Citation: Pei Chen, Hao Zhou, Han Cao, Chunwei Zhuo, Shunjie Liu, Xianhong Wang. Polymeric catalyst with polymerization-enhanced Lewis acidity for CO₂-based copolymers[J]. Chinese Chemical Letters, ;2023, 34(12): 108630. doi: 10.1016/j.cclet.2023.108630 shu

Polymeric catalyst with polymerization-enhanced Lewis acidity for CO₂-based copolymers

Pei Chen ^{a, b} ,
Hao Zhou ^{a, b} ,
Han Cao ^b ,
Chunwei Zhuo ^b ,
Shunjie Liu ^{a, b, *,} ,
Xianhong Wang ^{a, b, *,}

a.
School of Applied Chemistry and Engineering, University of Science and Technology of China, Hefei 230026, China
b.
Key Laboratory of Polymer Ecomaterials, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China

sjliu@ciac.ac.cn

xhwang@ciac.ac.cn

Received Date: 12 April 2023
Revised Date: 25 May 2023
Accepted Date: 29 May 2023
Available Online: 1 June 2023

Figures(3)

Ring-opening copolymerization of CO₂ and epoxides is a promising way to manufacture high value-added materials. Despite a variety of catalyst systems have been reported, the reaction is still limited by low activity and polymer selectivity. Herein, a strategy of polymerization-enhanced Lewis acidity is reported to construct a series of highly efficient polymeric aluminum porphyrin catalysts (PAPCs). The characterization of the coordination equilibrium constant (K_eq) showed significantly enhanced Lewis acidity of PAPC (K_eq = 18.2 L/mol) compared to the monomeric counterpart (K_eq = 6.4 L/mol), accompanied with increased turnover frequency (TOF) from 136 h⁻¹ to 5500 h⁻¹. Through detailed regulation of Lewis acidity, the highly Lewis acidic PAPC-OTs displayed a record high TOF of 30,200 h⁻¹ with polymer selectivity of up to 99%.
- Carbon dioxide,
- Ring-opening copolymerization,
- Polymerization,
- Lewis acidity,
- Polymeric aluminum porphyrin catalyst
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Polymeric catalyst with polymerization-enhanced Lewis acidity for CO2-based copolymers

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通讯作者: 陈斌, bchen63@163.com

Polymeric catalyst with polymerization-enhanced Lewis acidity for CO₂-based copolymers