阳 110142

Carbon dots confined nanosheets assembled NiCo2S4@CDs cross-stacked architecture for enhanced sodium ion storage

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通讯作者: 陈斌, bchen63@163.com

Carbon dots confined nanosheets assembled NiCo₂S₄@CDs cross-stacked architecture for enhanced sodium ion storage