Citation: Qian Wang, Ting Gao, Xiwen Lu, Hangchao Wang, Minggui Xu, Longtao Ren, Zheng Chang, Wen Liu. Nanophase separated, grafted alternate copolymer styrene-maleic anhydride as an efficient room temperature solid state lithium ion conductor[J]. Chinese Chemical Letters, ;2024, 35(7): 108887. doi: 10.1016/j.cclet.2023.108887 shu

Nanophase separated, grafted alternate copolymer styrene-maleic anhydride as an efficient room temperature solid state lithium ion conductor

Qian Wang ^{a, 1} ,
Ting Gao ^{b, 1} ,
Xiwen Lu ^b ,
Hangchao Wang ^b ,
Minggui Xu ^b ,
Longtao Ren ^{b, *,} ,
Zheng Chang ^{b, *,} ,
Wen Liu ^{b, *,}

a.
Institute of Science and Technology, China Three Gorges Corporation, Beijing 100038, China
b.
State Key Laboratory of Chemical Resource Engineering, Beijing Advanced Innovation Center for Soft Matter Science and Engineering, College of Chemistry, Beijing University of Chemical Technology, Beijing 100029, China

longtao.ren@buct.edu.cn

changzheng@buct.edu.cn

wenliu@mail.buct.edu.cn

Received Date: 26 May 2023
Revised Date: 3 July 2023
Accepted Date: 2 August 2023
Available Online: 6 August 2023

Figures(4)

All solid-state lithium metal batteries (ASSLMBs) based on polymer solid electrolyte and lithium metal anode have attracted much attention due to their high energy density and intrinsic safety. However, the low ionic conductivity at room temperature and poor mechanical properties of the solid polymer electrolyte result in increased polarization and poor cycling stability of the Li metal batteries. In order to improve the ionic conductivity at room temperature while maintaining mechanical strength, we combine the conductivity of short chain polyethylene oxide (PEO) and strength of styrene-maleic anhydride copolymer (SMA) to obtain a grafted block copolymer with nanophase separation structure, which has room temperature ionic conductivity up to 1.14 × 10⁻⁴ S/cm and tensile strength up to 1.4 MPa. Li||Li symmetric cell can work stably for more than 1500 h under the condition of 0.1 mA/cm². Li||LiFePO₄ full cells can deliver a high capacity of 151.4 mAh/g at 25 ℃ and 0.2 C/0.2 C charge/discharge conditions, showing 85.6% capacity retention after 400 cycles. Importantly, the all solid state Li||LiFePO₄ pouch cell shows excellent safety performance under different abuse conditions. These results demonstrate that the nanophase separated, grafted alternate copolymer electrolyte has huge potential for application in Li metal batteries.
- Solid polymer electrolyte,
- All solid-state battery,
- Li metal battery,
- Copolymers,
- Nanophase separation
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