Citation: Mei Li, Yanyan Zhou, Jingya Li, Wenru Huang, Zhiwei Yao, Yuying Li, Ting Gao, Pengfei Yan, Hongfeng Li. Circularly polarized luminescence switch based on a photochromic europium(III) helicate derived coordination polymer[J]. Chinese Chemical Letters, ;2024, 35(2): 108831. doi: 10.1016/j.cclet.2023.108831 shu

Circularly polarized luminescence switch based on a photochromic europium(III) helicate derived coordination polymer

Mei Li ^a ,
Yanyan Zhou ^a ,
Jingya Li ^b ,
Wenru Huang ^a ,
Zhiwei Yao ^a ,
Yuying Li ^a ,
Ting Gao ^a ,
Pengfei Yan ^{a, *,} ,
Hongfeng Li ^{a, *,}

a.
Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, China
b.
State Key Laboratory of Baiyunobo Rare Earth Resource Researches and Comprehensive Utilization Institution, Baotou 014030, China

Yanpf@vip.sina.com

lihongfeng@hlju.edu.cn

Received Date: 29 May 2023
Revised Date: 17 July 2023
Accepted Date: 23 July 2023
Available Online: 26 July 2023

Figures(6)

Chiroptical switches based on circularly polarized luminescence (CPL) have shown the promising applications in advanced information technologies. Herein, a pair of lanthanide coordination polymer enantiomers [Eu₂(L^R)₃(BTFPO)₂]_n and [Eu₂(L^S)₃(BTFPO)₂]_n with light-regulated CPL property are designed, which are assembled by a chiral binuclear triple-stranded Eu³⁺ helicates [Eu₂(L^R/S)₃] coordinated with two photochromic triphenylphosphine oxides (BTFPO). Upon the alternative UV and 526 nm light irradiation, the complexes show the reversible photochromism, PL and CPL responses. Notably, the luminescence dissymmetry factor, g_lum of ⁵D₀→⁷F₁ (591 nm) transition shows an obvious increase from 0.19 to 0.29 before and after 275 nm light irradiation. Additionally, the emission from Eu³⁺ center is not completely quenched in closed-ring state due to the low photocyclization (Ф_o-c) quantum yield of the polymer. The partial maintenance of emissive intensity is of essential importance for the monitor of CPL signal. More importantly, the CPL photo-switching property of the complexes in solid hybrid film is maintained, and still displays the enhanced CPL emission in photostationary state. Further, the potential applications of the doping film in logic gate and anti-counterfeiting were investigated.
- Chiroptical switches,
- Coordination polymer,
- CPL,
- Anti-counterfeiting,
- Logic gate
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