Citation: Lihua Ma, Song Guo, Zhi-Ming Zhang, Jin-Zhong Wang, Tong-Bu Lu, Xian-Shun Zeng. Sensitizing photoactive metal–organic frameworks via chromophore for significantly boosting photosynthesis[J]. Chinese Chemical Letters, ;2024, 35(5): 108661. doi: 10.1016/j.cclet.2023.108661 shu

Sensitizing photoactive metal–organic frameworks via chromophore for significantly boosting photosynthesis

Lihua Ma ^a ,
Song Guo ^{b, *,} ,
Zhi-Ming Zhang ^b ,
Jin-Zhong Wang ^{a, *,} ,
Tong-Bu Lu ^b ,
Xian-Shun Zeng ^{a, b, *,}

a.
School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001, China
b.
Institute for New Energy Materials and Low Carbon Technologies, School of Material Science & Engineering, Tianjin University of Technology, Tianjin 300384, China

guosong@email.tjut.edu.cn

jinzhong.wang@hit.edu.cn

Xshzeng@tjut.edu.cn

Received Date: 9 February 2023
Revised Date: 29 April 2023
Accepted Date: 7 June 2023
Available Online: 11 June 2023

Figures(5)

Photosensitization related to energy/electron transfer process is of great importance to natural photosynthesis. Herein, we proposed a promising strategy to improve the sensitizing ability of the typical photoactive MOFs (UiO-Ir) by engineering its metal coordination center with NBI (1, 8-naphthalenebenzimidizole) chromophore. The resulting MOFs (UiO-Ir-NBI) exhibited a strong sensitizing ability for significantly boosting photosynthesis. Impressively, the catalytic yield of 2-chloroethyl ethyl sulfoxide with UiO-Ir-NBI can reach 99%, over 6 times higher than that with UiO-Ir (16.4%). Moreover, UiO-Ir-NBI exhibited an excellent catalytic stability and a broad substrate tolerance, highlighting its great application prospect. Systematic investigations revealed that the strong visible light absorption, long excited state lifetime and efficient electron-hole separation of UiO-Ir-NBI greatly contributed to harvesting visible light and facilitating interface electron/energy transfer for efficient solar energy utilization. This work provides a new horizon to boost photosythesis of MOFs by engineering their metal sensitizing centers at a molecular level.
- Metal–organic framework,
- Photocatalysis,
- Excited state,
- Strong visible absorption,
- Iridium complex
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