Citation: Yaping Wang, Pengcheng Yuan, Zeyuan Xu, Xiong-Xiong Liu, Shengfa Feng, Mufan Cao, Chen Cao, Xiaoqiang Wang, Long Pan, Zheng-Ming Sun. Ti₃C₂T_x MXene in-situ transformed Li₂TiO₃ interface layer enabling 4.5 V-LiCoO₂/sulfide all-solid-state lithium batteries with superior rate capability and cyclability[J]. Chinese Chemical Letters, ;2024, 35(6): 108776. doi: 10.1016/j.cclet.2023.108776 shu

Ti₃C₂T_x MXene in-situ transformed Li₂TiO₃ interface layer enabling 4.5 V-LiCoO₂/sulfide all-solid-state lithium batteries with superior rate capability and cyclability

Yaping Wang ^{a, 1} ,
Pengcheng Yuan ^{a, 1} ,
Zeyuan Xu ^a ,
Xiong-Xiong Liu ^a ,
Shengfa Feng ^a ,
Mufan Cao ^a ,
Chen Cao ^b ,
Xiaoqiang Wang ^{b, *,} ,
Long Pan ^{a, *,} ,
Zheng-Ming Sun ^{a, *,}

a.
Key Laboratory of Advanced Metallic Materials of Jiangsu Province, School of Materials Science and Engineering, Southeast University, Nanjing 211189, China
b.
CALB Technology Co., Ltd., Changzhou 213200, China

xiaoqiang.wang@calb-tech.com

panlong@seu.edu.cn

zmsun@seu.edu.cn

Received Date: 22 May 2023
Revised Date: 8 June 2023
Accepted Date: 5 July 2023
Available Online: 6 July 2023

Figures(6)

All-solid-state lithium batteries (ASSLBs) based on sulfide electrolytes promise next-generation energy storage with high energy density and safety. However, the sulfide electrolytes suffer from phase instability and sluggish interfacial charge transport when pairing with layered oxide cathodes at high voltages. Herein, a simple and efficient strategy is proposed using two-dimensional Ti₃C₂T MXene as starting material to in-situ construct a 15 nm Li₂TiO₃ layer on a typical oxide cathode, LiCoO₂. The in-situ transformation of Ti₃C₂T into Li₂TiO₃ layer occurs at a low temperature of 500 ℃, avoiding the phase deterioration of LiCoO₂. The thin Li₂TiO₃ layer is Li⁺ conducting and electrochemically stable, thereby preventing the interfacial decomposition of sulfide electrolytes induced by LiCoO₂ at high voltages and facilitating Li⁺ transport at the interface. Moreover, Li₂TiO₃ can stabilize the layer structure of LiCoO₂ at high voltages. Consequently, the sulfide-based ASSLB using LiCoO₂@Li₂TiO₃ cathode can operate stably at a high voltage of up to 4.5 V (vs. Li⁺/Li), delivering an outstanding initial specific discharge capacity of 138.8 mAh/g with a high capacity retention of 86.2% after 100 cycles at 0.2 C. The in-situ transformation strategy may also apply to other MXenes, offering a general approach for constructing other advanced lithiated coatings for oxide cathodes.
- Solid sulfide electrolyte,
- Oxide cathode,
- MXene,
- In-situ transformation,
- Li₂TiO₃ interfacial layer
1. [1]
  R. Chen, Q. Li, X. Yu, et al., Chem. Rev. 120 (2020) 6820–6877. doi: 10.1021/acs.chemrev.9b00268
2. [2]
  L. Liu, J. Xu, S. Wang, et al., Etransportation 1 (2019) 100010. doi: 10.1016/j.etran.2019.100010
3. [3]
  X. Fan, M. Liu, R. Zhang, et al., Chin. Chem. Lett. 33 (2022) 4421–4427. doi: 10.1016/j.cclet.2021.12.064
4. [4]
  J. Liu, H. Yuan, H. Liu, et al., Adv. Energy Mater. 12 (2022) 2100748. doi: 10.1002/aenm.202100748
5. [5]
  J. Lau, R.H. DeBlock, D.M. Butts, et al., Adv. Energy Mater. 8 (2018) 1800933. doi: 10.1002/aenm.201800933
6. [6]
  Y. Kato, S. Hori, T. Saito, et al., Nat. Energy 1 (2016) 16030–16036. doi: 10.1038/nenergy.2016.30
7. [7]
  N. Kamaya, K. Homma, Y. Yamakawa, et al., Nat. Mater. 10 (2011) 682–686. doi: 10.1038/nmat3066
8. [8]
  J. Wu, L. Shen, Z. Zhang, et al., Electrochem. Energy Rev. 4 (2021) 101–135. doi: 10.1007/s41918-020-00081-4
9. [9]
  Z. Jiang, S. Chen, C. Wei, et al., Chin. Chem. Lett. 35 (2024) 108561. doi: 10.1016/j.cclet.2023.108561
10. [10]
  G. Peng, X. Yao, H. Wan, et al., J. Power Sources 307 (2016) 724–730. doi: 10.1016/j.jpowsour.2016.01.039
11. [11]
  S. Yang, B. Wang, Q. Lv, et al., Chin. Chem. Lett. 34 (2023) 107783. doi: 10.1016/j.cclet.2022.107783
12. [12]
  J. Yin, X. Yao, G. Peng, et al., Solid State Ion. 274 (2015) 8–11. doi: 10.1016/j.ssi.2015.02.014
13. [13]
  Y. Jin, Q. He, G. Liu, et al., Adv. Mater. 35 (2023) 2211047. doi: 10.1002/adma.202211047
14. [14]
  C. Chen, M. Jiang, T. Zhou, et al., Adv. Energy Mater. 11 (2021) 2003939. doi: 10.1002/aenm.202003939
15. [15]
  W. Zhang, F.H. Richter, S.P. Culver, et al., ACS Appl. Mater. Interfaces 10 (2018) 22226. doi: 10.1021/acsami.8b05132
16. [16]
  K. Takada, N. Ohta, L. Zhang, et al., Solid State Ion. 225 (2012) 594–597. doi: 10.1016/j.ssi.2012.01.009
17. [17]
  Y. Li, D. Zhang, X. Xu, et al., J. Energy Chem. 60 (2021) 32–60. doi: 10.1016/j.jechem.2020.12.017
18. [18]
  A. Banerjee, H. Tang, X. Wang, et al., ACS Appl. Mater. Interfaces 11 (2019) 43138–43145. doi: 10.1021/acsami.9b13955
19. [19]
  Y. Liao, J. Hu, Z. Fu, et al., J. Energy Chem. 80 (2023) 458–465. doi: 10.1016/j.jechem.2023.02.012
20. [20]
  L. Wang, R. Xie, B. Chen, et al., Nat. Commun. 11 (2020) 5889–5897. doi: 10.1038/s41467-020-19726-5
21. [21]
  J. Liang, X. Zeng, X. Zhang, et al., J. Am. Chem. Soc. 140 (2018) 6767–6770. doi: 10.1021/jacs.8b03319
22. [22]
  W. He, L. Zhou, M.K. Tufail, et al., Trans. Tianjin Univ. 27 (2021) 423–433. doi: 10.1007/s12209-021-00294-8
23. [23]
  N. Ohta, K. Takada, L. Zhang, et al., Adv. Mater. 18 (2006) 2226–2229. doi: 10.1002/adma.200502604
24. [24]
  U. Nisar, N. Muralidharan, R. Essehli, et al., Energy Storage Mater. 38 (2021) 309–328. doi: 10.1016/j.ensm.2021.03.015
25. [25]
  J.W. Lee, Y.J. Park, J. Electrochem. Sci. Technol. 9 (2018) 176–183. doi: 10.33961/JECST.2018.9.3.176
26. [26]
  N. Ohta, K. Takada, I. Sakaguchi, et al., Electrochem. Commun. 9 (2007) 1486–1490. doi: 10.1016/j.elecom.2007.02.008
27. [27]
  X. Li, L. Jin, D. Song, et al., J. Energy Chem. 40 (2020) 39–45. doi: 10.1167/iovs.61.5.39
28. [28]
  J. Shi, Z. Ma, K. Han, et al., J. Mater. Chem. A 10 (2022) 21336. doi: 10.1039/d2ta06703j
29. [29]
  A. Müller, F. Okur, A. Aribia, et al., Mater. Adv. 4 (2023) 2138–2146. doi: 10.1039/d3ma00155e
30. [30]
  C. Wang, F. Ren, Y. Zhou, et al., Energy Environ. Sci. 14 (2021) 437–450. doi: 10.1039/d0ee03212c
31. [31]
  Y. Xiao, L.J. Miara, Y. Wang, et al., Joule 3 (2019) 1252–1275. doi: 10.1016/j.joule.2019.02.006
32. [32]
  Y. Zhu, X. He, Y. Mo, J. Mater. Chem. A 4 (2016) 3253–3266. doi: 10.1039/C5TA08574H
33. [33]
  A.M. Nolan, Y. Liu, Y. Mo, Acs Energy Lett. 4 (2019) 2444–2451. doi: 10.1021/acsenergylett.9b01703
34. [34]
  Z. Li, Z. Wang, Y. Miao, et al., J. Power Sources 541 (2022) 231703. doi: 10.1016/j.jpowsour.2022.231703
35. [35]
  J. Liu, Z. Wu, M. Yu, et al., Small 18 (2022) 2106337. doi: 10.1002/smll.202106337
36. [36]
  J. Cao, H. Xie, F. Lv, et al., Acs Appl. Energy Mater. 3 (2020) 5462–5471. doi: 10.1021/acsaem.0c00446
37. [37]
  X. Li, Z. Huang, C.E. Shuck, et al., Nat. Rev. Chem. 6 (2022) 389–404. doi: 10.1038/s41570-022-00384-8
38. [38]
  H. Zhang, L. Yang, P. Zhang, et al., Adv. Mater. 33 (2021) 2008447. doi: 10.1002/adma.202008447
39. [39]
  D. Sha, C. Lu, W. He, et al., ACS Nano 16 (2022) 2711–2720. doi: 10.1021/acsnano.1c09639
40. [40]
  M. Xia, B. Chen, F. Gu, et al., ACS Nano 14 (2020) 5111–5120. doi: 10.1021/acsnano.0c01976
41. [41]
  R.S. Negi, P. Minnmann, R. Pan, et al., Chem. Mat. 33 (2021) 6713–6723. doi: 10.1021/acs.chemmater.1c01123
42. [42]
  J. Fu, Y. Bai, C. Liu, et al., Mater. Chem. Phys. 115 (2009) 105–109. doi: 10.1016/j.matchemphys.2008.11.027
43. [43]
  L. Cao, H. Wang, Z. Guo, et al., J. Mater. Chem. A 11 (2023) 9913–9921. doi: 10.1039/d3ta00999h
44. [44]
  H. Nie, L. Xu, D. Song, et al., Green Chem. 17 (2015) 1276–1280. doi: 10.1039/C4GC01951B
45. [45]
  J. Zhang, C. Liu, H. Zhang, et al., J. Mater. Chem. A 11 (2023) 8766–8775. doi: 10.1039/d2ta09893h
46. [46]
  W. Yoon, K. Kim, J. Power Sources (1999) 517–523.
47. [47]
  K. Dokko, S. Horikoshi, T. Itoh, et al., J. Power Sources 90 (2000) 109–115. doi: 10.1016/S0378-7753(00)00456-0
48. [48]
  M. Nakamura, E.G. Víllora, T. Ohsawa, et al., J. Cryst. Growth 609 (2023) 127153. doi: 10.1016/j.jcrysgro.2023.127153
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沈阳化工大学材料科学与工程学院沈阳 110142

Ti3C2Tx MXene in-situ transformed Li2TiO3 interface layer enabling 4.5 V-LiCoO2/sulfide all-solid-state lithium batteries with superior rate capability and cyclability

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通讯作者: 陈斌, bchen63@163.com

Ti₃C₂T_x MXene in-situ transformed Li₂TiO₃ interface layer enabling 4.5 V-LiCoO₂/sulfide all-solid-state lithium batteries with superior rate capability and cyclability