Citation: Yang Lan, Jinxuan Ren, Pu Zhang, Xuehua Dong, Ling Huang, Liling Cao, Daojiang Gao, Guohong Zou. ASb(SO₄)₂ (A = Rb, Cs): Two short-wave UV antimony sulfates exhibiting large birefringence[J]. Chinese Chemical Letters, ;2024, 35(1): 108652. doi: 10.1016/j.cclet.2023.108652 shu

ASb(SO₄)₂ (A = Rb, Cs): Two short-wave UV antimony sulfates exhibiting large birefringence

Yang Lan ^a ,
Jinxuan Ren ^a ,
Pu Zhang ^a ,
Xuehua Dong ^a ,
Ling Huang ^{a, *,} ,
Liling Cao ^a ,
Daojiang Gao ^a ,
Guohong Zou ^{b, *,}

a.
College of Chemistry and Materials Science, Sichuan Normal University, Chengdu 610066, China
b.
College of Chemistry, Sichuan University, Chengdu 610065, China

huangl026@sina.com

zough@scu.edu.cn

Received Date: 24 April 2023
Revised Date: 16 May 2023
Accepted Date: 5 June 2023
Available Online: 7 June 2023

Figures(3)

Herein, two antimony sulfates, named RbSb(SO₄)₂ (1) and CsSb(SO₄)₂ (2), have been successfully synthesized with the introduction of Sb³⁺ cation with stereochemically active lone pairs (SCALP) into sulfates by the conventional hydrothermal method. Both two compounds endow short ultraviolet (UV) absorption edges (281 nm and 278 nm, respectively) and large birefringence (0.171@546 nm and 0.174@546 nm, respectively), which means that they are promising short-wave UV optical materials. Interestingly, though both of the two compounds exhibit similar 1D chained structures, and possess the same functional moieties including SbO₄ seesaws and SO₄ tetrahedral groups, they exhibit significantly opposite macroscopic symmetries, i.e., compound 1 crystallizes in a centrosymmetric (CS) manner (P2₁/n) and compound 2 in a noncentrosymmetric (NCS) manner (P2₁2₁2₁), due to the size of cations [r(Rb⁺) = 1.56 Å, r(Cs⁺) = 1.67 Å] affects the orientation of SCALP of the adjacent Sb³⁺.
- Antimony sulfates,
- Birefringent crystals,
- Large birefringence,
- Short UV absorption edge,
- Stereochemically active lone pair
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ASb(SO4)2 (A = Rb, Cs): Two short-wave UV antimony sulfates exhibiting large birefringence

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通讯作者: 陈斌, bchen63@163.com

ASb(SO₄)₂ (A = Rb, Cs): Two short-wave UV antimony sulfates exhibiting large birefringence