Citation: Yunang Dong, Penglu Wang, Xiangyu Liu, Jiang Deng, Aling Chen, Lupeng Han, Dengsong Zhang. Alkali-resistant NO_x reduction over FeVO₄/TiO₂ catalysts via regulating the electron transfer between Fe and V[J]. Chinese Chemical Letters, ;2024, 35(2): 108635. doi: 10.1016/j.cclet.2023.108635 shu

Alkali-resistant NO_x reduction over FeVO₄/TiO₂ catalysts via regulating the electron transfer between Fe and V

International Joint Laboratory of Catalytic Chemistry, State Key Laboratory of Advanced Special Steel, College of Sciences, Shanghai University, Shanghai 200444, China

dszhang@shu.edu.cn

Received Date: 7 February 2023
Revised Date: 5 May 2023
Accepted Date: 30 May 2023
Available Online: 2 June 2023

Figures(5)

The presence of alkali metals in exhaust gas from stationary resources causes a grand challenge for the practical application of selective catalytic reduction (SCR) of NO_x with NH₃. Here, alkali-resistant NO_x reduction has been successfully implemented via tailoring the electron transfer over Fe and V species on FeVO₄/TiO₂ catalysts. The strong interaction between Fe and V induced electron transfer from V to Fe and strengthened the adsorption and activation of NH₃ and NO over active VO_x sites. In the presence of K₂O, the strong electron withdrawing effect of Fe offset the electron donating effect of K on the VO_x species, thus protecting the active species VO_x to maintain the NO_x reduction ability. The enhanced adsorption and activation of NH₃ allowed SCR reaction to proceed via E-R mechanism even after K₂O poisoning. This work elucidated the electronic effects on the alkali metals resistance of traditional ferric vanadate SCR catalysts and provided a promising strategy to design SCR catalysts with superior alkali resistance.
- Air pollution control,
- NO_X reduction,
- Selective catalytic reduction,
- Alkali metals,
- Electron transfer
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Alkali-resistant NOx reduction over FeVO4/TiO2 catalysts via regulating the electron transfer between Fe and V

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Alkali-resistant NO_x reduction over FeVO₄/TiO₂ catalysts via regulating the electron transfer between Fe and V