Citation: Yonghui Sun, Linnan Jiang, Yong Chen, Yu Liu. In situ crosslink polymerization induced long-lived multicolor supramolecular hydrogel based on modified β-cyclodextrin[J]. Chinese Chemical Letters, ;2024, 35(2): 108644. doi: 10.1016/j.cclet.2023.108644 shu

In situ crosslink polymerization induced long-lived multicolor supramolecular hydrogel based on modified β-cyclodextrin

College of Chemistry, State Key Laboratory of Elemento-Organic Chemistry Nankai University, Tianjin 300071, China

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yuliu@nankai.edu.cn

Received Date: 30 March 2023
Revised Date: 26 May 2023
Accepted Date: 2 June 2023
Available Online: 3 June 2023

Figures(5)

The construction of hydrogels with good mechanical properties and phosphorescent properties is full of challenges. Herein, we report a supramolecular phosphorescent hydrogel with long lifetime, high tensile strength and self-healing property, which can be easily constructed through in-situ thermal-initiated polymerization of isocyanatoethyl acrylate-modified β-cyclodextrin (β-CD-DA) and acrylate-modified adamantane (Ad-DA), acrylic acid (AA), followed by the non-covalent association with carbon dots (CNDs). The lifetime of phosphorescent hydrogel can reach 1261 ms at room temperature, and the quantum yield is 11%. Importantly, through the efficient triplet to singlet Förster resonance energy transfer (TS-FRET), the phosphorescent hydrogel shows the good phosphorescence energy transfer property for organic dyes Rhodamine B and Eosin Y with the delayed fluorescence lifetime up to 730 ms and 585 ms as well as the energy transfer efficiency (Φ_ET) up to 99.9% and 99.3%, respectively. Moreover, owing to the host-guest interactions between β-CD-DA and Ad-DA, the three-dimensional cross-linked network phosphorescent hydrogel can be easily stretched to 18 times of its original length, and can achieve self-healing of the cut surfaces within 30 min. These results will expand the scope of phosphorescent materials and provide new ideas and opportunities for materials science.
- Room temperature phosphorescence,
- Hydrogel,
- Phosphorescence energy transfer,
- Cyclodextrin,
- Supramolecular interaction
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