Citation: Keke Han, Wenjun Rao, Xiuli You, Haina Zhang, Xing Ye, Zhenhong Wei, Hu Cai. Two new high-temperature molecular ferroelectrics [1,5-3.2.2-Hdabcni]X (X = ClO₄⁻, ReO₄⁻)[J]. Chinese Chemical Letters, ;2024, 35(6): 108809. doi: 10.1016/j.cclet.2023.108809 shu

Two new high-temperature molecular ferroelectrics [1,5-3.2.2-Hdabcni]X (X = ClO₄⁻, ReO₄⁻)

Keke Han ^a ,
Wenjun Rao ^a ,
Xiuli You ^b ,
Haina Zhang ^a ,
Xing Ye ^a ,
Zhenhong Wei ^{a, *,} ,
Hu Cai ^{a, *,}

a.
School of Chemistry and Chemical Engineering, Nanchang University, Nanchang 330031, China
b.
Jiangxi Key laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University, Nanchang 330013, China

weizh@ncu.edu.cn

caihu@ncu.edu.cn

Received Date: 20 April 2023
Revised Date: 13 June 2023
Accepted Date: 12 July 2023
Available Online: 14 July 2023

Figures(6)

Molecular ferroelectrics have attracted much attention because of their excellent piezoelectricity, mechanical workability, and second harmonic effect. Here, we successfully prepared two molecular ferroelectrics 1,5–3.2.2-HdabcniX (X = ClO₄⁻, 1; ReO₄⁻, 2) by reactions of a quasi-spherical amine 1,5-diazabicycle[3.2.2]nonane (1.5–3.2.2-dabcn) with HX aqueous solution. Compounds 1 and 2 undergo high-temperature phase transitions at 381 K (1) and 396 K (2). Before and after the phase transition, they crystallize in the polar point group mm2, and the centrosymmetric point groups mmm and 4/mmm, respectively. According to Aizu rules, these two compounds experience mmmFmm2 and 4/mmmFmm2 type ferroelectric phase transitions, respectively. The ferroelectricity of both compounds is well expressed in their polycrystalline film at room temperature with low coercive voltages of 13 V for 1 and 25 V for 2. Using piezoelectric force microscopy (PFM), the 180° anti-parallel ferroelectric domains and the reversible polarization switching can be clearly observed in 1 and 2. This high-temperature molecular ferroelectric material has great application potential in flexible materials, biomechanics, intelligent wearables and other fields.
- Ferroelectric domains,
- Quasi-spherical amine,
- Phase transition,
- Polarization
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沈阳化工大学材料科学与工程学院沈阳 110142

Two new high-temperature molecular ferroelectrics [1,5-3.2.2-Hdabcni]X (X = ClO4−, ReO4−)

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通讯作者: 陈斌, bchen63@163.com

Two new high-temperature molecular ferroelectrics [1,5-3.2.2-Hdabcni]X (X = ClO₄⁻, ReO₄⁻)