Citation: Xijie Chen, Keqiang Xu, Jinhan Li, Xiao Wang, Tete Zhao, Fangming Liu, Meng Yu, Fangyi Cheng. Ni₃S₂@NiFeP_x electrode with dual-anion-modulated layer for efficient and stable oxygen evolution[J]. Chinese Chemical Letters, ;2023, 34(11): 108713. doi: 10.1016/j.cclet.2023.108713 shu

Ni₃S₂@NiFeP_x electrode with dual-anion-modulated layer for efficient and stable oxygen evolution

Xijie Chen ^a ,
Keqiang Xu ^a ,
Jinhan Li ^a ,
Xiao Wang ^a ,
Tete Zhao ^a ,
Fangming Liu ^a ,
Meng Yu ^{a, *,} ,
Fangyi Cheng ^{a, b, *,}

a.
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Engineering Research Center of High-efficiency Energy Storage (Ministry of Education), College of Chemistry, Nankai University, Tianjin 300071, China
b.
Haihe Laboratory of Sustainable Chemical Transformations, Tianjin 300192, China

mengyu@nankai.edu.cn

fycheng@nankai.edu.cn

Received Date: 23 April 2023
Revised Date: 30 May 2023
Accepted Date: 19 June 2023
Available Online: 21 June 2023

Figures(5)

The rational construction of high-performance and stable electrocatalyst for oxygen evolution reaction (OER) is a prerequisite for efficient water electrolysis. Herein, we develop a broccoli-like Ni₃S₂@NiFeP_x (Ni₃S₂@NFP) catalyst on nickel foam (NF) via a sequential two-step layer-by-layer assembly electrodeposition method. X-ray diffraction, in situ Raman and Fourier-transform infrared spectra have mutually validated the element segregation and phase refusion during OER condition. The reconstruction of double layer Ni₃S₂@NFP facilitates the formation of the active (oxy)hydroxides, which is modulated by the dual anionic layer with mixed sulfate and phosphate ions. As a result, the obtained Ni₃S₂@NFP electrode exhibits low overpotential (329 mV) and long-term durability (~500 h) for OER at current density of 500 mA/cm². Moreover, the self-supported Ni₃S₂@NFP can act as an efficient and durable anode in alkaline anion exchange membrane water electrolysis device (AEMWE). This work provides a facile and scaled-up strategy to construct self-supported electrocatalyst and emphasizes the crucial role of anions in pre-catalyst reconstruction and enhancing OER performance.
- Oxygen evolution reaction,
- Anion-modulated layer,
- Electrochemical reconstruction,
- Phosphide,
- Sulfide,
- Membrane electrode assembly
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Ni3S2@NiFePx electrode with dual-anion-modulated layer for efficient and stable oxygen evolution

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Ni₃S₂@NiFeP_x electrode with dual-anion-modulated layer for efficient and stable oxygen evolution