Citation: Shuangliang Xie, Yuyue Chen, Qing He, Liang Chen, Jikun Yang, Shiqing Deng, Yimei Zhu, He Qi. Relaxor antiferroelectric-relaxor ferroelectric crossover in NaNbO₃-based lead-free ceramics for high-efficiency large-capacitive energy storage[J]. Chinese Chemical Letters, ;2024, 35(7): 108871. doi: 10.1016/j.cclet.2023.108871 shu

Relaxor antiferroelectric-relaxor ferroelectric crossover in NaNbO₃-based lead-free ceramics for high-efficiency large-capacitive energy storage

Shuangliang Xie ^{a, 1} ,
Yuyue Chen ^{b, 1} ,
Qing He ^{b, 1} ,
Liang Chen ^b ,
Jikun Yang ^c ,
Shiqing Deng ^{b, d, *,} ,
Yimei Zhu ^{d, *,} ,
He Qi ^{b, *,}

a.
School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China
b.
Beijing Advanced Innovation Center for Materials Genome Engineering, Department of Physical Chemistry, University of Science and Technology Beijing, Beijing 100083, China
c.
School of Mathematics and Physics, University of Science and Technology Beijing, Beijing 100083, China
d.
Department of Condensed Matter Physics and Materials Science, Brookhaven National Laboratory, Upton, New York 11973, United States

sqdeng@ustb.edu.cn

zhu@bnl.gov

qiheustb@ustb.edu.cn

Received Date: 29 June 2023
Revised Date: 11 July 2023
Accepted Date: 30 July 2023
Available Online: 1 August 2023

Figures(4)

Relaxor ferroic dielectrics have garnered increasing attention in the past decade as promising materials for energy storage. Among them, relaxor antiferroelectrics (AFEs) and relaxor ferroelectrics (FEs) have shown great promise in term of high energy storage density and efficiency, respectively. In this study, a unique phase transition from relaxor AFE to relaxor FE was achieved for the first time by introducing strong-ferroelectricity BaTiO₃ into NaNbO₃-BiFeO₃ system, leading to an evolution from AFE R hierarchical nanodomains to FE polar nanoregions. A novel medium state, consisting of relaxor AFE and relaxor FE, was identified in the crossover of 0.88NaNbO₃–0.07BiFeO₃–0.05BaTiO₃ ceramic, exhibiting a distinctive core-shell grain structure due to the composition segregation. By harnessing the advantages of high energy storage density from relaxor AFE and large efficiency from relaxor FE, the ceramic showcased excellent overall energy storage properties. It achieved a substantial recoverable energy storage density W_rec ~ 13.1 J/cm³ and an ultrahigh efficiency η ~ 88.9%. These remarkable values shattered the trade-off relationship typically observed in most dielectric capacitors between W_rec and η. The findings of this study provide valuable insights for the design of ceramic capacitors with enhanced performance, specifically targeting the development of next generation pulse power devices.
- Relaxor ferroelectric,
- Antiferroelectric,
- Core-shell,
- Energy storage,
- High efficiency
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Relaxor antiferroelectric-relaxor ferroelectric crossover in NaNbO3-based lead-free ceramics for high-efficiency large-capacitive energy storage

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通讯作者: 陈斌, bchen63@163.com

Relaxor antiferroelectric-relaxor ferroelectric crossover in NaNbO₃-based lead-free ceramics for high-efficiency large-capacitive energy storage