Citation: Shanmei Zhu, Penghui Hu, Mengying Guo, Linlin Zhao, Linlin Yang, Wei-Jin Gu, Wei Han. Eco-friendly iron-catalyzed oxidation of unstrained tertiary aromatic alcohols to ketones[J]. Chinese Chemical Letters, ;2024, 35(1): 108835. doi: 10.1016/j.cclet.2023.108835 shu

Eco-friendly iron-catalyzed oxidation of unstrained tertiary aromatic alcohols to ketones

Jiangsu Collaborative Innovation Center of Biomedical Functional Materials, Jiangsu Key Laboratory of Biofunctional Materials, Key Laboratory of Applied Photochemistry, School of Chemistry and Materials Science, Nanjing Normal University, Nanjing 210023, China

whhanwei@outlook.com

Received Date: 7 May 2023
Revised Date: 30 June 2023
Accepted Date: 23 July 2023
Available Online: 29 July 2023

Figures(6)

A general, facile and eco-friendly iron catalysis enables oxidation of unstrained tertiary aromatic alcohols to ketones through C−C bond cleavage even with H₂O₂ as the oxidant. Notably, this transformation can tolerate oxidation-labile functional groups. The robustness of this method is further demonstrated on the late-stage oxidation of complex bioactive molecules.
- Iron catalysis,
- C−C bond cleavage,
- Oxidation,
- H₂O₂,
- Late-stage functionalization
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