Citation: Hongying Hou, Jinxu Qiu, Bao Li, Liang Wang, Zhuangzhuang Zhang, Mengmin Jia, Xiaobing Lai, Mingming Han, Pengyao Yan, Dai-Huo Liu, Dongmei Dai, Bao Wang. Trace doping realizing superior electrochemical performance in P2-type Na_0.50Li_0.08Mn_0.60Co_0.16Ni_0.16O₂ cathode for sodium-ion batteries[J]. Chinese Chemical Letters, ;2023, 34(12): 108810. doi: 10.1016/j.cclet.2023.108810 shu

Trace doping realizing superior electrochemical performance in P2-type Na_0.50Li_0.08Mn_0.60Co_0.16Ni_0.16O₂ cathode for sodium-ion batteries

Hongying Hou ^{a, 1} ,
Jinxu Qiu ^{a, b, 1} ,
Bao Li ^b ,
Liang Wang ^b ,
Zhuangzhuang Zhang ^b ,
Mengmin Jia ^b ,
Xiaobing Lai ^b ,
Mingming Han ^b ,
Pengyao Yan ^b ,
Dai-Huo Liu ^{b, *,} ,
Dongmei Dai ^{b, *,} ,
Bao Wang ^{c, *,}

a.
Faculty of Material Science and Engineering, Kunming University of Science and Technology, Kunming 650093 China
b.
Collaborative Innovation Center of Henan Province for Green Manufacturing of Fine Chemicals, Key Laboratory of Green Chemical Media and Reactions, Ministry of Education, School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang 453007, China
c.
State Key Laboratory of Biochemical Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China

liudaihuo@htu.edu.cn

daidongmei@htu.edu.cn

baowang@ipe.ac.cn

Received Date: 29 April 2023
Revised Date: 1 June 2023
Accepted Date: 12 July 2023
Available Online: 14 July 2023

Figures(4)

P2-type layered oxides are receiving significant interest due to their superior structure and intrinsic performances. There are strenuous attempts to balance the structure stability, phase transition as well as desirable electrochemical performances by inducing anion/cation ions, changing morphology, adjusting valence, etc. In this work, several same-period elements of Sc, Ti, V, Cr, Fe, Cu and Zn are doped into Na_0.50Li_0.08Mn_0.60Co_0.16Ni_0.16O₂ cathodes, which are manipulated by ions radii and valence state, further studied by operando X-ray powder diffraction patterns (XRD). As a result, the Cu²⁺ doped cathode performed higher rate capacities (as high as 86 mAh/g even at 10 C) and more stable structures (capacity retention of ~89.4% for 100 cycles), which owing to the synergistic effect among the tightened TMO₂ layer, enlarged d-spacing, reduce OO electrostatic repulsion, ameliorate lattice distortion as well as mitigate ordering of Na⁺/vacancy.
- P2-type layered oxide,
- Same-period elements doping,
- Rietveld refinement,
- Operando XRD,
- Sodium-ion battery
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沈阳化工大学材料科学与工程学院沈阳 110142

Trace doping realizing superior electrochemical performance in P2-type Na0.50Li0.08Mn0.60Co0.16Ni0.16O2 cathode for sodium-ion batteries

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通讯作者: 陈斌, bchen63@163.com

Trace doping realizing superior electrochemical performance in P2-type Na_0.50Li_0.08Mn_0.60Co_0.16Ni_0.16O₂ cathode for sodium-ion batteries