Citation: Jianwei Li, Joseph W.H. Burnett, Claudia Martinez Macias, Russell F. Howe, Xiaodong Wang. Oxide-supported metal catalysts for anaerobic NAD⁺ regeneration with concurrent hydrogen production[J]. Chinese Chemical Letters, ;2024, 35(2): 108737. doi: 10.1016/j.cclet.2023.108737 shu

Oxide-supported metal catalysts for anaerobic NAD⁺ regeneration with concurrent hydrogen production

a.
Chemical Engineering, School of Engineering, Lancaster University, Lancaster LA1 4YW, United Kingdom
b.
Chemistry Department, University of Aberdeen, Aberdeen AB24 3UE, United Kingdom

xiaodong.wang@lancaster.ac.uk

Received Date: 12 February 2023
Revised Date: 21 June 2023
Accepted Date: 26 June 2023
Available Online: 28 June 2023

Figures(5)

We report SiO₂-supported monometallic Pt, Pd, Au, Ni, Cu and Co catalysts for proton-driven NAD⁺ regeneration, co-producing H₂. All metals are fully selective to NAD⁺ where the order of turnover frequencies (Pt > Pd > Cu > Au, Ni and Co) coincides with those otherwise observed in electrochemical hydrogen evolution reactions. This has revealed that NADH is capable of converting the metal sites into a "cathode" without an external potential and the NADH to NAD⁺ reaction involves transferring electron and hydrogen atom separately. Electron-deficient Pt^δ+ (on CeO₂) enhances TOF and the heterogeneous Pt/CeO₂ catalyst is recyclable without losing any activity/selectivity.
- NAD⁺ regeneration,
- Heterogeneous catalyst,
- Hydrogenase mimic,
- Hydrogen binding energy,
- Hydrogen production
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Oxide-supported metal catalysts for anaerobic NAD+ regeneration with concurrent hydrogen production

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通讯作者: 陈斌, bchen63@163.com

Oxide-supported metal catalysts for anaerobic NAD⁺ regeneration with concurrent hydrogen production