Citation: Ang Li, Yanhong Wang, Haotian Tian, Alimujiang Yalikun, Yves Journaux, Min Luo, Hongcheng Lu. Multifunctional properties of a polar spin chain compound [N(C₃H₇)₄][Cu(C₈H₄NO₄)]·H₂O exhibiting both one-dimensional magnetism and nonlinear optical activity[J]. Chinese Chemical Letters, ;2024, 35(2): 108780. doi: 10.1016/j.cclet.2023.108780 shu

Multifunctional properties of a polar spin chain compound [N(C₃H₇)₄][Cu(C₈H₄NO₄)]·H₂O exhibiting both one-dimensional magnetism and nonlinear optical activity

a.
Key Laboratory of Material Chemistry for Energy Conversion and Storage, School of Chemistry and Chemical Engineering, Hubei Key Laboratory of Bioinorganic Chemistry & Materia Medica, Huazhong University of Science and Technology, Wuhan 430074, China
b.
Key Laboratory of optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 35002, China
c.
Institut Parisien de Chimie Moléculaire, IPCM, Sorbonne Université, CNRS, Paris F-75252, France

hcl@hust.edu.cn

Received Date: 22 May 2023
Revised Date: 15 June 2023
Accepted Date: 5 July 2023
Available Online: 6 July 2023

Figures(4)

Functional materials with multiple properties are urgent to be explored to reach high requirements for applications nowadays. In this work, a new multifunctional one-dimensional (1D) chain compound [N(C₃H₇)₄][Cu(ohpma)]·H₂O 1 (ohpma = deprotonated N-(2-hydoxyphenyl)oxamic acid) exhibiting both 1D antiferromagnetic and nonlinear optical properties, which are both originated from the same polar [Cu(C₈H₄NO₄)] magnetic units, has been successfully synthesized by evaporation at room temperature. Bis-polydentate nature of the (ohpma)³⁻ ligand with constrained tridentate and bidentate coordination sites conducts Cu²⁺ ions coordinating in different geometries and forms 1D chains along the c axis, which are further separated by the [N(C₃H₇)₄]⁺ cations. And the 1D magnetic chains further exhibit noncentrosymmetric polar arrangement. Nonlinear optical study shows polar compound 1 exhibits a discernible second-harmonic generation (SHG) efficiency and the calculation of the partial density of states indicates that the SHG efficiency of 1 is mainly originated from the polar [Cu(C₈H₄NO₄)] magnetic units. Moreover, magnetic susceptibility shows a broad maximum around 70 K with strong intrachain interaction of J/k_B = −113.0 K but no long-range order is observed down to 2 K, suggesting that 1 shows a good 1D magnetism. Both good 1D magnetism and SHG activity suggest that 1 could be as a potential multifunctional material, particularly.
- Multifunctional properties,
- Magnetic property,
- Nonlinear optical property,
- Evaporation,
- One-dimensional chain
1. [1]
  Y.B. Kudasov, R.V. Kozabaranov, Phys. Lett. A 382 (2018) 1120–1123. doi: 10.1016/j.physleta.2018.02.031
2. [2]
  P.H.Y. Li, R.F. Bishop, C.E. Campbell, Phys. Rev. B 88 (2013) 144423. doi: 10.1103/PhysRevB.88.144423
3. [3]
  L. Wang, K.S. Kim, Phys. Rev. B 99 (2019) 134441. doi: 10.1103/PhysRevB.99.134441
4. [4]
  Z. Wang, L. Hu, L. Lin, et al., Sci. Rep. UK 11 (2021) 14442. doi: 10.1038/s41598-021-93930-1
5. [5]
  H. Lu, T. Yamamoto, W. Yoshimune, et al., J. Am. Chem. Soc. 137 (2015) 9804–9807. doi: 10.1021/jacs.5b06120
6. [6]
  N. Li, Q. Lin, Y. Han, et al., Chin. Chem. Lett. 32 (2021) 3803–3806. doi: 10.1016/j.cclet.2021.04.042
7. [7]
  F. Ding, K.J. Griffith, C. Zhang, et al., J. Solid State Chem. 314 (2022) 123360. doi: 10.1016/j.jssc.2022.123360
8. [8]
  X. Li, J. Yang, Nat. Sci. Rev. 3 (2016) 365–381. doi: 10.1093/nsr/nww026
9. [9]
  R. Gautier, K. Oka, T. Kihara, et al., J. Am. Chem. Soc. 135 (2013) 19268–19274. doi: 10.1021/ja409831h
10. [10]
  Y. Wang, H. Liu, P. Fu, et al., Sci. China Mater. 62 (2019) 1815–1820. doi: 10.1007/s40843-019-1198-3
11. [11]
  Y. Deng, L. Huang, X. Dong, et al., Angew. Chem. Int. Ed. 59 (2020) 21151–21156. doi: 10.1002/anie.202009441
12. [12]
  G. Zou, K.M. Ok, Chem. Sci. 11 (2020) 5404–5409. doi: 10.1039/D0SC01936D
13. [13]
  E. Bainglass, M.N. Huda, J. Electrochem. Soc. 166 (2019) H3195. doi: 10.1149/2.0281905jes
14. [14]
  Z. Li, G. Zhu, Y. Li, et al., J. Am. Ceram. Soc. 104 (2021) 2655–2668. doi: 10.1111/jace.17620
15. [15]
  Q. Zhang, J. Hu, Q. Li, et al., Chin. Chem. Lett. 33 (2022) 1417–1421. doi: 10.1016/j.cclet.2021.08.029
16. [16]
  Y. Zhou, Y. Li, Q. Ding, et al., Chin. Chem. Lett. 32 (2021) 263–265. doi: 10.1016/j.cclet.2020.11.014
17. [17]
  Y.C. Yang, X. Liu, J. Lu, et al., Angew. Chem. Int. Ed. 60 (2021) 21216–21220. doi: 10.1002/anie.202107780
18. [18]
  E. Mitoudi-Vagourdi, J. Rienmüller, P. Lemmens, et al., ACS Omega 4 (2019) 15168–15174. doi: 10.1021/acsomega.9b02064
19. [19]
  X. Xu, C.L. Hu, B.P. Yang, et al., CrystEngComm 15 (2013) 7776–7782. doi: 10.1039/c3ce41185k
20. [20]
  R. Baies, V. Pralong, V. Caignaert, et al., Mater. Res. Bull. 41 (2006) 1170–1177. doi: 10.1016/j.materresbull.2005.11.004
21. [21]
  L.C. Liu, W.J. Ren, Y.X. Huang, et al., J. Solid State Chem. 254 (2017) 160–165. doi: 10.1016/j.jssc.2017.07.011
22. [22]
  R. Zhong, S. Guo, R.J. Cava, Phys. Rev. Mater. 4 (2020) 084406. doi: 10.1103/PhysRevMaterials.4.084406
23. [23]
  L.M. Volkova, D.V. Marinin, J. Phys. : Condens. Matter 30 (2018) 425801. doi: 10.1088/1361-648X/aade0b
24. [24]
  H. Jo, S. Lee, K.Y. Choi, et al., Inorg. Chem. 57 (2018) 3465–3473. doi: 10.1021/acs.inorgchem.8b00305
25. [25]
  S. Guo, T. Kong, F.A. Cevallos, et al., J. Magn. Magn. Mater. 472 (2019) 104–110. doi: 10.1016/j.jmmm.2018.10.037
26. [26]
  Q. Huang, L. Liu, X. Wang, et al., Inorg. Chem. 55 (2016) 12496–12499. doi: 10.1021/acs.inorgchem.6b02044
27. [27]
  X. Chen, B. Zhang, F. Zhang, et al., J. Am. Chem. Soc. 140 (2018) 16311–16319. doi: 10.1021/jacs.8b10009
28. [28]
  M. Luo, C. Lin, D. Lin, et al., Angew. Chem. Int. Ed. 59 (2020) 15978–15981. doi: 10.1002/anie.202006671
29. [29]
  M.D. Donakowski, R. Gautier, J. Yeon, et al., J. Am. Chem. Soc. 134 (2012) 7679–7689. doi: 10.1021/ja210984k
30. [30]
  D. Oka, Y. Hirose, H. Kamisaka, et al., Sci. Rep. UK 4 (2014) 4987. doi: 10.1038/srep04987
31. [31]
  H. Kageyama, K. Hayashi, K. Maeda, et al., Nat. Commun. 9 (2018) 772. doi: 10.1038/s41467-018-02838-4
32. [32]
  C. Tassel, Y. Kuno, Y. Goto, et al., Angew. Chem. Int. Ed. 54 (2015) 516–521. doi: 10.1002/anie.201408483
33. [33]
  Y. Goto, C. Tassel, Y. Noda, et al., Inorg. Chem. 56 (2017) 4840–4845. doi: 10.1021/acs.inorgchem.6b02834
34. [34]
  H.J. Wu, L.D. Zhao, F.S. Zheng, et al., Nat. Commun. 5 (2014) 4515. doi: 10.1038/ncomms5515
35. [35]
  D. Hirai, T. Yajima, D. Nishio-Hamane, et al., J. Am. Chem. Soc. 139 (2017) 10784–10789. doi: 10.1021/jacs.7b05128
36. [36]
  S. Wu, S. Bala, Z. Ruan, et al., Chin. Chem. Lett. 33 (2022) 1381–1384. doi: 10.1016/j.cclet.2021.08.012
37. [37]
  Y. She, Y. Wang, S. Li, et al., Nano Res. 16 (2023) 3552–3557. doi: 10.1007/s12274-022-5206-5
38. [38]
  L.N. Ma, X.Y. Li, W.J. Shi, et al., ChemPlusChem 84 (2019) 62–68. doi: 10.1002/cplu.201800470
39. [39]
  T. Grancha, J. Ferrando-Soria, M. Castellano, et al., Chem. Commun. 50 (2014) 7569–7585. doi: 10.1039/C4CC01734J
40. [40]
  Y. Journaux, J. Ferrando-Soria, E. Pardo, et al., Eur. J. Inorg. Chem. 2018 (2018) 228–247. doi: 10.1002/ejic.201701491
41. [41]
  A. Li, Y. Li, L.M. Chamoreau, et al., Eur. J. Inorg. Chem. 2020 (2020) 3311–3319. doi: 10.1002/ejic.202000490
42. [42]
  A. Li, L.M. Chamoreau, B. Baptiste, et al., Dalton Trans. 50 (2021) 681–688. doi: 10.1039/D0DT03269G
43. [43]
  S.J. Liu, C. Cao, F. Yang, et al., Cryst. Growth Des. 16 (2016) 6776–6780. doi: 10.1021/acs.cgd.6b00776
44. [44]
  M. Castellano, W.P. Barros, A. Acosta, et al., Chem. Eur. J. 20 (2014) 13965–13975. doi: 10.1002/chem.201403987
45. [45]
  T.T. da Cunha, C.O.C. da Silveira, V.M.M. Barbosa, et al., CrystEngComm 23 (2021) 1885–1897. doi: 10.1039/D0CE01742F
46. [46]
  E. Pardo, R. Ruiz-García, F. Lloret, et al., Chem. Eur. J. 13 (2007) 2054–2066. doi: 10.1002/chem.200600992
47. [47]
  N.G. Connelly, D. Ture, R.M. Hartshorn, et al., Nomenclature of Inorganic Chemistry: IUPAC Recommendations 2005, The Royal Society of Chemistry, Cambridge, 2005.
48. [48]
  N.E. Brese, M. O'Keeffe, Acta Crystallogr. B 47 (1991) 192–197. doi: 10.1107/S0108768190011041
49. [49]
  E.E. Oyeka, M.J. Winiarski, H. Świątek, et al., Angew. Chem. Int. Ed. 61 (2022) e202213499. doi: 10.1002/anie.202213499
50. [50]
  C. Han, A.J. Bradford, J.A. McNulty, et al., Chem. Mater. 34 (2022) 2458–2467. doi: 10.1021/acs.chemmater.2c00107
51. [51]
  H. Cheng, W. Jin, Z. Yang, et al., Inorg. Chem. Front 9 (2022) 4554–4568.
52. [52]
  C. Jin, F. Li, X. Li, et al., Chem. Mater. 34 (2022) 7516–7525. doi: 10.1021/acs.chemmater.2c01831
53. [53]
  J.C. Bonner, M.E. Fisher, Phys. Rev. 135 (1964) A640–A658. doi: 10.1103/PhysRev.135.A640
54. [54]
  E.Q. Gao, Q.H. Zhao, J.K. Tang, et al., J. Chem. Soc. Dalton Trans. (2001) 1537–1540. doi: 10.1039/B100142F
55. [55]
  C. Kachi-Terajima, M. Ishii, T. Saito, et al., Inorg. Chem. 51 (2012) 7502–7507. doi: 10.1021/ic202708e
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通讯作者: 陈斌, bchen63@163.com

Multifunctional properties of a polar spin chain compound [N(C₃H₇)₄][Cu(C₈H₄NO₄)]·H₂O exhibiting both one-dimensional magnetism and nonlinear optical activity