Citation: Na Wang, Wang Luo, Huaiyi Shen, Huakai Li, Zejiang Xu, Zhiyuan Yue, Chao Shi, Hengyun Ye, Leping Miao. Crystal engineering regulation achieving inverse temperature symmetry breaking ferroelasticity in a cationic displacement type hybrid perovskite system[J]. Chinese Chemical Letters, ;2024, 35(5): 108696. doi: 10.1016/j.cclet.2023.108696 shu

Crystal engineering regulation achieving inverse temperature symmetry breaking ferroelasticity in a cationic displacement type hybrid perovskite system

Chaotic Matter Science Research Center, Department of Materials, Metallurgy and Chemistry, Jiangxi University of Science and Technology, Ganzhou 341000, China

15150517670@163.com

miaoleping@jxust.edu.cn

Received Date: 24 April 2023
Revised Date: 16 May 2023
Accepted Date: 14 June 2023
Available Online: 19 June 2023

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Ferroelastic hybrid perovskite materials have been revealed the significance in the applications of switches, sensors, actuators, etc. However, it remains a challenge to design high-temperature ferroelastic to meet the requirements for the practical applications. Herein, we reported an one-dimensional organic-inorganic hybrid perovskites (OIHP) (3-methylpyrazolium)CdCl₃ (3-MBCC), which possesses a mmmF2/m ferroelastic phase transition at 263 K. Moreover, utilizing crystal engineering, we replace –CH₃ with –NH₂ and –H, which increases the intermolecular force between organic cations and inorganic frameworks. The phase transition temperature of (3-aminopyrazolium)CdCl₃ (3-ABCC), and (pyrazolium)CdCl₃ (BCC) increased by 73 K and 10 K, respectively. Particularly, BCC undergoes an unconventional inverse temperature symmetry breaking (ISTB) ferroelastic phase transition around 273 K. Differently, it transforms from a high symmetry low-temperature paraelastic phase (point group 2/m) to a low symmetry high-temperature ferroelastic phase (point group 1) originating from the rare mechanism of displacement of organic cations phase transition. It means that crystal BCC retains in ferroelastic phase above 273 K until melting point (446 K). Furthermore, characteristic ferroelastic domain patterns on crystal BCC are confirmed with polarized optical microscopy. Our study enriches the molecular mechanism of ferroelastics in the family of organic-inorganic hybrids and opens up a new avenue for exploring high-temperature ferroic materials.
- Organic-inorganic hybrid perovskite,
- Crystal engineering,
- Inverse temperature symmetry breaking,
- Displacement type phase transition,
- Ferroelasticity
1. [1]
  G.R. Desiraju, The Design of Organic Solids, Elsevier, Amsterdam, 1989.
2. [2]
  A.D. Bond, CrystEngComm 14 (2012) 2363–2366. doi: 10.1039/c2ce06662a
3. [3]
  F. Jona, G. Shirane, Ferroelectric Crystals, Dover Publications Inc., New York, 1993.
4. [4]
  E.K.H. Salje, Annu. Rev. Mater. Res. 42 (2012) 265–283. doi: 10.1146/annurev-matsci-070511-155022
5. [5]
  J. Erhart, Phase Transit. 77 (2004) 989–1074. doi: 10.1080/01411590410001710744
6. [6]
  N. Balke, S. Choudhury, S. Jesse, et al., Nat. Nanotech. (2009) 868–875. doi: 10.1038/nnano.2009.293
7. [7]
  P. Gao, J. Britson, C.T. Nelson, et al., Nat. Commun. 5 (2014) 4801. doi: 10.1038/ncomms5801
8. [8]
  R.G. Xiong, S.Q. Lu, Z.X. Zhang, et al., Angew. Chem. Int. Ed. 59 (2020) 9574–9578. doi: 10.1002/anie.202000290
9. [9]
  M.D. Hollingsworth, M.L. Peterson, K.L. Pate, et al., J. Am. Chem. Soc. 124 (2002) 2094–2095. doi: 10.1021/ja010327f
10. [10]
  A.I. Khan, X. Marti, C. Serrao, et al., Nano. Lett. 15 (2015) 2229–2234. doi: 10.1021/nl503806p
11. [11]
  E.J. Guo, R. Desautels, D. Keavney, et al., Sci. Adv. 5 (2019) eaav5050. doi: 10.1126/sciadv.aav5050
12. [12]
  H. Yokota, S. Matsumoto, E.K.H. Salje, et al., Phys. Rev. B 98 (2018) 104105. doi: 10.1103/PhysRevB.98.104105
13. [13]
  N. Balke, S. Choudhury, S. Jesse, et al., Nat. Nanotech. 4 (2009) 868–875. doi: 10.1038/nnano.2009.293
14. [14]
  C. Hill, M.C. Weber, J. Lehmann, et al., APL Mater. 8 (2020) 081108. doi: 10.1063/5.0011507
15. [15]
  H. Yokota, S. Niki, R. Haumont, et al., AIP Adv. 7 (2017) 085315. doi: 10.1063/1.4990608
16. [16]
  M. Moskwa, E. Ganczar, P. Sobieszczyk, et al., J. Phys. Chem. C 124 (2020) 18209–18218. doi: 10.1021/acs.jpcc.0c05322
17. [17]
  Z. Sun, X. Wang, J. Luo, et al., J. Mater. Chem. C 1 (2013) 2561–2567. doi: 10.1039/c3tc30166d
18. [18]
  H.Y. Zhang, C.L. Hu, Z.B. Hu, et al., J. Am. Chem. Soc. 142 (2020) 3240–3245. doi: 10.1021/jacs.9b13446
19. [19]
  W. Yuan, Y. Zeng, Y.Y. Tan, et al., Chem. Commun. 55 (2019) 8983–8986. doi: 10.1039/c9cc03862k
20. [20]
  L. Lu, X. Pan, J. Luo, et al., Chem. Eur. J. 26 (2020) 16975–16984. doi: 10.1002/chem.202000788
21. [21]
  Q. Xu, L. Ye, R.M. Liao, et al., Chem. Eur. J. 28 (2022) e202103913. doi: 10.1002/chem.202103913
22. [22]
  X. Zhang, L. Li, Z. Sun, et al., Chem. Soc. Rev. 48 (2019) 517–539. doi: 10.1039/c8cs00563j
23. [23]
  R. Jakubas, M. Rok, K. Mencel, et al., Inorg. Chem. Front. 7 (2020) 2107–2128. doi: 10.1039/d0qi00265h
24. [24]
  Y. Liu, L. Collins, R. Proksch, et al., Nat. Mater. 1 (2018) 1013–1019. doi: 10.1038/s41563-018-0152-z
25. [25]
  E. Strelcov, Q. Dong, T. Li, et al., Sci. Adv. 3 (2017) e1602165. doi: 10.1126/sciadv.1602165
26. [26]
  L. Zhou, R.X. Li, P.P. Shi, et al., Inorg. Chem. 59 (2020) 18174–18180. doi: 10.1021/acs.inorgchem.0c02649
27. [27]
  X.Q. Huang, H. Zhang, F. Wang, et al., J. Phys. Chem. Lett. 12 (2021) 5221–5227. doi: 10.1021/acs.jpclett.1c01473
28. [28]
  D.X. Liu, X.X. Chen, Z.M. Ye, et al., Sci. China Mater. 65 (2022) 263–267. doi: 10.1007/s40843-021-1794-1
29. [29]
  H.Y. Zhang, Z.X. Zhang, X.J. Song, et al., J. Am. Chem. Soc. 142 (2020) 20208–20215. doi: 10.1021/jacs.0c10686
30. [30]
  Y.Y. Tang, Y. Ai, W.Q. Liao, et al., Adv. Mater. 31 (2019) 1902163. doi: 10.1002/adma.201902163
31. [31]
  X.Q. Xu, H. Zhang, X.Q. Huang, et al., Inorg. Chem. Front. 8 (2021) 1197–1204. doi: 10.1039/d0qi01365j
32. [32]
  Z.X. Wang, Y. Zhang, Y.Y. Tang, et al., J. Am. Chem. Soc. 141 (2019) 4372–4378. doi: 10.1021/jacs.8b13109
33. [33]
  C.F. Wang, H. Li, M.G. Li, et al., Adv. Funct. Mater. 31 (2021) 2009457. doi: 10.1002/adfm.202009457
34. [34]
  M. Itoh, R. Wang, Y. Inaguma, et al., Phys. Rev. Lett. 82 (1999) 3540. doi: 10.1103/PhysRevLett.82.3540
35. [35]
  K. Chang, J.W. Liu, H.C. Lin, et al., Science 353 (2016) 274–278. doi: 10.1126/science.aad8609
36. [36]
  Y. Ai, H.P. Lv, Z.X. Wang, et al., Trends Chem. 3 (2021) 1088–1099. doi: 10.1016/j.trechm.2021.09.010
37. [37]
  B.D. Liang, T. Jin, L.P. Miao, et al., Chin. Chem. Lett. 33 (2022) 1422–1424. doi: 10.1016/j.cclet.2021.08.032
38. [38]
  S. Koval, J. Kohanoff, J. Lasave, et al., Phys. Rev. B 71 (2005) 184102. doi: 10.1103/PhysRevB.71.184102
39. [39]
  Q.R. Meng, W.J. Xu, W.H. Hu, et al., Chem. Commun. 57 (2021) 6292–6295. doi: 10.1039/d1cc02085d
40. [40]
  X. Zheng, L. Zhou, P.P. Shi, et al., Chem. Commun. 53 (2017) 7756–7759. doi: 10.1039/C7CC01771E
41. [41]
  S. Weinberg, Phys. Rev. D 9 (1974) 3357–3378.
42. [42]
  M. Szafranski, Cryst. Growth Des. 16 (2016) 3771–3776. doi: 10.1021/acs.cgd.6b00279
43. [43]
  P. Szklarz, A. Ingram, Z. Czapla, et al., Phase Trans. 90 (2017) 610–617. doi: 10.1080/01411594.2016.1252980
44. [44]
  A. Ingram, S. Wacke, Z. Czapla, et al., Phase Trans. 92 (2019) 467–474. doi: 10.1080/01411594.2019.1587440
45. [45]
  M.M. Zhao, L. Zhou, P.P. Shi, et al., Chem. Eur. J. 25 (2019) 6447–6454. doi: 10.1002/chem.201900771
46. [46]
  S.N. Cheng, K. Ding, T. Zhang, et al., Chem. Eur. J. 27 (2021) 17655–17659. doi: 10.1002/chem.202103229
47. [47]
  Y.P. Gong, X.X. Chen, B.Q. Zhao, et al., Chin. Chem. Lett. 34 (2023) 108282. doi: 10.1016/j.cclet.2023.108282
48. [48]
  M.A. Spackman, CrystEngComm. 4 (2002) 378–392. doi: 10.1039/B203191B
49. [49]
  M.A. Spackman, D. Jayatilaka, CrystEngComm. 11 (2009) 19–32. doi: 10.1039/B818330A
50. [50]
  L.P. Miao, L.L. Chu, X.B. Han, et al., Inorg. Chem. Front. 8 (2021) 2809–2816. doi: 10.1039/d1qi00309g
51. [51]
  B.Q. Zhao, X.X. Chen, H. Ye, et al., Chem. Sci. 14 (2023) 5965–5973. doi: 10.1039/d3sc01101a
52. [52]
  K. Aizu, J. Phys. Soc. Jpn. 28 (1970) 706. doi: 10.1143/JPSJ.28.706
53. [53]
  L.T. Li, C.X. Ji, Y.X. Sun, et al., Inorg. Chem. Front. 9 (2022) 1380–1385. doi: 10.1039/d2qi00114d
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