Citation: Guorong Li, Yijing Wu, Chao Zhong, Yixin Yang, Zian Lin. Predesigned covalent organic framework with sulfur coordination: Anchoring Au nanoparticles for sensitive colorimetric detection of Hg(Ⅱ)[J]. Chinese Chemical Letters, ;2024, 35(5): 108904. doi: 10.1016/j.cclet.2023.108904 shu

Predesigned covalent organic framework with sulfur coordination: Anchoring Au nanoparticles for sensitive colorimetric detection of Hg(Ⅱ)

Ministry of Education Key Laboratory of Analytical Science for Food Safety and Biology, Fujian Provincial Key Laboratory of Analysis and Detection Technology for Food Safety, College of Chemistry, Fuzhou University, Fuzhou 350108, China

zianlin@fzu.edu.cn

Received Date: 21 December 2022
Revised Date: 31 July 2023
Accepted Date: 6 August 2023
Available Online: 8 August 2023

Figures(5)

Targeted construction of new covalent organic frameworks (COFs) with specific purposes and rationalities to build colorimetric assay platform for environmental pollutant monitoring have attracted increasing interest. However, it is still challenging due to lack of available coordination sites inside COFs pores and only a slight bonding ability for anchoring metal. In this work, a two-dimensional (2D) COFs (termed as Tz-COF) with high crystallinity, excellent chemical stability, and abundant sulfur coordination in its skeletons was synthesized and used for the confined growth of Au NPs. It was found that the Au NPs showed significant dispersibility for the support of Tz-COF. The proposed Tz-COF@Au NPs possessed outstanding Hg²⁺-activated peroxidase-like activity benefited from physicochemical properties of gold amalgam and synergistic effect between COFs and Au NPs to oxidize chromogenic substrate. Based on highly efficient activity and distinctive color evolution, the strategy for detecting Hg²⁺ was developed and successfully applied to determine the content of Hg²⁺ in real environmental samples. This work manifests that a potential strategy to establish a colorimetric assay platform for environmental pollutant monitoring based on the targeted manufacturing of novel COFs with specific functions.
- Covalent organic frameworks,
- Thiazole,
- Sulfur coordination,
- Au nanoparticles,
- Hg²⁺-activated peroxidase-like activity
1. [1]
  C. Chen, D. Zhao, Y. Jiang, et al., Anal. Chem. 91 (2019) 15017–15024. doi: 10.1021/acs.analchem.9b03629
2. [2]
  Y. Huang, M. Zhao, S. Han, et al., Adv. Mater. 29 (2017) 1700102. doi: 10.1002/adma.201700102
3. [3]
  R. Xu, Z. Wang, S. Liu, H. Li, Chin. Chem. Lett. 33 (2022) 4683–4686. doi: 10.1016/j.cclet.2021.12.062
4. [4]
  X.K. Wan, H.B. Wu, B.Y. Guan, D. Luan, X.W.D. Lou, Adv. Mater. 32 (2020) 1901349. doi: 10.1002/adma.201901349
5. [5]
  L. Shang, T. Bian, B. Zhang, et al., Angew. Chem. Int. Ed. 53 (2014) 250–254. doi: 10.1002/anie.201306863
6. [6]
  W. Yuan, B. Zhu, K. Fang, et al., Science 371 (2021) 517–521. doi: 10.1126/science.abe3558
7. [7]
  L. Duan, C.T. Hung, J. Wang, et al., Angew. Chem. Int. Ed. 61 (2022) e202211307. doi: 10.1002/anie.202211307
8. [8]
  F. Jin, E. Lin, T. Wang, et al., Chemistry 8 (2022) 3064–3080. doi: 10.1016/j.chempr.2022.07.016
9. [9]
  Z. Li, Z. Zhang, R. Nie, et al., Adv. Funct. Mater. 32 (2022) 2112553. doi: 10.1002/adfm.202112553
10. [10]
  L. Chen, M. Huang, B. Chen, et al., Chin. Chem. Lett. 33 (2022) 2867–2882. doi: 10.1016/j.cclet.2021.10.060
11. [11]
  Q. Guan, L.L. Zhou, Y.B. Dong, Chem. Soc. Rev. 51 (2022) 6307–6416. doi: 10.1039/D1CS00983D
12. [12]
  Y. Zhang, G. Li, Y. Hu, Chin. Chem. Lett. 32 (2021) 2529–2533. doi: 10.1016/j.cclet.2021.01.031
13. [13]
  H.C. Ma, J.L. Kan, G.J. Chen, C.X. Chen, Y.B. Dong, Chem. Mater. 29 (2017) 6518–6524. doi: 10.1021/acs.chemmater.7b02131
14. [14]
  Y. Deng, Z. Zhang, P. Du, et al., Angew. Chem. Int. Ed. 59 (2020) 6082–6089. doi: 10.1002/anie.201916154
15. [15]
  M. Yu, Y. Chen, M. Gao, et al., Small 19 (2022) 2206407.
16. [16]
  Y. Tian, Q. Lu, X. Guo, et al., Nanoscale 12 (2020) 7776–7781. doi: 10.1039/C9NR08220D
17. [17]
  R. Tao, X. Shen, Y. Hu, et al., Small 16 (2020) 1906005. doi: 10.1002/smll.201906005
18. [18]
  L. Niu, X. Zhao, Z. Tang, et al., Sci. Total Environ. 835 (2022) 155423. doi: 10.1016/j.scitotenv.2022.155423
19. [19]
  X. Shi, Y. Yao, Y. Xu, et al., ACS Appl. Mater. Interfaces 9 (2017) 7481–7488. doi: 10.1021/acsami.6b16267
20. [20]
  W. Ma, G. Li, C. Zhong, et al., Chem. Commun. 57 (2021) 7362–7365. doi: 10.1039/D1CC02646A
21. [21]
  K. Wang, Z. Jia, Y. Bai, et al., J. Am. Chem. Soc. 142 (2020) 11131–11138. doi: 10.1021/jacs.0c03418
22. [22]
  A.C. Jakowetz, T.F. Hinrichsen, L. Ascherl, et al., J. Am. Chem. Soc. 141 (2019) 11565–11571. doi: 10.1021/jacs.9b03956
23. [23]
  Y. Xie, Y. Chen, X. Sun, Y. Wang, Y. Wang, Chin. Chem. Lett. 32 (2021) 2061–2065. doi: 10.1016/j.cclet.2020.10.001
24. [24]
  S.B. Ren, X.L. Chen, P.X. Li, et al., J. Power Sources 461 (2020) 228145. doi: 10.1016/j.jpowsour.2020.228145
25. [25]
  J. Dong, X. Li, S.B. Peh, et al., Chem. Mater. 31 (2018) 146–160.
26. [26]
  N. Liu, L. Shi, X. Han, et al., Chin. Chem. Lett. 31 (2020) 386–390. doi: 10.1016/j.cclet.2019.06.050
27. [27]
  Z. Zhang, C. Kang, S.B. Peh, et al., J. Am. Chem. Soc. 144 (2022) 14992–14996. doi: 10.1021/jacs.2c05309
28. [28]
  F. Haase, E. Troschke, G. Savasci, et al., Nat. Commun. 9 (2018) 2600. doi: 10.1038/s41467-018-04979-y
29. [29]
  Q. Peng, Z.Y. Wang, B.S. Sa, B. Wu, Z.M. Sun, ACS Appl. Mater. Interfaces 8 (2016) 13449–13457. doi: 10.1021/acsami.6b03368
30. [30]
  W.R. Cui, C.R. Zhang, W. Jiang, et al., ACS Sustain. Chem. Eng. 7 (2019) 9408–9415. doi: 10.1021/acssuschemeng.9b00613
31. [31]
  L. Tan, Y. Zhang, H. Qiang, et al., Sens. Actuat. B: Chem. 229 (2016) 686–691. doi: 10.1016/j.snb.2016.02.037
32. [32]
  L. Chen, J. Li, L. Chen, ACS Appl. Mater. Interfaces 6 (2014) 15897–15904. doi: 10.1021/am503531c
33. [33]
  J. Xu, F. Sun, Q. Li, et al., Small 18 (2022) 2200525. doi: 10.1002/smll.202200525
34. [34]
  L. Wang, F. Gao, A. Wang, et al., Adv. Mater. 32 (2020) 2005423. doi: 10.1002/adma.202005423
35. [35]
  Y. Guo, Y. Tao, X. Ma, et al., Chem. Eng. J. 350 (2018) 120–130. doi: 10.1016/j.cej.2018.05.135
36. [36]
  S. Zhang, D. Zhang, X. Zhang, et al., Anal. Chem. 89 (2017) 3538–3544. doi: 10.1021/acs.analchem.6b04805
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